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    • 18. 发明授权
    • Method for producing single-phase, incongruently melting intermetallic
phases
    • 生产单相,不熔融金属间相的方法
    • US5354354A
    • 1994-10-11
    • US955952
    • 1992-10-02
    • Martin EdelingHorst EggertMichael Steinhorst
    • Martin EdelingHorst EggertMichael Steinhorst
    • C22C1/05B22F9/20C22B5/04H01F1/057H01F1/059B22F9/26
    • B22F9/20C22B5/04H01F1/0573H01F1/059
    • A method for producing single-phase intermetallic phases, which melt incongruently within a temperature range of 900.degree. to 2,000.degree. K., with a homogeneity range of .ltoreq.10 atom % at room temperature by co-reduction is described. The exothermic reaction of the calciothermal reduction is adjusted by altering the oxide content of the reaction mixture, the composition of which corresponds to the desired single-phase alloy, in such a way that the temperature condition T.sub.m >T.sub.R .gtoreq.0.9 T.sub.m (in .degree. K.) is fulfilled, T.sub.m being the melting temperature of the intermetallic phase and T.sub.R the reaction temperature. The components of the reaction mixture, with the exception of calcium, have an average particle size of .ltoreq.75 .mu.m. The reaction product at the end of the exothermic reaction is tempered at a temperature which is at least 0.7 times the melting temperature T.sub.m of the desired, single-phase alloy, measured in .degree. K., but is less than the melting temperature T.sub.m, during a period sufficient for the diffusion of the components.
    • 描述了通过共同还原在室温下在均匀范围为 TR> / = 0.9Tm(在 DEG K.),Tm是金属间相的熔融温度,TR是反应温度。 除了钙之外,反应混合物的组分具有平均粒度<75μm。 在放热反应结束时的反应产物在至少为所需单相合金的熔融温度Tm的0.7倍的温度下回火,该温度在DEG下测量,但小于熔融温度Tm 足以使部件扩散的时间。