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11. 发明授权

US5191035A Blends of polyether sulfones and polyimides 失效
标题翻译：聚醚砜和聚酰亚胺的共混物
公开(公告)号：US5191035A
公开(公告)日：1993-03-02
申请号：US768009
申请日：1991-09-30
申请人： M. Jamal El-Hibri , James E. Harris , John L. Melquist
发明人： M. Jamal El-Hibri , James E. Harris , John L. Melquist
IPC分类号： C08L71/00 , C08L79/08
CPC分类号： C08L71/00 , C08L79/08
摘要： Blends of a polyether sulfone and the polyimide of the dianhydride sulfonyl bis(phthalic anhydride) ("SPAN") and the diamine 1,4-bis(p-aminocumyl)benzene ("BAP"). The blends will comprise from about 10 to about 90 wt % polyether sulfone, preferably greater than about 50 wt % polyether sulfone, based on the total weights of polyether sulfone and polyimide. The blends exhibit good toughness and improved thermal performance over polyether sulfone alone while remaining readily processable, and have good mechanical properties including unexpectedly high stiffness as determined by high tensile modulus values. Blends of this invention also are surprisingly miscible, defined as exhibiting a single Tg value.
摘要翻译：聚醚砜与二酐磺酰基双（邻苯二甲酸酐）（“SPAN”）和二胺1,4-双（对氨基辛基）苯（“BAP”）的聚酰亚胺的共混物。基于聚醚砜和聚酰亚胺的总重量，共混物将包含约10至约90重量％的聚醚砜，优选大于约50重量％的聚醚砜。共混物表现出优异的韧性和相对于聚醚砜的热性能，同时保持易于加工，并且具有良好的机械性能，包括由高拉伸模量值确定的出乎意料的高刚度。本发明的共混物也令人惊奇地是可混溶的，定义为表现出单一的Tg值。

12. 发明授权

US4766102A Silver aluminum borate oxidation catalyst and process for its preparation 失效
标题翻译：硼酸铝铝氧化催化剂及其制备方法
公开(公告)号：US4766102A
公开(公告)日：1988-08-23
申请号：US17315
申请日：1987-02-20
申请人： Larry Satek , Laura Wilwerding , John L. Melquist , Melvin L. Luetkens
发明人： Larry Satek , Laura Wilwerding , John L. Melquist , Melvin L. Luetkens
IPC分类号： B01J23/50 , C01B35/12 , C07C253/28 , B01J21/02 , B01J21/04
CPC分类号： C07C253/28 , B01J23/50 , C01B35/128
摘要： The present invention relates to a novel silver aluminum borate composition useful as a catalyst for oxidation and/or ammoxidation reactions. More particularly the invention is directed to silver aluminum borate having the general formula (x) Ag.sub.2 O.(y) Al.sub.2 O.sub.3.(z) B.sub.2 O.sub.3 where x, y and z are numbers representing molar amounts of the oxides such that the mole fraction of Ag.sub.2 O, calculated as x/(x+y+z) is from about 0.35 to about 0.60, the mole fraction of Al.sub.2 O.sub.3, calculated as y/(x+y+z) is from about 0.10 to about 0.40, and the mole fraction of B.sub.2 O.sub.3, calculated as z/(x+y+z) is from about 0.10 to about 0.45. The invention is further directed to a method for preparing the catalyst, and to its use as an oxidation or ammoxidation catalyst.
摘要翻译：本发明涉及一种可用作氧化和/或氨氧化反应催化剂的新型硼酸铝硼酸盐组合物。更具体地，本发明涉及具有通式（x）Ag 2 O（y）Al 2 O 3。（z）B 2 O 3的硼酸铝铝，其中x，y和z是表示氧化物的摩尔量的数，使得Ag 2 O的摩尔分数，以x /（x + y + z）计算为约0.35至约0.60，以y /（x + y + z）计算的Al 2 O 3的摩尔分数为约0.10至约0.40，并且B 2 O 3的摩尔分数以z /（x + y + z）计算为约0.10至约0.45。本发明进一步涉及一种制备该催化剂的方法及其作为氧化或氨氧化催化剂的用途。

13. 发明授权

US4154701A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4154701A
公开(公告)日：1979-05-15
申请号：US901588
申请日：1978-05-01
申请人： John L. Melquist
发明人： John L. Melquist
IPC分类号： C08F4/64 , C08F10/00 , C08F4/68
CPC分类号： C08F10/00
摘要： Olefin polymerization catalyst useful in preparation of polyolefins of broad molecular weight distribution comprising (a) a component prepared by reacting an organoaluminum compound with a mixture comprising a titanium compound, a zirconium compound, and a vanadium compound; and (b) an organoaluminum promoter. The (a) component can be further treated with a deactivating agent. The olefin polymerization performance of the (a) component can be varied depending on the choice of promoter and deactivating agent.
摘要翻译：用于制备宽分子量分布的聚烯烃的烯烃聚合催化剂包括（a）通过使有机铝化合物与包含钛化合物，锆化合物和钒化合物的混合物反应制备的组分; 和（b）有机铝促进剂。（a）组分可以进一步用去活化剂处理。（a）成分的烯烃聚合性能可以根据助催化剂和失活剂的选择而变化。

14. 发明授权

US4130699A Vapor phase polymerization with temporarily inactive titanium catalyst 失效
标题翻译：气相聚合与暂时不活泼的钛催化剂
公开(公告)号：US4130699A
公开(公告)日：1978-12-19
申请号：US854831
申请日：1977-11-25
申请人： Glen R. Hoff , John L. Melquist , Peter Fotis
发明人： Glen R. Hoff , John L. Melquist , Peter Fotis
IPC分类号： B01J8/10 , B01J8/36 , B01J8/38 , B01J19/18 , C08F2/00 , C08F2/34 , C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , B01J19/1881 , B01J8/10 , B01J8/36 , B01J8/382 , B01J2219/182 , Y02P20/584 , Y10S526/901
摘要： Vapor phase polymerization of an olefin which comprises conveying inactive high yield titanium catalyst component to a vapor phase polymerization reactor with a liquid comprising recycled quench liquid, reactivating said inactive high yield titanium catalyst component inside the reactor with a metal alkyl reducing agent and polymerizing olefin under gas phase polymerization conditions with reactivated high yield catalyst to form a resinous polymer of an olefin having a low level of catalyst residues.
摘要翻译：烯烃的气相聚合，其包括将惰性高产率钛催化剂组分输送到包含再循环骤冷液体的液体的气相聚合反应器中，使用金属烷基还原剂和聚合烯烃使所述反应器内的所述非活性高产率钛催化剂组分重新活化气相聚合条件与再活化的高产率催化剂形成具有低水平催化剂残余物的烯烃的树脂聚合物。

15. 发明授权

US5536793A Concentrate for use in the melt fabrication of polyester 失效
公开(公告)号：US5536793A
公开(公告)日：1996-07-16
申请号：US475325
申请日：1995-06-07
申请人： George E. Rotter , Weilong Chiang , Boh C. Tsai , John L. Melquist , Cheryl A. Pauer , Stephen Y. Chen
发明人： George E. Rotter , Weilong Chiang , Boh C. Tsai , John L. Melquist , Cheryl A. Pauer , Stephen Y. Chen
IPC分类号： C08G63/20 , C08J3/22 , C08J9/00 , C08L67/02 , C08F20/00
CPC分类号： C08J3/226 , C08G63/20 , C08J9/00 , C08L67/02 , C08J2367/00 , C08J2367/02 , C08J2467/00
摘要： Concentrates produced by melt processing a branching agent and a polyester carrier are disclosed. The concentrates are useful in melt processing polyesters. The concentrates contain sufficiently high concentrations of a branching agent to minimize the formation of crosslinked compounds in the concentrates. Process for using the concentrate also are disclosed.

16. 发明授权

US5288764A Increased throughput in foaming and other melt fabrication of polyester 失效
标题翻译：在聚酯的发泡和其他熔体制造中提高生产量
公开(公告)号：US5288764A
公开(公告)日：1994-02-22
申请号：US10767
申请日：1993-01-29
申请人： George E. Rotter , John L. Melquist , Weilong Chiang , Boh C. Tsai , John J. Kelly
发明人： George E. Rotter , John L. Melquist , Weilong Chiang , Boh C. Tsai , John J. Kelly
IPC分类号： A47J27/00 , C08G63/91 , C08J9/00 , C08J9/04 , C08K5/09 , C08L67/00 , C08L67/02 , C08J9/08
CPC分类号： C08J9/0023 , C08J9/00 , C08J9/0066 , C08L67/02 , C08J2367/00 , C08J2367/02
摘要： Disclosed is a process for obtaining polyester articles, including foamed articles, containing low levels of extractable branching agent. The process comprises: (1) forming a molten mixture comprising (i) a major amount of a first resin composition comprising polyester and from 0 up to about 1 wt. % of a compound capable of branching the polyester, and (ii) a minor amount of a second polyester resin composition comprising at least about 50 wt. % polyester resin and greater than about 2 wt. % of a compound capable of branching the polyester, wherein the relative amounts of (i) and (ii) are such that said molten mixture comprises from about 0.1 wt. % to about 1 wt. % of said branching compound; (2) adding a blowing agent to the molten mixture; and (3) extruding the resultant mixture to obtain a foam. The invention is also directed to the second composition used in the above process, and foamed polyester articles obtained from the process.
摘要翻译：公开了一种获得包含低含量可萃取支化剂的聚酯制品，包括发泡制品的方法。该方法包括：（1）形成熔融混合物，其包含（i）主要量的第一树脂组合物，其包含聚酯和0至约1wt。能够分支聚酯的化合物的％，和（ii）少量的第二聚酯树脂组合物，其包含至少约50重量％％聚酯树脂和大于约2重量％能够分支聚酯的化合物的％，其中（i）和（ii）的相对量使得所述熔融混合物包含约0.1重量％％至约1wt。％的所述支化化合物; （2）向熔融混合物中加入发泡剂; 和（3）挤出所得混合物以获得泡沫。本发明还涉及上述方法中使用的第二组合物，以及由该方法获得的发泡聚酯制品。

17. 发明授权

US4210559A Catalyst for the preparation of polyalpha-olefins having broad molecular weight distributions 失效
标题翻译：用于制备具有宽分子量分布的聚α-烯烃的催化剂
公开(公告)号：US4210559A
公开(公告)日：1980-07-01
申请号：US955775
申请日：1978-10-30
申请人： John L. Melquist , Nicholas K. Kildahl , Peter Fotis
发明人： John L. Melquist , Nicholas K. Kildahl , Peter Fotis
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F10/00
摘要： Catalyst for the polymerization of alpha-olefins to polymers having broad molecular weight distributions consisting essentially of an organometallic promoter and the solid reaction product of an alkylaluminum component, at least one titanium(IV) compound, and at least one zirconium(IV) compound.
摘要翻译：用于将α-烯烃聚合到具有基本上由有机金属助催化剂和烷基铝组分，至少一种钛（IV）化合物和至少一种锆（IV））化合物的固体反应产物组成的宽分子量分布的聚合物的催化剂。

18. 发明授权

US5556926A Concentrate for use in the melt fabrication of polyester 失效
标题翻译：集中用于聚酯的熔体制造
公开(公告)号：US5556926A
公开(公告)日：1996-09-17
申请号：US593839
申请日：1996-01-30
申请人： George E. Rotter , Weilong Chiang , Boh C. Tsai , John L. Melquist , Cheryl A. Pauer , Stephen Y. Chen
发明人： George E. Rotter , Weilong Chiang , Boh C. Tsai , John L. Melquist , Cheryl A. Pauer , Stephen Y. Chen
IPC分类号： C08G63/20 , C08J3/22 , C08J9/00 , C08L67/02 , C08F20/00
CPC分类号： C08J3/226 , C08G63/20 , C08J9/00 , C08L67/02 , C08J2367/00 , C08J2367/02 , C08J2467/00
摘要： Concentrates produced by melt processing a branching agent and a polyester carrier are disclosed. The concentrates are useful in melt processing polyesters. The concentrates contain sufficiently high concentrations of a branching agent to minimize the formation of crosslinked compounds in the concentrates. Process for using the concentrate also are disclosed.
摘要翻译：公开了通过熔融加工支化剂和聚酯载体生产的浓缩物。浓缩物可用于熔融加工聚酯。浓缩物含有足够高浓度的支化剂以最小化浓缩物中交联化合物的形成。公开了使用浓缩物的方法。

19. 发明授权

US5189115A Polyetherimide copolymers 失效
标题翻译：聚醚酰亚胺共聚物
公开(公告)号：US5189115A
公开(公告)日：1993-02-23
申请号：US613401
申请日：1990-11-15
申请人： John L. Melquist
发明人： John L. Melquist
IPC分类号： C08G73/10 , C08L65/00 , C08L67/03 , C08L69/00 , C08L71/00 , C08L79/08 , C08L81/06
CPC分类号： C08L69/005 , C08G73/1042 , C08L65/00 , C08L67/03 , C08L71/00 , C08L79/08 , C08L81/06
摘要： Novel polyetherimide copolymers comprising the reaction product of 2,2-bis(3',4'-dicarboxyphenyl)propane dianhydride, an aromatic bis(ether anhydride), and a diamine are described. The polyetherimide copolymers have improved thermal properties, are soluble in conventional solvents, and are compatible with other engineering resins.
摘要翻译：描述了包含2,2-双（3'，4'-二羧基苯基）丙烷二酸酐，芳族双（醚酐）和二胺的反应产物的新型聚醚酰亚胺共聚物。聚醚酰亚胺共聚物具有改进的热性能，可溶于常规溶剂，并与其它工程树脂相容。

20. 发明授权

US4929763A Alcohol conversion 失效
标题翻译：酒精转化
公开(公告)号：US4929763A
公开(公告)日：1990-05-29
申请号：US330417
申请日：1989-03-29
申请人： Melvin L. Luetkens, Jr. , Steve T. McKenna , John L. Melquist
发明人： Melvin L. Luetkens, Jr. , Steve T. McKenna , John L. Melquist
IPC分类号： B01J23/10 , B01J29/86 , C07C1/20 , C07C45/38 , C07C45/39
CPC分类号： C07C45/39 , B01J23/10 , B01J29/86 , C07C1/20 , C07C45/38 , C07C2529/86
摘要： Conversion of alcohol to organic compounds which comprises contacting the alcohol with a heterogeneous catalyst composition comprising at least one member selected from the group consisting of(a) crystalline LnAl.sub.1.67+0.67X (B.sub.4 O.sub.10)O.sub.X, and(b) crystalline LnAl.sub.2.67+0.33Z (B.sub.4 O.sub.11)O.sub.Zwhere Ln is at least one transition element selected from the group consisting of Group IIIB of the Periodic Table, X is a number ranging from 0 to 1, and Z is a number ranging from 0 to 2, each crystalline phase having a characteristic X-ray diffraction pattern.
摘要翻译：将醇转化为有机化合物，其包括使醇与包含选自（a）结晶LnAl1.67 + 0.67X（B4O10）OX和（b）结晶LnAl2.67中的至少一种的非均相催化剂组合物接触 + 0.33Z（B4O11）OZ其中Ln是选自周期表第IIIB组中的至少一种过渡元素，X是0至1的数，Z是0至2的数，每个具有特征X射线衍射图的结晶相。

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