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11. 发明授权

US07803886B2 Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers 有权
标题翻译：用于催化低聚烯烃单体的配体及其催化剂体系
公开(公告)号：US07803886B2
公开(公告)日：2010-09-28
申请号：US11961638
申请日：2007-12-20
申请人： Eric Johannes Maria De Boer , Harry Van der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/22 , C07F9/535 , B01J31/02
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R4)—P(R1)(R2)═N(R3) (I) wherein: the R1 group and R2 group are independently selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（I）的配体; P（R 4）-P（R 1）（R 2）= N（R 3）（I）其中：R 1基团和R 2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

12. 发明授权

US07238764B2 Process for the co-oligomerisation of ethylene and alpha olefins 失效
标题翻译：乙烯和α-烯烃的共低聚方法
公开(公告)号：US07238764B2
公开(公告)日：2007-07-03
申请号：US10739715
申请日：2003-12-18
申请人： Eric Johannes Maria De Boer , Hendrikus Hyacinthus Deuling , Harry Van Der Heijden , Quoc An On , Aart Bartus Van Oort , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Hendrikus Hyacinthus Deuling , Harry Van Der Heijden , Quoc An On , Aart Bartus Van Oort , Arie Van Zon
IPC分类号： C08F110/04 , C08F110/14
CPC分类号： C07C2/32 , C07C11/02 , C07C2531/22 , Y02P20/52 , Y02P20/582
摘要： A process for production of higher linear alpha olefins and/or alkyl-branched alpha olefins, which comprises the co-oligomerisation of one or more alpha olefins with ethylene in the presence of a metal catalyst system employing one or more bis-aryliminepyridine MXa complexes and/or one or more [bis-aryliminepyridine MYp.Lb+][NC−]q complexes; and said process is carried out at an ethylene pressure of less than 2.5 MPa.
摘要翻译：一种生产高级直链α-烯烃和/或烷基支链α-烯烃的方法，其包括在使用一种或多种双芳基亚氨基吡啶MX 一个或多个配合物和/或一种或多种[双芳基亚氨基吡啶MY + - ]

13. 发明授权

US07037988B2 Process for the co-oligomerisation of ethylene and alpha olefins 失效
标题翻译：乙烯和α-烯烃的共低聚方法
公开(公告)号：US07037988B2
公开(公告)日：2006-05-02
申请号：US09964714
申请日：2001-09-27
申请人： Eric Johannes Maria De Boer , Hendrikus Hyacinthus Deuling , Harry Van Der Heijden , Quoc An On , Aart Bartus Van Oort , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Hendrikus Hyacinthus Deuling , Harry Van Der Heijden , Quoc An On , Aart Bartus Van Oort , Arie Van Zon
IPC分类号： C08F4/44 , C07C2/04
CPC分类号： C07C2/32 , C07C11/02 , C07C2531/22 , Y02P20/52 , Y02P20/582
摘要： A process for production of higher linear alpha olefins and/or alkyl-branched alpha olefins, which comprises the co-oligomerisation of one or more alpha olefins with ethylene in the presence of a metal catalyst system employing one or more bis-aryliminepyridine MXa complexes and/or one or more [bis-aryliminepyridine MYp.Lb+][NC−]q complexes; and said process is carried out at an ethylene pressure of less than 2.5 MPa.
摘要翻译：一种生产高级直链α-烯烃和/或烷基支链α-烯烃的方法，其包括在使用一种或多种双芳基亚氨基吡啶MX 一个或多个配合物和/或一种或多种[双芳基亚氨基吡啶MY + - ]

14. 发明申请

US20100311932A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体催化低级化合物的配体和催化剂体系
公开(公告)号：US20100311932A1
公开(公告)日：2010-12-09
申请号：US12859337
申请日：2010-08-19
申请人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/22 , C07F9/08 , B01J31/12
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4) (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

15. 发明授权

US07589245B2 Process for preparing linear alpha olefins 失效
标题翻译：线性α-烯烃的制备方法
公开(公告)号：US07589245B2
公开(公告)日：2009-09-15
申请号：US11179459
申请日：2005-07-12
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
IPC分类号： C07C2/26 , C07C2/34
CPC分类号： C07C2/08 , C07C1/327 , C07C5/2575 , C07C2523/755 , C07C2527/128 , C07C2531/14 , C07C11/02
摘要： A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i) reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin; and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.
摘要翻译：制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下二聚具有n个碳原子的直链α-烯烃以产生线性内烯烃具有2n个碳原子; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化，从所述三烷基铝化合物置换烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是由所述直链内烯烃的异构化衍生的直链烷基; 和（b）（ii）任选地在置换催化剂存在下使所述烷基铝化合物与α-烯烃反应，以使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

16. 发明授权

US07179871B2 Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins 失效
标题翻译：用于乙烯低聚成直链α-烯烃的非对称配体及其催化剂体系
公开(公告)号：US07179871B2
公开(公告)日：2007-02-20
申请号：US10320213
申请日：2002-12-16
申请人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
IPC分类号： C08F4/44 , C08F4/52
CPC分类号： C07D213/53 , Y02P20/582
摘要： Non-symmetrical ligands of formula (I); bis-aryliminepyridine MXn complexes comprising a non-symmetrical ligand of formula (I), wherein M is a metal selected from Fe or Co, n is 2 or 3, and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; [bis-aryliminepyridine MYp.Ln+][NC−]q complexes, comprising a non-symmetrical ligand of formula (I), wherein Y is a ligand which may insert an olefin, M is Fe or Co, NC− is a non-coordinating anion and p+q is 2 or 3, matching the formal oxidation of the metal atom M, L is a neutral Lewis donor molecule and n=0, 1, or 2; and processes for the production of alpha-olefins from ethylene, using said complexes.
摘要翻译：式（I）的非对称配体; 包含式（I）的非对称配位体的双芳基亚氨基吡啶MX复合物，其中M为选自Fe或Co的金属，n为2或3，X为卤化物，任选取代的烃基，醇盐，酰胺或氢化物; [双 - 芳基亚氨基吡啶] n + 1 / n + >络合物，其包含式（I）的非对称配体，其中Y是可插入烯烃的配体，M是Fe或Co，NC是非配位阴离子，p + q是2或3，匹配金属原子M的形式氧化，L是中性Lewis供体分子，n = 0,1或2; 以及使用所述复合物从乙烯生产α-烯烃的方法。

17. 发明申请

US20060014989A1 Process for preparring linear alpha olefins 失效
标题翻译：制备直链α-烯烃的方法
公开(公告)号：US20060014989A1
公开(公告)日：2006-01-19
申请号：US11179459
申请日：2005-07-12
申请人： Eric Johannes De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
发明人： Eric Johannes De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
IPC分类号： C07C2/00
CPC分类号： C07C2/08 , C07C1/327 , C07C5/2575 , C07C2523/755 , C07C2527/128 , C07C2531/14 , C07C11/02
摘要： A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i) reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin; and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.
摘要翻译：制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下二聚具有n个碳原子的直链α-烯烃以产生线性内烯烃具有2n个碳原子; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化，从所述三烷基铝化合物置换烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是由所述直链内烯烃的异构化衍生的直链烷基; 和（b）（ii）任选地在置换催化剂存在下使所述烷基铝化合物与α-烯烃反应，以使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

18. 发明授权

US08637617B2 Catalyst systems for the catalytic oligomerization of olefinic monomers 失效
标题翻译：用于催化低聚烯烃单体的催化剂体系
公开(公告)号：US08637617B2
公开(公告)日：2014-01-28
申请号：US13198997
申请日：2011-08-05
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/78 , B01J31/02
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (IV); (R8)(R1)P—N(R3)—P(R4) (IV).
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（Ⅳ）的配体; （R8）（R1）P-N（R3）-P（R4）（IV）。

19. 发明申请

US20100311928A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体催化低级化合物的配体和催化剂体系
公开(公告)号：US20100311928A1
公开(公告)日：2010-12-09
申请号：US12859331
申请日：2010-08-19
申请人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/78 , C07F9/06 , B01J31/18
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand comprising the product formed by reacting i) a compound having the general formula (III); (R1)(R2)P—N(R3)—R5 (III); and ii) a compound of the formula X—P(R4), preferably at a temperature in the range of from −30 to 200° C.
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，该配体包括通过使i）具有通式（III）的化合物与通式（R1）（R2）P-N（R3）-R5（III）; 和ii）式X-P（R4）的化合物，优选在-30至200℃的温度范围内。

20. 发明授权

US07381857B2 Catalytic trimerization and tetramerization of olefinic monomers 失效
标题翻译：烯烃单体的催化三聚和四聚
公开(公告)号：US07381857B2
公开(公告)日：2008-06-03
申请号：US11770520
申请日：2007-06-28
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C07C2/08
CPC分类号： B01J31/188 , B01J31/143 , B01J31/2409 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2540/10 , C07C2/36 , C07C2531/24 , C07C11/02 , C07C11/107
摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I): (R1)(R2)P-X-P(R3)(R4) (I) where X is a bivalent organic bridging group, R1 and R3 are hydrocarbyl groups, and R2 and R4 are aromatic groups; and c) a second ligand having the general formula (II): (R1′)(R2′)P-X′-P(R3′)(R4′) (II) where X′ is a bridging group containing nitrogen and R1′, R2′, R3′ and R4′ are hydrocarbyl groups. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.
摘要翻译：一种催化剂前体组合物，其包含a）铬，钼或钨的源; b）具有通式（I）的第一配体：<？in-line-formula description =“In-line formula”end =“lead”？>（R 1 SUP）（2）PXP（R 3）（R 4）（I）<βin-line-formula description =“In-line Formulas”end = “尾”→>其中X是二价有机桥基，R 1和R 3是烃基，R 2和R 2， SUP> 4是芳基; 和（c）具有通式（II）的第二配位体：<？in-line-formula description =“In-line formula”end =“lead”→（R 1> （二）'P-X'-P（R 3'）（R 4'）（II）<β在线式 description =“In-line Formulas”end =“tail”？>其中X'是含有氮和R 1'的桥连基团，R 2'，R“ > 3'和R 4'是烃基。本发明还涉及包含本发明的催化剂前体组合物和助催化剂的催化剂体系。

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