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    • 16. 发明授权
    • Process for carbon-carbon composite fabrication
    • 碳 - 碳复合材料制造工艺
    • US4745008A
    • 1988-05-17
    • US852597
    • 1986-04-16
    • Irene G. PlotzkerJoan H. CranmerDonald R. UhlmannLeighton H. Peebles, Jr.
    • Irene G. PlotzkerJoan H. CranmerDonald R. UhlmannLeighton H. Peebles, Jr.
    • C04B35/83B05D3/02C01B31/02
    • C04B35/83
    • A fabrication process is disclosed that achieves a higher density carbon-bon article, than the prior art processes by maintaining a vertical temperature gradient in a reservoir of pitch (e.g. 550.degree. C. at the bottom to 250.degree. C. at the top) into which a carbon fiber preform is immersed. The use of the vertical temperature gradient results in a reservoir of hot fluid pitch around the upper end of the preform during pitch impregnation of the preform. This permits the fluid pitch to drain down by gravity into the interstices of the carbon fiber and the hardening pitch below. The next step of the process involves gradually increasing the pitch-hardening temperature from bottom to top to harden the pitch from bottom to top. Thereafter, the impregnated preform is carbonized at high temperature. This method takes advantage of the thermal conductivity of the carbon fibers and does not require extremely high pressures. In fact, a high pressure would be a detriment since it results in closed pores. The process of the present disclosure depends on the development of large, connected pores that can be more easily filled. This manner results in the production of suitable carbonized billets in a fraction of the time currently required and using much less energy.
    • 公开了一种制造方法,其比现有技术方法更高密度的碳 - 碳制品,其通过将间距贮存器中的垂直温度梯度(例如,顶部的底部至550℃)保持在垂直温度梯度 浸渍碳纤维预成型体。 垂直温度梯度的使用导致在预成型件的间距浸渍期间围绕预成型件的上端的热流体间距的储存器。 这允许液体沥青通过重力排入碳纤维的间隙和下面的硬化间距。 该方法的下一步包括从底部到顶部逐渐增加沥青硬化温度,从而从顶部到顶部硬化沥青。 此后,浸渍的预成型体在高温下碳化。 该方法利用碳纤维的导热性,不需要极高的压力。 事实上,高压是一个有害的因为它导致闭孔。 本公开的方法取决于可以更容易地填充的大的连接的孔的发展。 这种方式导致在目前所需时间的一小部分中生产合适的碳化坯料并且使用更少的能量。
    • 19. 发明授权
    • Plasticization of carbon fibers
    • 碳纤维增塑
    • US4336283A
    • 1982-06-22
    • US714542
    • 1976-08-16
    • Leighton H. PeeblesDonald R. UhlmannSteven B. Warner
    • Leighton H. PeeblesDonald R. UhlmannSteven B. Warner
    • D01F11/12B05D3/10
    • D01F11/121
    • An improved method of manufacturing articles containing carbon fibers when the fibers are temporarily plasticized to render them more flexible thereby permitting tortuous mechanical manipulation of the fibers to be carried out with little or no mechanical damage. The improvement comprises exposing the carbon fibers to agents capable of intercalating single crystals of graphite, such as bromine or iodine monochloride which have the effect of plasticizing the fibers by lowering their tensile modulus. While the fiber yarns are appreciably more flexible in the plasticized state, and have a higher elongation-at-break, on removal of the plasticizer they tend to return to their original state but retain a measurable degree of the shape imparted to them.
    • 一种改进的制造含有碳纤维的制品的方法,其中纤维被暂时塑化以使它们更具柔性,从而允许纤维的曲折机械操作以很少或没有机械损伤进行。 该改进包括将碳纤维暴露于能够嵌入石墨单晶的试剂,例如溴或碘一氯化物,其具有通过降低其拉伸模量来增塑纤维的作用。 虽然纤维纱在增塑状态下明显更具柔性,并且具有较高的断裂伸长率,但在去除增塑剂时,它们趋向于恢复到其原始状态,但是保留了赋予它们的形状的可测量的程度。