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    • 15. 发明授权
    • Organic electroluminescent device and process for producing the same
    • 有机电致发光器件及其制造方法
    • US6143433A
    • 2000-11-07
    • US526083
    • 1995-09-11
    • Hideyuki MurataHideki Hirano
    • Hideyuki MurataHideki Hirano
    • H05B33/10H05B33/14H05B33/00B05D5/00
    • H05B33/14H05B33/10Y10S428/917
    • In a first aspect, an organic electroluminescent device having an electroluminescent layer and/or a charge injecting/transporting layer formed out of a thin film of organic polymers of network structure which are excellent in heat resistance and durability, e.g., polyoxadiazoles is obtained by conducting a vapor deposition polymerization of a bifunctional monomer, a polyfunctional monomer of 3 or higher in functionality or a mixture of the polyfunctional monomer and bifunctional monomer and heating the resultant polymer in vacuum or an inert gas. In another aspect, an organic electroluminescent device having an electroluminescent layer and/or a charge injecting/transporting layer formed out of a thin film of polyoxadiazoles is produced without the formation of hydrogen halides (acids) as by-products by performing a vapor deposition polymerization of a monomer having two carboxylic acid halide groups and a monomer having two silylated carbohydrazide groups and heating the resultant polymer in vacuum or an inert gas.
    • 在第一方面中,具有由耐热性和耐久性优异的网状结构的有机聚合物的薄膜形成的电致发光层和/或电荷注入·输送层的有机电致发光元件,例如聚恶二唑,通过导电 双功能单体的蒸气聚合,功能性为3以上的多官能单体或多官能单体和双官能单体的混合物,并在真空或惰性气体中加热所得聚合物。 另一方面,通过进行气相沉积聚合而形成作为副产物形成卤化物(酸)的具有由多偶二恶唑薄膜形成的电致发光层和/或电荷注入/输送层的有机电致发光器件 的具有两个羧酸卤化物基团的单体和具有两个甲硅烷基化碳酰肼基团的单体,并在真空或惰性气体中加热所得聚合物。