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11. 发明授权

US4511743A Process for homologating alcohols through the intermediate production of ketals with cobalt carbonyl complexes as catalysts 失效
标题翻译：通过羰基配合物作为催化剂通过中间体生产缩酮来使醇同步化的方法
公开(公告)号：US4511743A
公开(公告)日：1985-04-16
申请号：US548737
申请日：1983-11-04
申请人： Claude Seite , Dominique Commereuc , Yves Chauvin
发明人： Claude Seite , Dominique Commereuc , Yves Chauvin
IPC分类号： C07C29/14 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/141 , C07C41/50 , C07C45/00 , C07C45/49 , C07C45/51 , C07C67/00 , C07C27/20
CPC分类号： C07C41/50 , C07C29/141 , C07C45/49 , C07C45/515
摘要： Process for the homologation of an alcohol wherein a ketal of the alcohol is reacted with hydrogen and carbon monoxide in the presence of a cobalt carbonyl complex and the resultant product is hydrolyzed to yield the aldehyde with one more carbon atom.
摘要翻译：醇的同系化方法，其中醇的缩酮在羰基钴络合物的存在下与氢气和一氧化碳反应，并将所得产物水解以产生具有多一个碳原子的醛。

12. 发明授权

US4005047A Catalytic composition and its use for polymerizing cycloolefins 失效
标题翻译：催化组合物及其用于聚合环烯烃的用途
公开(公告)号：US4005047A
公开(公告)日：1977-01-25
申请号：US547032
申请日：1975-02-04
申请人： Yves Chauvin , Dominique Commereuc , Daniel Cruypelinck , Jean-Pierre Soufflet
发明人： Yves Chauvin , Dominique Commereuc , Daniel Cruypelinck , Jean-Pierre Soufflet
IPC分类号： C08G61/00 , C08F4/22 , C08F4/78 , C08G61/06 , C08G61/08
CPC分类号： C08G61/08
摘要： New catalytic composition of improved activity in the process of polymerizing cycloolefins, comprising a carbonyl compound or a carbonyl-metal-carbenic compound of molybdenum or tungsten and titanium tetrachloride, said composition being preferably subjected to an irradiation with rays of a wave length from 180 to 700 nanometers during or before use.
摘要翻译：在包含钼或钨和四氯化钛的羰基化合物或羰基 - 金属 - 碳化合物的环烯烃聚合过程中改进的活性的新催化组合物，所述组合物优选经受从180至使用期间或之前700纳米。

13. 发明授权

US06846465B2 Vibratory helicoidal conveyor for treatment of metathesis catalysts for olefins 失效
标题翻译：用于处理烯烃复分解催化剂的振动螺旋输送机
公开(公告)号：US06846465B2
公开(公告)日：2005-01-25
申请号：US09837379
申请日：2001-04-19
申请人： Dominique Commereuc , Hélène Olivier , Lucien Saussine
发明人： Dominique Commereuc , Hélène Olivier , Lucien Saussine
IPC分类号： B01J38/04 , B01J38/12 , C07C6/04 , C08F2/34 , B01D50/00 , B01D53/34
CPC分类号： B01J38/12 , B01J38/04 , C07C6/04 , Y02P20/584 , Y10S526/901
摘要： A vibratory helidcoidal lifting device (12) suitable for regenerating metathesis catalysts for olefins, comprises a combustion zone (14) and a calcination zone (15), as well as a preheating zone, a zone for stripping hydrocarbons and a zone for cooling the catalyst, but no zone for introducing a gas containing a halogenated compound.
摘要翻译：一种适于再生烯烃复分解催化剂的振动式氦气提升装置（12）包括燃烧区（14）和煅烧区（15），以及预热区，用于汽提烃的区和用于冷却催化剂的区但是没有用于引入含有卤化化合物的气体的区域。

14. 发明授权

US06743958B2 Process for selective production of propylene from hydrocarbon fractions with four carbon atoms 有权
$Process for selective production of propylene from hydrocarbon fractions with four carbon atoms$
标题翻译：从具有四个碳原子的烃馏分中选择性生产丙烯的方法
公开(公告)号：US06743958B2
公开(公告)日：2004-06-01
申请号：US09846690
申请日：2001-05-02
申请人： Dominique Commereuc , Christine Travers
发明人： Dominique Commereuc , Christine Travers
IPC分类号： C07C604
CPC分类号： C07C11/06 , C07C6/04 , C07C11/09 , C07C2521/06 , C07C2523/36
摘要： For the selective production of propylene from an olefinic C4 fraction, a process is implemented that successively comprises: 1) the selective hydrogenation of butadiene with isomerization of butene-1 into butene-2; 2) the separation by distillation of a mixture that is rich in isobutene and butene-1 at the top and a fraction that is rich in butene-2 at the bottom; 3) the skeletal isomerization of isobutene into n-butenes on the top fraction, with recycling in stage 1; and 4) the metathesis of the butene-2-rich fraction with ethylene.
摘要翻译：对于从烯烃C4馏分中选择性生产丙烯的方法，其顺序包括：1）丁烯与丁烯-2的异构化的选择性氢化; 2）通过蒸馏分离富集的混合物在顶部的异丁烯和丁烯-1，底部富含丁烯-2的馏分; 3）在第一阶段循环的异丁烯在顶级馏分上的正丁烯异构化成正丁烯; 和4）富含丁烯的富烯馏分与乙烯的复分解。

15. 发明授权

US06437209B1 Process for metathesis of olefins in the presence of a stabilizing agent of the catalyst 失效
标题翻译：烯烃在催化剂稳定剂存在下复分解的方法
公开(公告)号：US06437209B1
公开(公告)日：2002-08-20
申请号：US09493255
申请日：2000-01-28
申请人： Dominique Commereuc , Paul Mikitenko
发明人： Dominique Commereuc , Paul Mikitenko
IPC分类号： C07C600
CPC分类号： C07C6/04 , C07C2523/00 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2531/14 , C07C2531/32 , Y02P20/127 , Y02P20/582
摘要： Catalytic process for metathesis of olefins in the presence of a catalyst and a stabilizing agent that is injected into the reaction medium. Application in particular to rebalancing between one another the light olefins that are obtained from steam cracking or catalytic cracking (FCC), such as ethylene, propylene, butenes or pentenes.
摘要翻译：在催化剂和注入反应介质的稳定剂存在下烯烃复分解的催化方法。尤其适用于从蒸汽裂化或催化裂化（FCC）获得的轻质烯烃（如乙烯，丙烯，丁烯或戊烯）之间的平衡。

16. 发明授权

US06277781B1 Process for preparing a rhenium and cesium based metathesis catalyst 失效
标题翻译：制备铼和铯基复分解催化剂的方法
公开(公告)号：US06277781B1
公开(公告)日：2001-08-21
申请号：US09413192
申请日：1999-10-05
申请人： Dominique Commereuc , François Hugues , Lucien Saussine
发明人： Dominique Commereuc , François Hugues , Lucien Saussine
IPC分类号： B01J2304
CPC分类号： C07C6/04 , B01J23/36 , C07C2521/04 , C07C2523/04 , C07C2523/36 , Y02P20/52
摘要： The present invention provides a catalyst and a process for metathesis of olefinic C4 cuts. The catalyst contains rhenium, cesium and delta alumina. The preferred catalyst contains at least one rhenium compound deposited on a support principally composed of alumina, treated at a temperature of more than 750° C., and modified by at least one cesium compound. With the use of the catalyst, the duration of the cycle between two regeneration operations can be substantially increased. The catalyst is suitable for use in a process for production of propylene from an olefinic C4 cut in three steps: (1) selective hydrogenation of butadiene with isomerisation of 1-butene to 2-butene, (2) separation by distillation of the major portion of the isobutene, and (3) metathesis of the cut rich in 2-butene with ethylene.
摘要翻译：本发明提供催化剂和烯烃C4馏分的复分解方法。催化剂含有铼，铯和δ氧化铝。优选的催化剂含有沉积在主要由氧化铝组成的载体上的至少一种铼化合物，其在大于750℃的温度下处理并被至少一种铯化合物修饰。通过使用催化剂，可以显着增加两次再生操作之间的循环持续时间。该催化剂适用于以下三个步骤从烯烃C4馏分生产丙烯的方法：（1）丁烯与1-丁烯异构化至2-丁烯的选择性氢化，（2）通过主蒸馏分离的异丁烯，（3）富含2-丁烯的馏分与乙烯的复分解。

17. 发明授权

US06207115B1 Process and plant for the conversion of olefinic C4 cuts to polyisobutene and to propylene 有权
标题翻译：用于将烯烃C4馏分转化为聚异丁烯和丙烯的方法和装置
公开(公告)号：US06207115B1
公开(公告)日：2001-03-27
申请号：US09201087
申请日：1998-11-30
申请人： Jean-Alain Chodorge , Dominique Commereuc , Jean Cosyns , Didier Duee , Bernard Torck
发明人： Jean-Alain Chodorge , Dominique Commereuc , Jean Cosyns , Didier Duee , Bernard Torck
IPC分类号： B01J804
CPC分类号： C08F110/10 , B01J8/08 , C07C6/04 , C07C7/163 , C07C11/06 , C07C2521/04 , C07C2523/20 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/755 , C08F2/00 , C08F4/12
摘要： The present invention concerns a process for the conversion of an olefinic C4 cut to polyisobutene and to propylene by metathesis. The process comprises three successive steps: (1) selective hydrogenation of diolefins with simultaneous isomerisation of 1-butene to 2-butenes, (2) polymerisation of the isobutene, including optional prior extraction of the isobutene, (3) metathesis of 2-butene with ethylene. Part or all of the C4 cut may originate from the metathesis of an olefinic C5 cut with ethylene after hydroisomerisation of the C5 cut. Application to C4 and C5 steam cracking cuts.
摘要翻译：本发明涉及通过复分解将烯烃C4馏分转化为聚异丁烯和丙烯的方法。该方法包括三个连续步骤：（1）将1-丁烯同时异构化为2-丁烯的二烯烃的选择性氢化，（2）异丁烯的聚合，包括任选先前提取的异丁烯，（3）2-丁烯的复分解与乙烯。 C4馏分的部分或全部可以源自C5馏分加氢异构化后的烯烃C5馏分的复分解。应用于C4和C5蒸汽裂解切割。

18. 发明授权

US5817905A Process for the conversion of ethylene into light alpha olefins with the use of additives based on quaternary ammonium salts 失效
标题翻译：使用基于季铵盐的添加剂将乙烯转化成轻质α-烯烃的方法
公开(公告)号：US5817905A
公开(公告)日：1998-10-06
申请号：US842504
申请日：1997-04-24
申请人： Dominique Commereuc , Yves Glaize , Fran.cedilla.ois Hugues , Pierre Panzarella , Lucien Saussine
发明人： Dominique Commereuc , Yves Glaize , Fran.cedilla.ois Hugues , Pierre Panzarella , Lucien Saussine
IPC分类号： B01J31/14 , C07B61/00 , C07C2/26 , C07C2/30 , C07C11/02 , C07C2/02 , C07C2/08
CPC分类号： C07C2/30 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/24 , C07C2531/38
摘要： The invention concerns an improved process for the conversion of ethylene into light alpha olefins wherein the ethylene is brought into contact with a catalyst obtained by mixing a compound of zirconium with an organic compound selected from the class of acetals and ketals, esters, ketones, ethers, amines, nitrites, anhydrides, chlorides of acids, amides, aldehydes, thioethers, sulphides and disulphides, thiophenes, thioureas and phosphines, and with a chloro or bromo compound of aluminium hydrocarbyl, in the presence of an additive formed by at least one quaternary ammonium salt.
摘要翻译：本发明涉及将乙烯转化成轻质α-烯烃的改进方法，其中乙烯与通过将锆化合物与选自缩醛和缩酮类，有机酮，酮类，醚类的有机化合物混合而得到的催化剂接触，胺，亚硝酸盐，酸酐，酸的酰胺，酰胺，醛，硫醚，硫化物和二硫化物，噻吩，硫脲和膦以及与烃基的氯或溴化合物在存在由至少一种季铵盐形成的添加剂铵盐。

19. 发明授权

US5496783A Catalyst for the production of light alpha olefins by oligomerization of ethylene 失效
标题翻译：用于通过乙烯低聚生产轻质α-烯烃的催化剂
公开(公告)号：US5496783A
公开(公告)日：1996-03-05
申请号：US253017
申请日：1994-06-02
申请人： Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
发明人： Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
IPC分类号： C07B61/00 , B01J31/38 , C07C2/30 , C07C11/02 , C08F4/642
CPC分类号： C07C2/30 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/38 , Y02P20/52
摘要： Process for oligomerizing ethylene into light alpha olefins, mainly 1-butene, 1-hexene, 1-octene and 1-decene, in which the ethylene is contacted with a catalyst obtained by mixing a zirconium compound with an organic compound chosen from within the class of acetals and ketals and with a chlorine or bromine-containing compound of aluminium hydrocarbyl.
摘要翻译：将乙烯低聚成轻质α-烯烃，主要是1-丁烯，1-己烯，1-辛烯和1-癸烯的方法，其中乙烯与通过混合锆化合物与选自类中的有机化合物获得的催化剂接触的缩醛和缩酮以及含有氯或溴的铝盐化合物。

20. 发明授权

US5449852A Process for the metathesis of olefins with an improved rhenium catalyst 失效
标题翻译：使用改进的铼催化剂进行烯烃复分解的方法
公开(公告)号：US5449852A
公开(公告)日：1995-09-12
申请号：US293194
申请日：1994-08-19
申请人： Yves Chauvin , Dominique Commereuc
发明人： Yves Chauvin , Dominique Commereuc
IPC分类号： B01J23/36 , B01J27/08 , C07B61/00 , C07C6/04 , C07C6/06 , C07C11/02
CPC分类号： B01J23/36 , C07C6/04 , C07C6/06 , C07C2521/04 , C07C2523/20 , C07C2523/36
摘要： A process for the metathesis of olefins, wherein the olefins are reacted in contact with an improved catalyst comprising a niobium and/or tantalum compound and a rhenium compound on a porous support containing at least 75% alumina and having a surface area of at least 10 m.sup.2 /g.
摘要翻译：一种用于烯烃复分解的方法，其中所述烯烃与包含铌和/或钽化合物和铼化合物的改进的催化剂接触，所述改进的催化剂包含至少75％的氧化铝并且具有至少10的表面积的多孔载体 m2 / g。

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