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11. 发明授权

US06911485B1 Anionic and Lewis base photopolymerization process and its use for making optical articles 失效
标题翻译：阴离子和路易斯碱光聚合方法及其制备光学制品的用途
公开(公告)号：US06911485B1
公开(公告)日：2005-06-28
申请号：US10126572
申请日：2002-04-19
申请人： Charles R. Kutal , Sirisoma Wanigatunga , Gabriel Keita , Yassin Turshani
发明人： Charles R. Kutal , Sirisoma Wanigatunga , Gabriel Keita , Yassin Turshani
IPC分类号： C08F2/50 , C08F2/48 , C08F4/52 , C08F4/78 , G03C1/735 , G03F7/029
CPC分类号： C08F2/50
摘要： The invention relates to a process for polymerising a monomer, polymerizing and/or crosslinking a oligomer, or crosslinking a polymer or copolymer, said monomer, oligomer, polymer and copolymer being selected among precursor monomers, urethane, thiourethane and episulfide oligomers, and urethane, thiourethane and episulfide polymers and copolymers, which comprises: (a) adding to precursor monomers or oligomers or polymers or copolymers an effective amount of at least one complex of Co, Mo or W which under irradiation conditions photochemically reacts to release at least one anionically charged nucleophile or uncharged Lewis base; and (b) irridiating the mixture of (a) to release the at least one anionically charged nucleophile or uncharged Lewis base to initiate polymerisation and/or crosslinking of the monomer, oligomer, polymer or copolymer.
摘要翻译：本发明涉及聚合单体，聚合和/或交联低聚物或交联聚合物或共聚物的方法，所述单体，低聚物，聚合物和共聚物选自前体单体，氨基甲酸酯，硫代氨基甲酸酯和环硫化物低聚物，以及聚氨酯，硫代氨基甲酸酯和环硫化物聚合物和共聚物，其包括：（a）向前体单体或低聚物或聚合物或共聚物添加有效量的至少一种Co，Mo或W的复合物，其在照射条件下光化学反应以释放至少一个阴离子充电亲核或不带电的路易斯碱; 和（b）将（a）的混合物冲洗以释放至少一个带阴离子电荷的亲核试剂或不带电的路易斯碱以引发单体，低聚物，聚合物或共聚物的聚合和/或交联。

12. 发明申请

US20050093187A1 Methods relating to molding optical lenses 有权
标题翻译：关于模制光学透镜的方法
公开(公告)号：US20050093187A1
公开(公告)日：2005-05-05
申请号：US10696503
申请日：2003-10-29
申请人： Gabriel Keita , Joseph Boryslawski
发明人： Gabriel Keita , Joseph Boryslawski
IPC分类号： B29C31/04 , B29C33/00 , B29C39/24 , B29C41/04 , B29D11/00 , G01N3/00 , G01N33/44
CPC分类号： B29C39/42 , B29C31/04 , B29C33/0038 , B29C39/006 , B29C39/24 , B29C39/26 , B29C41/04 , B29D11/00 , B29D11/00413 , B29D11/00528 , B29D11/00538 , B29L2011/0016 , B29L2011/0041
摘要： A method that includes providing a cavity defined by at least a portion of a mold and a closure member attached to the portion of the mold, the portion of the mold being oriented vertically and having a top and a bottom, and a sealing material being positioned near the bottom and attached to the closure member; puncturing the sealing material and the closure member with an instrument near the bottom, the puncturing creating an opening in the sealing material; and introducing a polymerizable composition into the cavity through the instrument. A method useful in testing sealing materials. Other methods are also disclosed.
摘要翻译：一种方法，其包括提供由模具的至少一部分和附接到所述模具的所述部分的封闭构件限定的空腔，所述模具的所述部分垂直取向并具有顶部和底部，以及密封材料被定位靠近底部并附接到封闭构件; 用靠近底部的器具刺穿密封材料和封闭构件，刺穿在密封材料中形成开口; 并通过仪器将可聚合组合物引入空腔。一种用于测试密封材料的方法。还公开了其它方法。

13. 发明授权

US07820085B2 Methods relating to molding optical lenses 有权
标题翻译：关于模制光学透镜的方法
公开(公告)号：US07820085B2
公开(公告)日：2010-10-26
申请号：US10696503
申请日：2003-10-29
申请人： Gabriel Keita , Joseph Boryslawski
发明人： Gabriel Keita , Joseph Boryslawski
IPC分类号： B29C35/00 , B29D11/00
CPC分类号： B29C39/42 , B29C31/04 , B29C33/0038 , B29C39/006 , B29C39/24 , B29C39/26 , B29C41/04 , B29D11/00 , B29D11/00413 , B29D11/00528 , B29D11/00538 , B29L2011/0016 , B29L2011/0041
摘要： A method that includes providing a cavity defined by at least a portion of a mold and a closure member attached to the portion of the mold, the portion of the mold being oriented vertically and having a top and a bottom, and a sealing material being positioned near the bottom and attached to the closure member; puncturing the sealing material and the closure member with an instrument near the bottom, the puncturing creating an opening in the sealing material; and introducing a polymerizable composition into the cavity through the instrument. A method useful in testing sealing materials. Other methods are also disclosed.
摘要翻译：一种方法，其包括提供由模具的至少一部分和附接到所述模具的所述部分的封闭构件限定的空腔，所述模具的所述部分垂直取向并具有顶部和底部，以及密封材料被定位靠近底部并附接到封闭构件; 用靠近底部的器具刺穿密封材料和封闭构件，刺穿在密封材料中形成开口; 并通过仪器将可聚合组合物引入空腔。一种用于测试密封材料的方法。还公开了其它方法。

14. 发明申请

US20050203200A1 Anionic and Lewis base photopolymerization process and its use for making optical articles 失效
标题翻译：阴离子和路易斯碱光聚合方法及其制备光学制品的用途
公开(公告)号：US20050203200A1
公开(公告)日：2005-09-15
申请号：US11114753
申请日：2005-04-26
申请人： Charles Kutal , Sirisoma Wanigatunga , Gabriel Keita , Yassin Turshani
发明人： Charles Kutal , Sirisoma Wanigatunga , Gabriel Keita , Yassin Turshani
IPC分类号： C08F2/50 , C08J3/00
CPC分类号： C08F2/50
摘要： The invention relates to a process for polymerising a monomer, polymerizing and/or crosslinking an oligomer, or crosslinking a polymer or copolymer, said monomer, oligomer, polymer and copolymer being selected among precursor monomers, urethane, thiourethane and episulfide oligomers, and urethane, thiourethane and episulfide polymers and copolymers, which comprises: (a) adding to precursor monomers or oligomers or polymers or copolymers an effective amount of at least one complex of Co, Mo or W which under irradiation conditions photochemically reacts to release at least one anionically charged nucleophile or uncharged Lewis base; and (b) irradiating the mixture of (a) to release the at least one anionically charged nucleophile or uncharged Lewis base to initiate polymerisation and/or crosslinking of the monomer, oligomer, polymer or copolymer.
摘要翻译：本发明涉及聚合单体，聚合和/或交联低聚物或交联聚合物或共聚物的方法，所述单体，低聚物，聚合物和共聚物选自前体单体，氨基甲酸酯，硫代氨基甲酸酯和环硫化物低聚物，以及聚氨酯，硫代氨基甲酸酯和环硫化物聚合物和共聚物，其包括：（a）向前体单体或低聚物或聚合物或共聚物添加有效量的至少一种Co，Mo或W的复合物，其在照射条件下光化学反应以释放至少一个阴离子充电亲核或不带电的路易斯碱; 和（b）照射（a）的混合物以释放至少一个带阴离子电荷的亲核试剂或不带电的路易斯碱以引发单体，低聚物，聚合物或共聚物的聚合和/或交联。

15. 发明授权

US5973098A Polymerizable compositions for making thio containing resins including a thiocyanate salt catalyst and process for making thio containing resin articles 失效
标题翻译：用于制备包含硫氰酸盐催化剂的含硫树脂和用于制备含硫树脂制品的方法的可聚合组合物
公开(公告)号：US5973098A
公开(公告)日：1999-10-26
申请号：US182577
申请日：1998-10-29
申请人： Gabriel Keita , Pamela Anne McClimans , Steve Weber , Yassin Turshani
发明人： Gabriel Keita , Pamela Anne McClimans , Steve Weber , Yassin Turshani
IPC分类号： C08G18/08 , C08G18/22 , C08G18/38 , C08G18/00 , C08G18/06 , C08G18/16
CPC分类号： C08G18/3876 , C08G18/0852 , C08G18/225 , C08G18/3868
摘要： The polymerizable compositions compriseA) at least one polyiso(thio)cyanate monomer, and at least one polythiol monomer; or at least one episulfide compound and optionally one or more compounds having two or more functional groups capable of reacting with episulfide groups; andB) an effective amount of a thiocyanate salt as a polymerization catalyst.Application to the fabrication of optical articles, such as lenses.
摘要翻译：可聚合组合物包含A）至少一种多异（硫代）氰酸酯单体和至少一种多硫醇单体; 或至少一种环硫化合物和任选的一种或多种具有两个或更多个能够与环硫基反应的官能团的化合物; 和B）有效量的硫氰酸盐作为聚合催化剂。适用于光学制品如镜片的制造。

16. 发明授权

US5545828A Low yellow index polymer compositions, polymerizable compositions and lenses using said compositions 失效
标题翻译：使用所述组合物的低黄色指数聚合物组合物，可聚合组合物和透镜
公开(公告)号：US5545828A
公开(公告)日：1996-08-13
申请号：US374378
申请日：1995-01-18
申请人： Gabriel Keita , Joel Renaudineau
发明人： Gabriel Keita , Joel Renaudineau
IPC分类号： C08F220/30 , G02B1/04 , C08F232/04
CPC分类号： C08F220/30 , G02B1/041
摘要： The present invention relates to new polymer compositions for use in the manufacture of opthalmic lenses which result from the copolymerization of a component (A) comprising at least 50% by weight of a monomer or mixture having formula ##STR1## wherein R.sub.1 and R.sub.2 are selected from H and C.sub.1 -C.sub.6 alkyl radical,X is --O--, --S--, --SO.sub.2, --CO--, --CH.sub.2 --, --CH.dbd.CH--, or C(CH.sub.3).sub.2,m and n are integers and m+n ranging from 0 to 10 and 0,5 to 15% by weight of a component (B) comprising a monomer having an ethylenic unsaturation which does not contribute to an aromatic system and having a free hydroxy group in position .alpha. of the unsaturation, as well as to their use in opthalmology and to apparatus using these lenses, such as eyepieces and film/video camera optics.
摘要翻译：本发明涉及用于制造眼用透镜的新型聚合物组合物，其由包含至少50重量％的具有式（I）+ TR（I））的单体或混合物的组分（A）其中R1和R2选自H和C1-C6烷基，X是-O - ， - S - ， - SO2，-CO-，-CH2 - ， - CH = CH-或C（CH3）2 ，m和n为整数，m + n为0至10,0.5至15重量％的组分（B），其包含不对芳族体系有贡献且具有游离羟基的具有烯属不饱和度的单体在不饱和位置的α位，以及它们在眼科学中的使用以及使用这些透镜的装置，例如目镜和胶片/摄像机光学元件。

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