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11. 发明授权

US5210144A Diene polymers having reduced hysteresis and improved raw viscosity incorporating primary partial coupling and fused-ring polynuclear aromatic terminators 失效
标题翻译：二烯聚合物具有降低的滞后和改进的原始粘度，其中包含初级部分偶联和稠环多核芳族终止子
公开(公告)号：US5210144A
公开(公告)日：1993-05-11
申请号：US812172
申请日：1991-12-20
申请人： David F. Lawson , Mark L. Stayer, Jr. , Thomas A. Antkowiak
发明人： David F. Lawson , Mark L. Stayer, Jr. , Thomas A. Antkowiak
IPC分类号： C08C19/44
CPC分类号： C08C19/44
摘要： Diene polymers or copolymers having improved raw polymer viscosity and reduced hysteresis in the cured and carbon black reinforced state are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from fused-ring polynuclear aromatic compounds.The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using fused-ring polynuclear aromatic compounds. The resultant diene polymers or copolymers have improved raw polymer viscosity and when compounded with carbon black and cured have reduced hysteresis properties. The polymers can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.
摘要翻译：提供了在固化和炭黑增强状态下具有改进的原料聚合物粘度和降低的滞后的二烯聚合物或共聚物。这些二烯聚合物或共聚物包含在主聚合物或共聚物链中含有碳 - 锡键的二烯聚合物或共聚物链的混合物，以及含有衍生自稠环多核芳族化合物的末端的二烯聚合物或共聚物链。二烯聚合物或共聚物是通过首先将一部分活性二烯聚合物或通过阴离子聚合得到的共聚物链与多卤化锡偶联剂偶联，然后使用稠环多核芳族化合物终止剩余的活性二烯聚合物或共聚物链来制备的。所得二烯聚合物或共聚物具有改善的原始聚合物粘度，并且当与炭黑复合并固化时具有降低的滞后性能。聚合物可用于形成具有降低的滚动阻力的轮胎胎面的弹性体组合物。

12. 发明授权

US5153271A Diene polymers and copolymers terminated by reaction with aromatic nitriles 失效
标题翻译：二烯聚合物和共聚物通过与芳族腈反应终止
公开(公告)号：US5153271A
公开(公告)日：1992-10-06
申请号：US794082
申请日：1991-11-18
申请人： David F. Lawson , Mark L. Stayer, Jr. , Thomas A. Antkowiak
发明人： David F. Lawson , Mark L. Stayer, Jr. , Thomas A. Antkowiak
IPC分类号： C08C19/44 , C08F8/00 , C08F8/30 , C08F36/00 , C08F136/06 , C08F236/10 , G01N30/64
CPC分类号： C08C19/44 , B60C1/0016
摘要： A terminally functionalized polymer is prepared by reacting a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer with an aromatic nitrile compound. Especially useful aromatic nitriles are the unsubstituted and substituted benzonitriles. The resultant terminally functionalized polymers have reduced hysteresis in the carbon black reinforced and cured state and can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.

13. 发明授权

US5109907A Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines 失效
标题翻译：通过与N-烷基和N-芳基亚胺反应终止二烯聚合物和共聚物
公开(公告)号：US5109907A
公开(公告)日：1992-05-05
申请号：US732851
申请日：1991-07-19
申请人： Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
发明人： Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
IPC分类号： B60C1/00 , C08C19/44
CPC分类号： C08C19/44 , B60C1/0016
摘要： A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.
摘要翻译：提供了一种通过二烯单体或二烯单体和乙烯基芳族烃单体的混合物的阴离子聚合获得的活性聚合物制备末端官能化聚合物的方法，其包括使活性聚合物与具有下式的化合物反应：其中R 1和R 2选自H，烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 其中R 3选自烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 条件是R1，R2和R3基团中的至少一个必须是二烷基氨基芳基，并且不是所有的R 1，R 2和R 3基团都可以是芳基。所得的末端官能化聚合物具有降低的滞后性能，并且可用于制备具有降低的滚动阻力的弹性体组合物和轮胎胎面。

14. 发明授权

US06349753B1 Aminoalkyllithium compounds containing cyclic amines and polymers therefrom 有权
标题翻译：含有环胺的氨基烷基锂化合物及其聚合物
公开(公告)号：US06349753B1
公开(公告)日：2002-02-26
申请号：US09604034
申请日：2000-06-27
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
IPC分类号： B60C902
CPC分类号： B60C1/0016 , B60C1/00 , B60C1/0025 , B60C15/06 , C08C19/44 , C08F4/48 , C08F36/04 , Y10T152/10
摘要： A tire component comprising a plurality of elastomers, where at least one of said elastomers has a functional group defined by the formula where R1 is selected from the group consisting of a divalent alkylene group, an oxy-alkylene group, an amino alkylene group, and a substituted alkylene group, each group having from about 6 to about 20 carbon atoms, and R2 is covalently bonded to the elastomer and is selected from the group consisting of a linear-alkylene group, a branched-alkylene group, and a cyclo-alkylene group, each group having from about 2 to about 20 carbon atoms.
摘要翻译：一种轮胎组件，其包含多个弹性体，其中至少一个所述弹性体具有由所述结构域限定的官能团，R 1选自二价亚烷基，氧亚烷基，氨基亚烷基和取代的亚烷基，各自具有约6至约20个碳原子，并且R 2与弹性体共价键合并且选自线性亚烷基，支链亚烷基和环 - 亚烷基，每个基团具有约2至约20个碳原子。

15. 发明授权

US5785778A Aminoalkyllithium compounds containing cyclic amines and polymers therefrom 失效
标题翻译：含有环胺的氨基烷基锂化合物及其聚合物
公开(公告)号：US5785778A
公开(公告)日：1998-07-28
申请号：US813703
申请日：1997-03-07
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
IPC分类号： B60C1/00 , B60C15/06 , C08F36/04 , B60C5/00 , C08F293/00
CPC分类号： B60C15/06 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08F36/04 , Y10T152/10
摘要： A functionalized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
摘要翻译：根据本发明的官能化聚合物包括具有通式AYLi的聚合物分子，其中A是具有通式“IMAGE”的含环胺基团，其中R 1是二价亚烷基，氧基或氨基亚烷基或取代的亚烷基具有6至约20个碳原子; R2是具有约2-约20个碳原子的直链，支链或环 - 亚烷基; Y是二价聚合物基团，Li是与Y的碳原子键合的锂原子。

16. 发明授权

US5574109A Aminoalkyllithium compounds containing cyclic amines and polymers therefrom 失效
标题翻译：含有环胺的氨基烷基锂化合物及其聚合物
公开(公告)号：US5574109A
公开(公告)日：1996-11-12
申请号：US382358
申请日：1995-02-01
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
IPC分类号： B60C1/00 , C08C19/44 , C08F2/04 , C08F2/06 , C08F4/42 , C08F4/48 , C08F36/04 , C08K3/04 , C08L19/00 , C08L101/00 , C08L101/02 , C08F293/00
CPC分类号： C08F4/48 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10T152/10
摘要： A functionalized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
摘要翻译：根据本发明的官能化聚合物包括具有通式AYLi的聚合物分子，其中A是具有通式R 1的含环胺基团是二价亚烷基，氧基或氨基亚烷基或取代的亚烷基，其具有 6至约20个碳原子; R2是具有约2-约20个碳原子的直链，支链或环 - 亚烷基; Y是二价聚合物基团，Li是与Y的碳原子键合的锂原子。

17. 发明授权

US5521309A Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same 失效
标题翻译：叔氨基烯丙基或二甲苯基锂引发剂及其制备方法
公开(公告)号：US5521309A
公开(公告)日：1996-05-28
申请号：US363111
申请日：1994-12-23
申请人： Thomas A. Antkowiak , James E. Hall , David F. Lawson , John R. Schreffler , Mark L. Stayer, Jr.
发明人： Thomas A. Antkowiak , James E. Hall , David F. Lawson , John R. Schreffler , Mark L. Stayer, Jr.
IPC分类号： B60C1/00 , C08C19/44 , C08F4/08 , C08F4/42 , C08F4/48 , C08F8/00 , C08F10/00 , C08F10/08 , C08F10/14 , C08F12/00 , C08F12/04 , C08F36/04 , C08K3/00 , C08K3/02 , C08K3/04 , C08L3/04 , C08L15/00 , C08L23/18 , C08L25/04 , C08L101/00 , C07D295/04 , C07C211/21
CPC分类号： C08F12/04 , C08C19/44 , C08F36/04 , Y02T10/862 , Y10T152/10495
摘要： An anionic polymerization initiator includes the C-lithio reaction product of an organolithium compound and a tertiary-amino allyllithium or a tertiary-amino xylyllithium. When used in an anionic polymerization, a functional group from the initiator is incorporated onto the head of the growing polymer and a lithium atom is incorporated at the "living" end of the polymer chain prior to quenching. The initiator may be used to polymerize a monomer(s) including diolefin monomers, monovinyl aromatic monomers and trienes, and the living ends of the polymers are effectively maintained even at temperatures of up to 300.degree. F. and higher. Such polymers exhibit an increased efficiency in coupling termination reactions, and products prepared from such polymers exhibit improved hysteresis characteristics. Products such as tires and the like can be prepared from such polymers and from vulcanizable elastomer compositions employing the polymers.
摘要翻译：阴离子聚合引发剂包括有机锂化合物和叔氨基烯丙基锂或叔氨基二羟基锂的C - 锂反应产物。当用于阴离子聚合时，将来自引发剂的官能团引入生长的聚合物的头部上，并且在淬火之前将锂原子并入聚合物链的“活性”端。引发剂可以用于聚合包含二烯烃单体，单乙烯基芳族单体和三烯的单体，并且甚至在高达300°F或更高的温度下也有效地保持聚合物的活性末端。这种聚合物表现出增加的偶联终止反应的效率，并且由这种聚合物制备的产物表现出改善的滞后特性。诸如轮胎等的产品可以由这样的聚合物和使用聚合物的可硫化的弹性体组合物制备。

18. 发明授权

US5500447A Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效
公开(公告)号：US5500447A
公开(公告)日：1996-03-19
申请号：US469125
申请日：1995-06-06
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr.
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr.
IPC分类号： C08F4/08 , C07F1/02 , C08F4/42 , C08F4/46 , C08F4/48 , C08F236/04 , C08F236/10
CPC分类号： C07F1/02
摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.

19. 发明授权

US5496940A Alkyllithium compounds containing cyclic amines and their use in polymerization 失效
标题翻译：含有环胺的烷基锂化合物及其在聚合反应中的应用
公开(公告)号：US5496940A
公开(公告)日：1996-03-05
申请号：US382477
申请日：1995-02-01
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
IPC分类号： C07F1/02 , C08F4/00 , C08F4/42 , C08F4/48 , C08F36/06 , C07D227/04 , C07D223/02
CPC分类号： C07F1/02
摘要： An organolithium compound according to the present invention containing a cyclic amino group, has the general formula: ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and the lithium, Li, is bonded directly to a carbon atom of R.sub.2. A method of preparing an organolithium compound containing a cyclic amino group, comprising reacting a cyclic amino organo halide having the general formula ##STR2## where R.sub.1 and R.sub.2 are as above, and X is bromine or chlorine bonded directly to a carbon atom of R.sub.2, with a lithium reactant selected from lithium metal or an organolithium compound.
摘要翻译：具有环状氨基的本发明的有机锂化合物具有以下通式：其中R 1是二价亚烷基，氧基或氨基亚烷基或具有6至约20个碳原子的取代的亚烷基; R2是具有约2-约20个碳原子的直链，支链或环 - 亚烷基; 锂直接与R2的碳原子键合。一种制备含有环状氨基的有机锂化合物的方法，包括使具有通式“IMAGE”的环状氨基有机卤化物，其中R1和R2如上所述，X是直接与R 2的碳原子键合的溴或氯，与选自锂金属或有机锂化合物的锂反应物。

20. 发明授权

US5274106A Amino-substituted aryllithium compounds as anionic polymerization initiators 失效
标题翻译：氨基取代的芳基锂化合物作为阴离子聚合引发剂
公开(公告)号：US5274106A
公开(公告)日：1993-12-28
申请号：US814935
申请日：1991-12-30
申请人： David F. Lawson , Thomas A. Antkowiak , Mark L. Stayer, Jr. , John R. Schreffler , Hideki Komatsu
发明人： David F. Lawson , Thomas A. Antkowiak , Mark L. Stayer, Jr. , John R. Schreffler , Hideki Komatsu
IPC分类号： B60C1/00 , C08F4/42 , C08F4/48 , C08F12/00 , C08F12/02 , C08F36/04 , C08K3/00 , C08K3/02 , C08K3/04 , C08L9/00 , C07D233/02 , C07C211/01
CPC分类号： C08F4/484 , B60C1/0016 , C08F36/04
摘要： A vulcanizable elastomeric compound and products such as pneumatic tires and the like, are formed from a functionalized polymer having a functional group derived from an anionic polymerization initiator. The anionic polymerization initiator comprises the general formula ##STR1## where R.sup.1 -R.sup.5 are the same or different and are selected from the group consisting of hydrogen; alkyls having from alkyls having from 1 to about 12 carbon atoms; aralkyls having from 7 to about 20 carbon atoms; dialkylaminos having from 2 to about 20 carbon atoms; and, dialkylaminoalkyls having from 3 to about 20 carbon atoms. At least one of R.sup.1 -R.sup.5 is selected from the group consisting of the dialkylaminos and the dialkylaminoalkyls. Methods of the present invention include preparing functionalized polymers and reducing the hysteresis of vulcanizable elastomeric compounds.

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