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    • 14. 发明授权
    • Functional molecular device
    • 功能分子装置
    • US07679080B2
    • 2010-03-16
    • US11571135
    • 2005-06-23
    • Eriko MatsuiNobuyuki MatsuzawaAkio YasudaOliver Harnack
    • Eriko MatsuiNobuyuki MatsuzawaAkio YasudaOliver Harnack
    • H01L51/30
    • B82Y30/00B82Y10/00H01L27/283H01L51/005H01L51/0067H01L51/0512H01L51/0583H01L51/0595Y10S977/731Y10S977/791Y10S977/94Y10S977/943
    • A functional molecular device displaying its functions under the action of an electrical field is provided. A Louis base molecule, exhibiting positive dielectric constant anisotropy or exhibiting dipole moment along the long-axis direction of the Louis base molecule, is arrayed in the form of a pendant on an electrically conductive linear or film-shaped principal-axis molecule of a conjugated system, via a metal ion capable of acting as a Louis acid. The resulting structure is changed in conformation on application of an electrical field to exhibit its function. The electrically conductive linear or film-shaped principal-axis molecule and the Louis base molecule form a complex with the metal ion. On application of the electrical field, the Louis base molecule performs a swinging movement or a seesaw movement to switch the electrical conductivity of the principal-axis molecule. This molecule exhibits electrical characteristics which may be reversed depending on whether or not the molecule has been subjected to electrical field processing. A molecular device having a function equivalent to one of CMOS may be produced from one and the same material.
    • 提供了在电场作用下显示其功能的功能分子装置。 在路易斯碱分子的长轴方向显示出正介电常数各向异性或显示偶极矩的路易斯碱基分子以共轭的导电线性或膜状主轴分子的侧基的形式排列 系统,通过能够作为路易斯酸的金属离子。 所产生的结构在施加电场以表现其功能的结构上改变。 导电线性或膜状主轴分子和路易斯碱分子与金属离子形成络合物。 在施加电场时,路易斯碱分子进行摆动运动或跷跷板运动以切换主轴分子的导电性。 该分子表现出电特性,其可以根据分子是否经受电场加工而反转。 具有与CMOS之一相当的功能的分子器件可以由同一材料制造。
    • 19. 发明申请
    • FUNCTIONAL MOLECULAR ELEMENT, METHOD FOR PRODUCING FUNCTIONAL MOLECULAR ELEMENT, AND FUNCTIONAL MOLECULAR DEVICE
    • 功能分子元件,生产功能分子元件的方法和功能分子装置
    • US20060278868A1
    • 2006-12-14
    • US11422485
    • 2006-06-06
    • Eriko Matsui
    • Eriko Matsui
    • H01L29/08
    • H01L51/0077B82Y10/00G11C13/0014G11C13/02G11C2213/14H01L51/0012H01L51/0026H01L51/0076H01L51/0558H01L51/0595H01L51/105Y10S977/791
    • A functional molecular element with a reduced contact resistance between the constituting molecule and the electrode, a method for production thereof, and a functional molecular device are provided herein. The method consists of the following steps. A closely adhering molecular monolayer is formed on the surface of the electrodes from a π-electron conjugated molecule (one species of linear tetrapyrrole) composed of the porphyrin-like nearly discoid skeleton and the flexible side chains (alkyl chains). A π-electron conjugated molecule of the same species as the one or different species from the one is piled on the monolayer by π-π stacking to form the array structure. As the result of the foregoing steps, the π-electron conjugated molecule constituting the first molecular layer of the array structure takes on such a configuration that the flexible side chains adsorb to the surface of the electrode and the discoid skeleton orients parallel to and adheres to the surface of the electrode. The second and subsequent molecular layers constituting the array structure have their piling direction controlled by the π-π mutual action.
    • 本文提供了构成分子与电极之间的接触电阻降低的功能性分子元件,其制造方法和功能性分子器件。 该方法由以下步骤组成。 由卟啉样的近似盘状骨架和柔性侧链(烷基链)组成的π电子共轭分子(一种线性四吡咯)形成电极表面上紧密分散的单层。 通过pi-pi堆叠将与一种或不同种类相同物种的π电子共轭分子堆叠在单层上以形成阵列结构。 作为上述步骤的结果,构成阵列结构的第一分子层的π-电子共轭分子具有这样的构造:柔性侧链吸附到电极的表面,并且盘状骨架定向平行并粘附于 电极的表面。 构成阵列结构的第二和随后的分子层的打桩方向由pi-pi相互作用控制。