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    • 11. 发明授权
    • Radiation-sensitive recording material for the production of
planographic printing plates
    • 用于生产平版印刷版的辐射敏感记录材料
    • US5998084A
    • 1999-12-07
    • US749854
    • 1996-11-15
    • Andreas ElsaesserRaimund HaasGuenter HultzschPeter LehmannRudolf NeubauerRudolf Zertani
    • Andreas ElsaesserRaimund HaasGuenter HultzschPeter LehmannRudolf NeubauerRudolf Zertani
    • G03F7/004B41N1/14B41N3/03G03F7/00G03F7/022G03F7/023G03F7/075G03F7/30
    • B41N3/038G03F7/0226
    • A positive-working, radiation-sensitive recording material capable of being used for the production of planographic printing plates, comprising: an aluminum support and a radiation-sensitive layer coated thereon, whereinthe aluminum support has been grained in nitric acid, then cleaned in sulfuric acid, anodized in sulfuric acid, and subsequently hydrophilized with a compound comprising at least one unit with a phosphonic acid or phosphonate group; andthe radiation-sensitive layer comprisesa) a radiation-sensitive 1,2-naphthoquinone-2-diazide-4- or -5-sulfonic acid ester of a polycondensate having phenolic hydroxy groups, said polycondensate being obtained by reacting a phenolic compound with an aldehyde or ketone,b) a novolak or a polycondensation product obtained by reacting a polyphenol with an aldehyde or ketone, as an alkali-soluble resin,c) a vinyl-type polymer comprising at least one unit having a lateral hydroxyphenyl group,d) a clathrate-forming compound,e) a low-molecular weight compound which comprises at least one acidic hydrogen atom, andf) silica gel particles having a maximum diameter of 15 .mu.m.
    • 能够用于生产平版印刷版的正面工作的辐射敏感记录材料,包括:铝载体和涂覆在其上的辐射敏感层,其中铝载体已经在硝酸中粒化,然后在 硫酸,在硫酸中阳极氧化,随后用包含至少一个具有膦酸或膦酸酯基团的单元的化合物亲水化; 辐射敏感层包括a)具有酚羟基的缩聚物的辐射敏感的1,2-萘醌-2-二叠氮化物-4-或-5-磺酸酯,所述缩聚物是通过使酚类化合物与 醛或酮,b)通过使多酚与醛或酮反应得到的酚醛清漆或缩聚产物作为碱溶性树脂,c)包含至少一个具有侧羟基苯基单元的乙烯基型聚合物,d )包合物形成化合物,e)包含至少一个酸性氢原子的低分子量化合物,和f)最大直径为15μm的硅胶颗粒。