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11. 发明授权

US5817592A Process for the preparation of a hydrogenation catalyst 失效
标题翻译：制备氢化催化剂的方法
公开(公告)号：US5817592A
公开(公告)日：1998-10-06
申请号：US590455
申请日：1996-01-23
申请人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
IPC分类号： B01J23/42 , B01J23/96 , B01J37/16 , B01J38/64 , C01B21/14 , B01J21/18 , B01J23/16 , B01J27/185
CPC分类号： B01J23/42 , B01J37/16 , C01B21/1418
摘要： A process for the preparation of a hydrogenation catalyst by reduction of platinum in an oxidation stage of not less than 2 in an aqueous medium in the presence of a carboniferous support, optionally following partial poisoning with a sulfur, arsenic, tellurium, or antimony-containing compound, using a reducing agent, in which the reducing agent used is an ammonium or phosphonium salt of the general formula I �XR.sup.4 !.sub.n Y I in which X stands for N or P, R stands for hydrogen, C.sub.1 --C.sub.18 alkyl, C.sub.5 --C.sub.10 cycloalkyl, phenyl radical, and also a C.sub.1 --C.sub.4 alkyl radical substituted by phenyl, the phenyl radicals being mono-to tri-substituted by C.sub.1 --C.sub.6 alkyl, halogen, nitro or amino, if desired, provided that the radicals R may be the same or different but cannot simultaneously denote hydrogen, if X is P, n is an integer of 1 to 3, and Y is an organic anion which can reduce platinum in an oxidation stage other than zero to platinum in the oxidation stage of zero.
摘要翻译：一种通过在含水载体的存在下在水性介质中在不少于2的氧化阶段还原铂的氢化催化剂的方法，任选地在用硫，砷，碲或含锑的部分中毒后化合物，使用还原剂，其中所用的还原剂是通式I [XR4] nYinin的铵盐或鏻盐，其中X代表N或P，R代表氢，C1-C18烷基，C5-C10环烷基苯基，以及被苯基取代的C1-C4烷基，如果需要，苯基由C1-C6烷基，卤素，硝基或氨基单取代至三取代，条件是基团R可以相同或不同，但不能同时表示氢，如果X为P，n为1至3的整数，Y为有机阴离子，在氧化阶段为零的情况下，铂可以在除氧以外的氧化阶段中还原为铂。

12. 发明授权

US4550195A Manufacture of pent-3-enoic acid and its alkyl esters 失效
标题翻译：戊-3-烯酸及其烷基酯的制备
公开(公告)号：US4550195A
公开(公告)日：1985-10-29
申请号：US295088
申请日：1981-08-21
申请人： Rolf Platz , Rudolf Kummer , Heinz-Walter Schneider , Kurt Schwirten
发明人： Rolf Platz , Rudolf Kummer , Heinz-Walter Schneider , Kurt Schwirten
IPC分类号： C07C69/533 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/14 , C07C57/03 , C07C67/00 , C07C67/38
CPC分类号： C07C51/14
摘要： A process for the manufacture of pent-3-enoic acid and its alkyl esters, of the general formulaCH.sub.3 --CH.dbd.CH--CH.sub.2 --CO--ORwhere R is hydrogen or alkyl of 1 to 4 carbon atoms, comprising carbonylating butadiene with carbon monoxide and a compound ROH at from 300 to 1,000 bars CO pressure and from 100.degree. to 160.degree. C. in the presence of cobalt catalysts and nitrogen bases, wherein C.sub.4 cuts are used as starting materials and a tertiary amine having a pK.sub.A of from 3 to 11 is used as the nitrogen base. The pent-3-enoic acid or alkyl esters produced may be used for the manufacture of adipic acid or its alkyl esters, which compounds are starting materials for the manufacture of nylons.
摘要翻译：制备通式为CH 3 -CH = CH-CH 2 -CO-OR的戊-3-烯酸及其烷基酯的方法，其中R是氢或1至4个碳原子的烷基，其包括将碳酸丁二烯与碳在钴催化剂和氮碱的存在下，在300至1,000巴CO压力和100至160℃下进行一氧化碳和化合物ROH，其中使用C4馏分作为起始原料，并使用pKA为3的叔胺至11为氮基。所制备的戊-3-烯酸或烷基酯可用于制造己二酸或其烷基酯，该化合物是用于制造尼龙的起始原料。

13. 发明授权

US07056356B2 Process for producing crystals 失效
标题翻译：晶体生产工艺
公开(公告)号：US07056356B2
公开(公告)日：2006-06-06
申请号：US10296442
申请日：2001-05-21
申请人： Peter Mark Allen , Christoph Gahn , Christopher William Rieker , Heinz-Walter Schneider , Robert Wagner
发明人： Peter Mark Allen , Christoph Gahn , Christopher William Rieker , Heinz-Walter Schneider , Robert Wagner
IPC分类号： B01D9/00
CPC分类号： B01D9/0022 , B01D9/0031 , B01D9/0036 , B01D9/0059
摘要： An apparatus and a process for crystallizing substances from solutions or dispersions containing these substances, in a crystallizer containing a classifying zone (3), comprise a) an inner and an outer circulation system (1; 2), the inner circulation system (1) being present in the crystallizer, the inlet of the outer circulation system (2) being connected to the inner circulation system (1) via the classifying zone (3), the outer circulation system, being present outside the crystallizer, the outlet of the outer circulation system (2) being connected to the inner circulation system (1) of the crystallizer, and a means for dissolving crystals being arranged in the outer circulation system (2), before its outlet, b) an inflow (4) for solution and/or dispersion, which inflow is present on the crystallizer or on the outer circulation system, and c) an outflow (5) for dispersions, which outflow is arranged on the crystallizer or on the outer circulation system. The novel apparatus has the special feature that a line (8) connecting the outer and inner circulation systems (1; 2) to one another and intended for transporting (recycling) dispersion and/or a line (8) for transporting (recycling) dispersion are additionally present, in which both its entrance and its exit are connected to the inner circulation system (1).
摘要翻译：一种用于在含有分级区（3）的结晶器中使含有这些物质的溶液或分散液中的物质结晶的装置和方法包括：a）内循环系统（1; 2），内循环系统（1）存在于结晶器中，外循环系统（2）的入口经由分级区（3）连接到内循环系统（1），外循环系统存在于结晶器外部，外部出口循环系统（2）连接到结晶器的内循环系统（1），以及用于溶解布置在外循环系统（2）中的晶体在其出口之前的装置，b）用于溶液的流入物（4） /或分散体，其流入存在于结晶器或外循环系统上，以及c）用于分散体的流出物（5），该流出物布置在结晶器或外循环系统上。该新型装置的特征在于，将外部和内部循环系统（1; 2）彼此连接并用于运输（再循环）分散体和/或用于运输（再循环）分散体的管线（8）的管线（8）另外存在，其入口和出口都连接到内循环系统（1）。

14. 发明授权

US5189182A Preparation of 5-methylbutyrolactone 失效
标题翻译： 5-甲基丁酰胺的制备
公开(公告)号：US5189182A
公开(公告)日：1993-02-23
申请号：US236199
申请日：1988-08-25
申请人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： 5-Methylbutyrolactone is prepared by a process in which a pentenoic ester of the formula IX--CO.sub.2 R (I),where X is CH.sub.2 .dbd.CH--CH.sub.2 --CH.sub.2 --, CH.sub.3 --CH.dbd.CH--CH.sub.2 -- or CH.sub.3 --CH.sub.2 --CH.dbd.CH-- and R is alkyl, cycloalkyl, aralkyl or aryl, or a mixture of these esters is reacted with water at from 50.degree. to 350.degree. C. in the presence or absence of a diluenta) over a zeolite and/or phosphate catalyst orb) in the presence of from 0.01 to 0.25 mole of a sulfonic acid, a Lewis acid and/or a non-oxidizing mineral acid per mole of pentenoic ester or over from 0.1 to 40% by weight, based on the pentenoic ester, of a strongly acidic ion exchanger as a catalyst in a first stage, or the pentenoic ester of the formula I, where X and R have the stated meanings, is hydrolyzed in a first stage with the aid of a strongly acidic ion exchanger as a catalyst to give the pentenoic acid of the formula I, where R is hydrogen, and the resulting pentenoic acid is subjected to cyclization in a second stage in the presence of from 0.005 to 0.1 mole of a sulfonic acid, a Lewis acid or a non-oxidizing mineral acid per mole of pentenoic acid or over from 0.1 to 20% by weight, based on the pentenoic acid, of a strongly acidic ion exchanger at from 50.degree. to 350.degree. C.
摘要翻译：通过以下方法制备5-甲基丁内酯，其中式I X-CO 2 R（I）的戊烯酸酯，其中X为CH 2 = CH-CH 2 -CH 2 - ，CH 3 -CH = CH-CH 2 - 或CH 3 -CH 2 -CH = CH-和R是烷基，环烷基，芳烷基或芳基，或这些酯的混合物与水在50-350℃下在存在或不存在稀释剂a）的情况下与沸石和/或磷酸盐催化剂或b）在0.01至0.25摩尔磺酸，路易斯酸和/或非氧化性无机酸/摩尔烯酸酯存在下或基于戊烯酸酯为0.1至40重量％的作为第一阶段的催化剂的强酸性离子交换剂或其中X和R具有所述含义的式I的戊烯酸在第一阶段中借助于强酸性离子交换剂作为催化剂得到式I的戊烯酸，其中R是氢，所得戊烯酸在第二阶段中在0.005t的存在下进行环化 o 0.1摩尔磺酸，路易斯酸或非氧化性无机酸/摩尔烯酸，或超过0.1-20重量％，基于戊烯酸，强酸性离子交换剂为50〜 350℃

15. 发明授权

US5003102A Preparation of 5-formylvaleric esters 失效
标题翻译： 5-甲酰戊酸酯的制备
公开(公告)号：US5003102A
公开(公告)日：1991-03-26
申请号：US206751
申请日：1988-06-15
申请人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
发明人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
IPC分类号： C07B61/00 , C07C67/313 , C07C69/66 , C07C69/67
CPC分类号： C07C67/347
摘要： 5-Formylvaleric esters are prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a carbonyl complex of a metal of group 8 of the Periodic Table with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) Isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) Cleavage of the mixture essentially consisting of 4- and 3-formylvaleric esters at from 50.degree. to 400.degree. C. in the presence of a catalyst to give pentenoic esters and(d) Recycling of the pentenoic esters to stage (a).
摘要翻译： 5-甲酰戊酸酯通过包括以下步骤的方法制备：（a）在升高的温度和超大气压下，在第8组的金属的羰基络合物存在下，通过与一氧化碳和氢气反应来进行戊烯基酯的加氢甲酰化的化合物，形成5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离5-甲酰基戊酸酯，基本上由4-和3-甲酰基戊酸酯组成，（c）在催化剂存在下，在50-400℃下将基本上由4-和3-甲酰基戊酸酯组成的混合物切割，得到戊烯酸酯和（d ）将戊烯酸酯循环回到（a）阶段。

16. 发明授权

US4801738A Preparation of .delta.-formylvalerates 失效
标题翻译：三甲酸戊酯的制备
公开(公告)号：US4801738A
公开(公告)日：1989-01-31
申请号：US608460
申请日：1984-05-09
申请人： Heinz-Walter Schneider , Rudolf Kummer , Volker Taglieber
发明人： Heinz-Walter Schneider , Rudolf Kummer , Volker Taglieber
IPC分类号： C07C67/313 , B01J29/12 , B01J31/00 , B01J31/20 , C07B61/00 , C07C67/333 , C07C67/38 , C07C69/67
CPC分类号： C07C67/347
摘要： .delta.-Formylvalerates are prepared by a process wherein a 3-pentenoate is treated with an isomerization catalyst at elevated temperatures and a 4-pentenoate is distilled off, and the resulting 4-pentenoate is reacted with carbon monoxide and hydrogen at from 80 to 160.degree. C. under from 1 to 30 bar in the presence of a rhodium carbonyl complex which has been modified with tertiary organic phosphines or phosphites.
摘要翻译： δ-甲酸戊酯通过其中3-异戊烯酸酯在高温下用异构化催化剂处理并蒸馏除去4-戊烯酸酯的方法制备，所得4-戊烯酸酯与一氧化碳和氢气在80至160℃下反应。在1至30巴下，在用叔有机膦或亚磷酸酯改性的羰基铑络合物的存在下。

17. 发明授权

US4561942A Isolation of methyl 4-pentenoate from mixtures containing this and methyl 3-pentenoate 失效
标题翻译：从含有此和3-戊烯酸甲酯的混合物中分离4-戊烯酸甲酯
公开(公告)号：US4561942A
公开(公告)日：1985-12-31
申请号：US717108
申请日：1985-03-28
申请人： Heinz-Walter Schneider , Rudolf Kummer , Dieter Zimmerling
发明人： Heinz-Walter Schneider , Rudolf Kummer , Dieter Zimmerling
IPC分类号： C07C67/54 , C07C69/533 , B01D3/36
CPC分类号： C07C67/54
摘要： Methyl 4-pentenoate is isolated from mixtures containing this and methyl 3-pentenoate by a process in which from 0.25 to 0.4 part by weight of water is added per part by weight of methyl 4-pentenoate, and the azeotrope of methyl 4-pentenoate and water is distilled off.
摘要翻译： 4-戊烯酸甲酯由含有该戊烯酸甲酯和3-戊烯酸甲酯的混合物中分离，其中每重量份4-戊烯酸甲酯中加入0.25至0.4重量份的水，以及4-戊烯酸甲酯的共沸物和水被蒸馏掉。

18. 发明授权

US5554353A Preparation of hydroxylammonium salts 失效
标题翻译：羟基铵盐的制备
公开(公告)号：US5554353A
公开(公告)日：1996-09-10
申请号：US384321
申请日：1995-02-01
申请人： Heinz-Walter Schneider , Axel Wilms , R udiger Schmitz , Robert Schulz , Klaus Michelsen
发明人： Heinz-Walter Schneider , Axel Wilms , R udiger Schmitz , Robert Schulz , Klaus Michelsen
IPC分类号： C01C1/28 , B01J23/42 , C01B21/14 , C01B21/20
CPC分类号： C01B21/1418
摘要： A process for the preparation of hydroxylammonium salts by catalytic reduction of nitrogen monoxide using hydrogen in the presence of a hydrogenation catalyst, comprises(a) in a first step, filtering the reaction mixture obtained after the reaction, giving a solution of essentially hydroxylammonium salt and a filter residue essentially comprising a mixture of hydrogenation catalyst and a solution of essentially hydroxylammonium salt, and(b) in a second step, subjecting the filter residue to a further separation process in order to concentrate the hydrogenation catalyst, giving a mixture having a higher concentration of hydrogenation catalyst than the filter residue and a mixture having a lower concentration of hydrogenation catalyst than the filter residue.
摘要翻译：在氢化催化剂存在下通过使用氢气催化还原一氧化氮制备羟基铵盐的方法包括（a）在第一步骤中，过滤反应后获得的反应混合物，得到基本上羟基铵盐的溶液和基本上包含氢化催化剂和基本上羟基铵盐的溶液的混合物的过滤残余物，和（b）在第二步中，将过滤残余物进行进一步的分离过程以浓缩氢化催化剂，得到具有较高氢化催化剂的浓度比过滤残渣和氢化催化剂浓度低于过滤残渣的混合物。

19. 发明授权

US4730041A Preparation of .epsilon.-caprolactams 失效
标题翻译： ε-己内酰胺的制备
公开(公告)号：US4730041A
公开(公告)日：1988-03-08
申请号：US7789
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
IPC分类号： B01J23/74 , B01J23/78 , B01J25/00 , C07B61/00 , C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) a 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as a solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture and(c) the reaction mixture thus obtained is heated to 150.degree.-250.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译：己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在烷醇作为溶剂的存在下和氢化催化剂的存在下在超大气压下在40℃的液相中反应至130℃，（b）从反应混合物中分离出过量的氨和氢，（c）将所得反应混合物加热至150-250℃，得到ε-己内酰胺。

20. 发明授权

US4529815A Preparation of 4-pentenoates 失效
标题翻译： 4-戊烯酸酯的制备
公开(公告)号：US4529815A
公开(公告)日：1985-07-16
申请号：US608459
申请日：1984-05-09
申请人： Heinz-Walter Schneider , Rudolf Kummer
发明人： Heinz-Walter Schneider , Rudolf Kummer
IPC分类号： B01J29/00 , B01J29/06 , B01J31/00 , B01J31/26 , C07B61/00 , C07C67/333 , C07C69/533
CPC分类号： C07C67/333
摘要： 4-Pentenoates are prepared by isomerization of isomeric pentenoates in the presence of a catalyst, by a process in which isomeric pentenoates are treated at elevated temperatures with an acidic ion exchanger or acidic zeolite which contains a noble metal of group eight of the periodic table, and the 4-pentenoate is distilled off from the reaction mixture.
摘要翻译：通过在酸性离子交换剂或包含元素周期表第八族的贵金属的酸性沸石的高温下处理异构戊烯酸酯的方法，在催化剂存在下异构戊烯酸酯制备4-戊烯酸酯，并从反应混合物中蒸馏出4-戊烯酸酯。

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