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11. 发明授权

US3948902A Method for preparing azines 失效
标题翻译：制备吖嗪的方法
公开(公告)号：US3948902A
公开(公告)日：1976-04-06
申请号：US515156
申请日：1974-10-16
申请人： Jean Pierre Schirmann , Francis Weiss
发明人： Jean Pierre Schirmann , Francis Weiss
IPC分类号： C07C109/00
CPC分类号： C07C251/88
摘要： A method is disclosed for preparing symmetrical azines of the formulas ##EQU1## and unsymmetrical azines of the formulas ##EQU2## and mixtures of azines (I), (II) and (IV) and (I), (III) and (V), wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each is a hydrogen atom, a straight chain alkyl radical of from 1 to 12 carbon atoms, a branched chain alkyl radical or unsubstituted or alkyl substituted cycloalkyl radical of from 3 to 12 carbon atoms, a hydrocarbon radical of from 6 to 12 carbon atoms containing a benzene ring; further provided that R.sup.1 and R.sup.2 can be the same or different radicals, R.sup.3 is a radical different from R.sup.1 and R.sup.2 and R.sup.3 and R.sup.4 are radicals different from each other and each is different from R.sup.1 and R.sup.2 ; or R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3 or R.sup.3 and R.sup.4 bonded to the same carbon atom together form an unsubstituted or alkyl substituted alkylene radical of from 3 to 11 carbon atoms, each of the aforesaid radicals being unsubstituted or substituted with one or more radicals which are stable in the medium in which said azines are produced.The method involves reacting in the liquid phase and in the absence of a nitrile, a carbonyl compound of the formula ##EQU3## alone or together with a different carbonyl compound ##EQU4## or ##EQU5## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each has the same meaning defined above, with ammonia and hydrogen peroxide in the presence of an effective amount of at least one catalyst selected from the group consisting of the hydroxides and water soluble organic and inorganic salts of ammonium and the metals of Groups 1a and IIa of the Periodic Table of the Elements, and recovering the azine or mixture of azines from the reaction medium.
摘要翻译：公开了一种用于制备式R1R1的对称吖嗪的方法。方法C = NN = C ANGLE（I）R2R2 R1R1角度C = NN = C角度（II）R3R3 R3R3角度C = NN = C角度（III）R4R4和不对称吖嗪式（I），（II）和（IV）和（I），（III）的混合物，其中R 1，R 2，R 3，R 3，R 3，和（V），其中R 1，R 2，R 3和R 4各自为氢原子，具有1至12个碳原子的直链烷基，支链烷基或未取代的或烷基取代的3至12个碳原子的环烷基原子，含有苯环的6-12个碳原子的烃基; 进一步提供R1和R2可以是相同或不同的基团，R3是不同于R1和R2的基团，R3和R4是彼此不同的基团，并且各自不同于R1和R2; 或者R 1和R 2或R 1，R 3或R 3和R 4与相同碳原子一起形成未取代的或具有3至11个碳原子的烷基取代的亚烷基，上述每个基团是未取代的或被一个或多个基团取代，在生产所述吖嗪的培养基中是稳定的。

12. 发明授权

US4178292A Process for the preparation of oxaziridine 失效
标题翻译：制备恶唑嗪的方法
公开(公告)号：US4178292A
公开(公告)日：1979-12-11
申请号：US625113
申请日：1975-10-23
申请人： Pierre Tellier , Francis Weiss
发明人： Pierre Tellier , Francis Weiss
IPC分类号： C07D273/00 , C07D273/01 , C07D413/04
CPC分类号： C07D273/00
摘要： This invention relates to a method for preparing oxaziridines which comprises reacting hydrogen peroxide with an azomethinic derivative or with a mixture of a carbonyl compound and a primary amine in the presence of catalytic amounts of selenium or of oxygenated compounds of selenium.
摘要翻译：本发明涉及一种制备氧氮杂环丁烷的方法，其包括在催化量的硒或氧化的硒化合物的存在下，使过氧化氢与偶氮甲碱衍生物或羰基化合物与伯胺的混合物反应。

13. 发明授权

US4049712A Method for manufacturing hydrazodicarbonamide 失效
标题翻译：制备肼基二酰胺的方法
公开(公告)号：US4049712A
公开(公告)日：1977-09-20
申请号：US265749
申请日：1972-06-23
申请人： Jean-Pierre Schirmann , Francis Weiss
发明人： Jean-Pierre Schirmann , Francis Weiss
IPC分类号： C07C67/00 , C07C239/00 , C07C281/02 , C07C281/06 , C07C133/02 , C01B21/16
CPC分类号： C07C281/06
摘要： This invention relates to a method for preparing hydrazodicarbonamide ##STR1## which comprises reacting urea, sulfuric acid, water and an azine or a solution containing an azine of the formula ##STR2## wherein R.sub.1 is hydrogen and R.sub.2 or R.sub.1 and R.sub.2 each is a straight or branched alkyl radical or cycloalkyl radical of up to 6 carbon atoms or R.sub.1 and R.sub.2 of both the >C=N-- moieties together form a straight or branched chain alkylene radical of from 3 to 5 carbon atoms and recovering the hydrazodicarbonamide from the reaction medium.
摘要翻译：本发明涉及一种制备肼基二羰酰胺（I）的方法，其包括使尿素，硫酸，水和吖嗪或含有式（Ⅺ）的吖嗪的溶液，其中R 1为氢，R 2或R 1 并且R 2各自是具有至多6个碳原子的直链或支链烷基或环烷基，或者两个> C = N-部分的R 1和R 2一起形成3至5个碳原子的直链或支链亚烷基，并回收来自反应介质的肼基二酰胺。

14. 发明授权

US3944591A Enolic ethers of adipic dialdehyde and method for preparing the same 失效
标题翻译：己二酸二醛的醚类醚及其制备方法
公开(公告)号：US3944591A
公开(公告)日：1976-03-16
申请号：US326137
申请日：1973-01-23
申请人： Andre Bader , Francis Weiss
发明人： Andre Bader , Francis Weiss
IPC分类号： C07C45/51 , C07C47/277 , C07C121/66 , C07C43/14 , C07C47/26 , C07C121/34
CPC分类号： C07C47/277 , C07C45/513
摘要： Enolic monoether and diether of adipic dialdehyde such as 6-methoxy-5-hexene-1-al, 1,6-dimethoxy-1,5-hexadiene, 1,6-bis-(2 hydroxy propoxy)-1,5-hexadiene are prepared by heating to a sufficiently high temperature for a Cope rearrangement, e.g., 150.degree. to 450.degree. C. of the corresponding monoether or diether of 1,5-hexadiene-3,4-diol.
摘要翻译：己二醛二元醇的单醚和二醚如6-甲氧基-5-己烯-1-a1,1,6-二甲氧基-1,5-己二烯，1,6-双 - （2-羟基丙氧基）-1,5-己二烯通过加热到足够高的温度进行Cope重排，例如150至450℃的相应的1,5-己二烯-3,4-二醇的单醚或二醚制备。

15. 发明申请

US20050120227A1 Method and system for secure filtering of users of a public transport network 审中-公开
标题翻译：用于公共交通网络用户安全过滤的方法和系统
公开(公告)号：US20050120227A1
公开(公告)日：2005-06-02
申请号：US10497977
申请日：2002-12-04
申请人： Francis Weiss
发明人： Francis Weiss
IPC分类号： G06Q10/00 , G06Q50/00 , G07C9/00 , H04L9/32 , H04K1/00 , H04L9/00
CPC分类号： G07C9/00087 , G07C9/00103
摘要： According to the process, a preparatory stage to transport for enrolling (10, 100) users is planned, to form a set of approved users (90), excluding people to be refused (75), and an initial stage of transport for the verification (250) of approved users. The security filtering system contains a network (R1) with means (10, 100) of enrolling people, computerised means (60, 80, 90) for storing the identities of approved users, to which are connected the means of enrolling people, and at least one network (R6, R7) with means (250) of verification of approved users, connected to the said computerised means of storage.
摘要翻译：根据这个过程，计划投入使用（10,100）用户的运输准备阶段，形成一套认可用户（90），不包括被拒绝的人（75），以及验证的初始运输阶段（250）批准用户。所述安全过滤系统包括具有登记人员的装置（10,100）的网络（R 1），用于存储被认可用户的身份的计算机化装置（60,80,90），所述身份与所述人员的登记手段相关联，以及至少一个网络（R 6，R 7），具有连接到所述计算机化存储装置的经认可的用户验证的装置（250）。

16. 发明授权

US3984451A Method for preparing hydrazo-bis-acetonitriles 失效
标题翻译：制备双氢 - 二乙腈的方法
公开(公告)号：US3984451A
公开(公告)日：1976-10-05
申请号：US579548
申请日：1975-05-21
申请人： Francis Weiss , Jean-Pierre Schirmann
发明人： Francis Weiss , Jean-Pierre Schirmann
IPC分类号： C07C255/66 , C07C120/00
CPC分类号： C07C251/88 , C07C255/00
摘要： This invention relates to a method for preparing hydrazo-bis-acetonitriles of the general formula: ##EQU1## wherein R.sub.1 and R.sub.2 have the same meaning hereinafter given, which comprises:A. i. reacting a carbonyl compound of the general formula: ##EQU2## wherein R.sub.1 and R.sub.2 have the same meaning hereinafter given, with ammonia and hydrogen peroxide in the presence of cyanogen or a nitrile of the formulaR.sub.3 (CN).sub.n (III)wherein n is an integer from 1 to 6 and R.sub.3 is an unsubstituted or substituted saturated aliphatic, acyclic or cyclic radical of from 1 to 12 carbon atoms or a benzenyl or pyridinyl radical, to form a symmetrical azine of the formula ##EQU3## ii. oxidizing a secondary alcohol of ##EQU4## wherein R.sub.1 and R.sub.2 have the same meaning hereinafter given, at a temperature and pressure which is sufficient to maintain the alcohol in the liquid phase and result in a liquid phase mixture containing the peroxidic products of the auto-oxidation of the alcohol [v] and reacting auto-oxidation products with ammonia and cyanogen or the nitrile R.sub.3 (CN).sub.n of formula (III) to form the symmetrical azine of formula (IV)b. eliminating unreacted ammonia from the medium resulting from (a);C. reacting the azine of formula (IV) contained in the ammonia-free medium resulting from (b) with at least two moles of hydrocyanic acid per mole of azine; andD. recovering the hydrazo-bis-acetonitrile of formula (I).
摘要翻译：本发明涉及通式为R1R1 || NC-C-NH-NH-C-CN（Ⅰ）| R2R2的双氢 - 二乙腈制备方法，其中R1和R2具有以下相同的含义，包含：

17. 发明授权

US3972876A Process for the preparation of symmetrical and unsymmetrical azines and mixtures thereof 失效
标题翻译：制备对称和不对称吖嗪及其混合物的方法
公开(公告)号：US3972876A
公开(公告)日：1976-08-03
申请号：US532650
申请日：1974-12-13
申请人： Jean-Pierre Schirmann , Francis Weiss
发明人： Jean-Pierre Schirmann , Francis Weiss
IPC分类号： C07C249/02 , C01B21/16 , C07C20060101 , C07C251/88 , C07C255/45 , C07C109/00
CPC分类号： C07C251/88
摘要： A process is disclosed for the preparation of symmetrical azines of the formulas ##EQU1## and unsymmetrical azines of the formulas ##EQU2## and mixtures of azines (I), (II), and (IV), and (I), (III) and (V), wherein R.sup.1 , R.sup.2, R.sup.3 and R.sup.4 each is hydrogen, a straight-chain alkyl radical of from 1 to 12 carbon atoms, a branched-chain alkyl radical or a cycloalkyl radical of from 3 to 12 carbon atoms or a phenyl radical, the aforesaid radicals being unsubstituted or substituted with a radical which is stable in the medium in which said azines are produced; and in which case R.sup.1 and R.sup.2 can be the same or different radicals, R.sup.3 is a radical different from R.sup.1 and R.sup.2, R.sup.3 and R.sup. 4 are radicals different from each other, and each are different radicals from R.sup.1 and R.sup.2 ; or R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, or R.sup. 3 and R.sup.4 of either or both the >C=N-- moieties together form a cyclic or substituted cyclic radicals of from 3 to 11 carbon atoms in the ring.
摘要翻译：公开了用于制备式R1R1的对称吖嗪的方法。R1 = NN = C ANGLE（I）R2R2 R1R1角度C = NN = C角度（II）R3R3 R3R3角度C = NN = C角度（III）R4R4和（I），（II）和（IV）和（I）的混合物，其中R 1，R 2，R 3，R 3，R 4，，（III）和（V），其中R 1，R 2，R 3和R 4各自为氢，具有1至12个碳原子的直链烷基，支链烷基或环烷基为3至12 碳原子或苯基，上述基团是未被取代的或被在所述制备所述吖嗪的介质中稳定的基团取代; 在这种情况下，R 1和R 2可以是相同或不同的基团，R 3是不同于R 1和R 2的基团，R 3和R 4是彼此不同的基团，并且各自是不同的R 1和R 2基团; 或者R 1和R 2或R 1和R 3或R 3和R 4中的任一个或两个> C = N-部分一起形成环中具有3至11个碳原子的环状或取代的环状基团。

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