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    • 11. 发明授权
    • Fast-writable and precision-writable high-capacity optical storage media
    • 快速写入和精确写入的大容量光存储介质
    • US06849315B2
    • 2005-02-01
    • US10483130
    • 2002-07-04
    • Urs LehmannPeter AeschlimannPeter SutterBeat SchmidhalterJean-Luc BudryHeinz Spahni
    • Urs LehmannPeter AeschlimannPeter SutterBeat SchmidhalterJean-Luc BudryHeinz Spahni
    • B41M5/26C09B11/00C09B11/02C09B11/20C09B11/28C09B45/14C09B45/20C09B55/00C09B69/02G11B7/004G11B7/24G11B7/244G11B7/246G11B7/2467G11B7/249G11B7/253G11B7/254G11B7/2542G11B7/258G11B7/259G11B7/26B32B3/02
    • G11B7/244C09B11/28G11B7/2467G11B7/249G11B7/253G11B7/2542G11B7/259Y10T428/21
    • The invention relates to an optical recording medium, comprising a substrate and a recording layer, wherein the recording layer comprises a compound of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 are each independently of the others hydrogen, G1 or C1-C24alkyl, C2-C24alkenyl, C2-C24alkynyl, C3-C24cycloalkyl, C3-C24cycloalkenyl, C7-C24aralkyl, C6-C24aryl, C4-C12heteroaryl or C1-C12heterocycloalkyl, each unsubstituted or substituted by one or more identical or different substituents G1, wherein R1 and R2, R1 and R13, R2 and R3, R3 and R4, R4 and R5, R5 and R6, R6 and R7, R7 and R8, R8 and R9, R9 and R10, R10 and R11, R11 and R12 and/or R12 and R13 can independently of one another be bonded to one another in pairs separately or, when they contain substitutable sites, via a direct bond or via a —CH2—, —O—, —S—, —NH— or —NC1-C24alkyl-bridge in such a manner that, together with the atoms and bonds indicated in formula (I), five- or six-membered, saturated, unsaturated or aromatic, unsubstituted or G1-substituted rings are formed, G1 is any desired substituent,? xm- is an inorganic, organic organometallic anion, Yn+ is a proton or a metal, ammonium or phosphonium cation, and m and n are each independently of the other a number from 1 to 5, and p and q are each independently of the other O or a number from 0.2 to 6, the ratio of p and q to one another, depending upon m and n and, as applicable, the number of charged G1, being such that in formula (I) there is no excess positive or negative charge. Generally the optical recording medium according to the invention additionally comprises a reflecting layer. The recording media according to the invention exhibit high sensitivity and good playback characteristics, especially at high recording and playback speeds. The light stability is also excellent.
    • 本发明涉及一种光记录介质,包括基片和记录层,其中记录层包括式(I)化合物,其中R1,R2,R3,R4,R5,R6,R7,R8,R9,R10 ,R11,R12和R13各自独立地为氢,G1或C1-C24烷基,C2-C24链烯基,C2-C24炔基,C3-C24环烷基,C3-C24环烯基,C7-C24芳烷基,C6-C24芳基,C4-C12杂芳基或C1- C 1 -C 6杂环烷基,每个未取代或被一个或多个相同或不同的取代基G1取代,其中R1和R2,R1和R13,R2和R3,R3和R4,R4和R5,R5和R6,R6和R7,R7和R8,R8 并且R 9,R 9和R 10,R 10和R 11,R 11和R 12和/或R 12和R 13可以彼此独立地彼此相互键合,或者当它们含有可取代的位置时,经由直接键或通过-CH 2 - ,-O - , - S - , - NH-或-NCl-C24烷基 - 桥,其与式(I)中所示的原子和键一起为五或六元饱和, 形成不饱和或芳族,未取代或者G1取代的环,G1是a
    • 12. 发明申请
    • Writable high-capacity optical storage media containing metal complexes
    • 包含金属络合物的可写入大容量光存储介质
    • US20050008974A1
    • 2005-01-13
    • US10495678
    • 2002-11-07
    • Colin MortonTaher YousafJean-Luc BudryBeat SchmidhalterHeinz Spahni
    • Colin MortonTaher YousafJean-Luc BudryBeat SchmidhalterHeinz Spahni
    • B41M5/26C07D487/22C07F15/02G11B7/004G11B7/24G11B7/244G11B7/248G11B7/253G11B7/26C09B47/04
    • C07D487/22G11B7/248
    • The invention relates to an optical recording medium comprising a substrate and a recording layer, wherein the recording layer comprises a complex of formula (I), or wherein Q2 is a ligand of formula (II), or a tautomer thereof, and R1, R2, R3, R4, R5, R6, R7, and R8 are each dependently of the others H, halogen, cyano, COOR9, CONHR9, CONR9R10, R9, OR9, SR9, NHR9 or NR9R10, wherein R9 and R10 are each independently of the other C6-C10aryl, C4-C9heteroaryl or linear or branched C1-C24alkyl, C3-C24cycloallyl, C2-C24alkenyl, C3-C24cycloalkenyl, C2-C24alkynyl, C1-C12heterocycloalkyl, C1-C12heterocycloalkenyl, unsubstituted or substituted, it also being possible for R1 and R2, R3 and R4, R5 and R6, and R7 and R8, independently of one another, to be bonded by a direct bond or via a bridge O or S, Mm+ is a transition metal cation having 5 or 6 electrons in the outermost occupied d-shell, L1 is a ligand having a sub-structure N—C, P—C or As—C, L2, independently of L1, is a further ligand containing at least one hetero atom N, P, As, O, S, Se or Te, L3− is CN−, SCN−, NCS−, OCN−, NCO−, N3—, L1-O−, L1-S—, L1-CO2−, L1-S03− or L1-P03−, L4−, independently of L3−, is CN−, SCN−, NCS−, OCN−, NCO−, N3−, L3-O−, L3-S−, L3-CO2− L3-SO3− or L3-PO3−, p and q are each independently of the other a number 0 or 1 (formula III), are each a counter-ion, m is a number 1, 2, 3 or 4 equal to the positive charge in Mm+ and n is a number −2, −1, +1 or +2, so that the quotient (formula IV) is not negative. Amorphous solid layers having excellent optical properties are obtained.
    • 本发明涉及一种包括基材和记录层的光学记录介质,其中记录层包含式(I)的配合物,或其中Q 2是式(II)的配体或其互变异构体,和 R1,R2,R3,R4,R5,R6,R7和R8各自独立地为H,卤素,氰基,COOR9,CONHR9,CONR9R10,R9,OR9,SR9,NHR9或NR9R10,其中R9和R10各自 独立于其它C 6 -C 10芳基,C 4 -C 9杂芳基或直链或支链C 1 -C 24烷基,C 3 -C 24环烯基,C 2 -C 24烯基,C 3 -C 24环烯基,C 2 -C 24炔基,C 1 -C 12杂环烷基,未取代或取代的C 1 -C 12杂环烯基, R 1和R 2,R 3和R 4,R 5和R 6以及R 7和R 8彼此独立地可以通过直接键合或通过桥O或S键合,M m是具有5个碳原子的过渡金属阳离子 或6个电子,L1是具有子结构NC,PC或As-C,L2的配体,独立于L1,是另一个配体c 保持至少一个杂原子N,P,As,O,S,Se或Te,L3 - 是CN - ,SCN - ,NCS - ,OCN - ,NCO - , - N3-,L1-O - ,L1-S-,L
    • 17. 发明授权
    • High-capacity storage media
    • 大容量存储介质
    • US5851621A
    • 1998-12-22
    • US842292
    • 1997-04-23
    • Heinz WollebBeat SchmidhalterJean-Luc Budry
    • Heinz WollebBeat SchmidhalterJean-Luc Budry
    • B41M5/26C07D311/82C07D491/16C09B11/28G11B7/244G11B7/246G11B7/249G11B7/253G11B7/2534G11B7/258B32B3/00
    • G11B7/246C09B11/28G11B7/249G11B7/253G11B7/258G11B7/2534Y10S428/913Y10S430/146Y10T428/21Y10T428/31678
    • The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, which recording layer consists essentially of a dye of the formula (I), ##STR1## in which R.sub.1 and R.sub.6 are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, aralkyl or aryl, R.sub.6 and R.sub.7 are unsubstituted or substituted alkyl, alkenyl, alkynyl, aralky or aryl, R.sub.3, R.sub.4, R.sub.8 and R.sub.9 are hydrogen, halogen, OR.sub.17, SR.sub.17, NR.sub.18 R.sub.19, NO.sub.2, alkyl, alkenyl or Alkynyl, R.sub.5 and R.sub.10 are hydrogen, halogen, OR.sub.17, SR.sub.17, NO.sub.2, NR.sub.18 R.sub.19 or unsubstituted or substituted alkyl, alkenyl, alkynyl or aralkyl, and R.sub.11 is hydrogen, (CH.sub.2).sub.1-10 COO.sup.-, (CH.sub.2).sub.1-10 COOR.sub.24, alkyl, alkenyl, alkynyl or unsubstituted or substituted aralkyl or aryl; Y is the anion of an inorganic, organic or organometallic acid, Z is a metal cation, ammonium cation or phosphonium cation, m, n and o are from 1 to 3, and p and q are from 0 to 4; and the stoichiometry of o, p and q is such as not to result in any excess positive or negative charge in the formula (I). The substituents can, if desired, be connected to one another in such a way, via a direct bond or via a bridge --O-- or --NR.sub.12 --, as to form additional five- or six-membered rings. The novel recording media are of high sensitivity and have good reproduction characteristics.
    • 本发明涉及一种光记录介质,其包括基板,反射层和记录层,该记录层基本上由式(I)的染料,其中R 1和R 6为氢或未取代的 或取代的烷基,烯基,炔基,芳烷基或芳基,R6和R7是未取代的或取代的烷基,烯基,炔基,芳基或芳基,R3,R4,R8和R9分别是氢,卤素,OR17,SR17,NR18R19, ,烯基或炔基,R 5和R 10是氢,卤素,OR 17,SR 17,NO 2,NR 18 R 19或未取代或取代的烷基,烯基,炔基或芳烷基,R 11是氢,(CH 2)1-10 COO-,(CH 2) 烷基,烯基,炔基或未取代或取代的芳烷基或芳基; Y是无机,有机或有机金属酸的阴离子,Z是金属阳离子,铵阳离子或鏻阳离子,m,n和o为1至3,p和q为0至4; 并且o,p和q的化学计量比如在式(I)中不会导致任何过量的正电荷或负电荷。 如果需要,取代基可以以这样的方式通过直接键或通过桥-O-或-NR 12 - 彼此连接,形成另外的五元或六元环。 该新颖的记录介质具有高灵敏度和良好的再生特性。