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11. 发明授权

US4057487A Fluid coking process 失效
标题翻译：流体焦化工艺
公开(公告)号：US4057487A
公开(公告)日：1977-11-08
申请号：US706218
申请日：1976-07-19
申请人： William J. Metrailer , Joseph P. Matula
发明人： William J. Metrailer , Joseph P. Matula
IPC分类号： C10B55/10 , C10G9/32
CPC分类号： C10B55/10
摘要： A hydrocarbonaceous oil is introduced to a quench and scrubbing zone mounted on a fluid coking reactor. Heat from the coker vapor product vaporizes a portion of the hydrocarbonaceous oil. The unvaporized portion of the oil is used to quench and scrub the coker vapor product. The bottoms fraction of the quench and scrubbing zone is passed to a vacuum distillation zone to recover a heavy oil fraction and to produce a vacuum residuum for use as coker feed.
摘要翻译：将烃油引入安装在流化焦化反应器上的骤冷和洗涤区。来自焦化蒸气产物的热量蒸发出一部分含烃油。油的未蒸发部分用于淬火和洗涤焦化蒸气产物。骤冷和洗涤区的底部馏分通入真空蒸馏区，以回收重油馏分，并产生用作焦化器进料的真空渣油。

12. 发明授权

US4325815A Catalytic fluid coking and gasification process 失效
标题翻译：催化液焦化和气化过程
公开(公告)号：US4325815A
公开(公告)日：1982-04-20
申请号：US183435
申请日：1980-09-02
申请人： William J. Metrailer
发明人： William J. Metrailer
IPC分类号： C10G9/32 , C10B55/10 , C10J3/54 , C10G9/28
CPC分类号： C10J3/54 , C10B55/10 , C10J3/482 , C10J3/78 , C10K1/024 , C10K3/04 , C10J2300/093 , C10J2300/0933 , C10J2300/0943 , C10J2300/0946 , C10J2300/0956 , C10J2300/0959 , C10J2300/0966 , C10J2300/0976 , C10J2300/1606 , C10J2300/1807
摘要： An integrated catalytic fluid coking and gasification process is provided in which a portion of the coke produced in the coker is steam gasified to produce a hydrogen-containing gas and a catalytic partially gasified coke. Subsequently, a portion of the catalytic partially gasified coke is burned to provide heated partially gasified coke which is recycled to the gasification zone. A portion of the catalytic partially gasified coke is passed from the gasification zone to the coker to contact the coker vapor phase product comprising normally liquid hydrocarbons and to crack at least a portion of the normally liquid hydrocarbons. Optionally, solid fines recovered from the gaseous effluent of the gasification zone may be recycled to the carbonaceous chargestock of the coker.
摘要翻译：提供了一种综合的催化流体焦化和气化方法，其中在焦化器中产生的一部分焦炭被蒸汽气化以产生含氢气体和催化部分气化的焦炭。随后，一部分催化部分气化的焦炭被燃烧以提供加热的部分气化的焦炭，其被再循环到气化区。催化部分气化的焦炭的一部分从气化区通入焦化器，以与包含常规液体烃的焦化气相产物接触并裂解至少一部分常规液体烃。任选地，从气化区的气态流出物回收的固体细粉可以再循环到焦化器的碳质装料中。

13. 发明授权

US4269696A Fluid coking and gasification process with the addition of cracking catalysts 失效
标题翻译：流化焦化和气化过程中加入裂化催化剂
公开(公告)号：US4269696A
公开(公告)日：1981-05-26
申请号：US92471
申请日：1979-11-08
申请人： William J. Metrailer
发明人： William J. Metrailer
IPC分类号： C10G9/32 , C10G11/18 , C10G51/04
CPC分类号： C10G9/32 , C10G11/18
摘要： An integrated fluid coking and gasification process is provided in which a solid cracking catalyst is added to the coker chargestock and in which a partially gasified coke matrix comprising the cracking catalyst is recycled to the coker vapor phase product.
摘要翻译：提供一种综合流体焦化和气化方法，其中将固体裂化催化剂加入到焦化器料料中，其中将包含裂化催化剂的部分气化的焦炭基体再循环到焦化器气相产物中。

14. 发明授权

US4244805A Liquid yield from pyrolysis of coal liquefaction products 失效
标题翻译：煤液化产物热解产生液体产物
公开(公告)号：US4244805A
公开(公告)日：1981-01-13
申请号：US45683
申请日：1979-06-05
申请人： William J. Metrailer
发明人： William J. Metrailer
IPC分类号： C10G1/00 , C10G9/28 , C10G57/00
CPC分类号： C10G1/002
摘要： The quantity and quality of liquids produced from solid coal can be enhanced by a process comprising a liquefaction zone and a pyrolysis reactor, preferably a fluid coking zone, wherein the heavy liquids obtained in the pyrolysis reactor, e.g., 1000.degree. F.+ materials having a Conradson Carbon content of at least 15 wt. % are recycled to the liquefaction zone, rather than to the pyrolysis reactor, for further treatment under hydrogenation conditions and, consequently, conversion of the heavy liquids to lower boiling liquids which may be removed from the pyrolysis reactor feed by distillation is achieved.
摘要翻译：可以通过包括液化区和热解反应器，优选流体焦化区的方法来提高从固体煤产生的液体的量和质量，其中在热解反应器中获得的重液体，例如1000°F。具有 Conradson碳含量至少为15wt。％被再循环到液化区而不是热解反应器，用于在氢化条件下进一步处理，从而实现重液体转化成可通过蒸馏从热解反应器进料中除去的低沸点液体。

15. 发明授权

US4178227A Combination hydroconversion, fluid coking and gasification 失效
标题翻译：组合加氢转化，流化焦化和气化
公开(公告)号：US4178227A
公开(公告)日：1979-12-11
申请号：US913394
申请日：1978-06-07
申请人： William J. Metrailer , Roby Bearden, Jr. , Clyde L. Aldridge
发明人： William J. Metrailer , Roby Bearden, Jr. , Clyde L. Aldridge
IPC分类号： C10B55/10 , C10G1/00 , C10G1/08 , C10G47/20 , C10G69/06 , C10J3/54 , C10G37/00
CPC分类号： C10G47/20 , C10B55/10 , C10G1/002 , C10G1/08 , C10G1/086 , C10G69/06 , C10J3/482 , C10J3/54 , C10J3/721 , C10J3/78 , C10J3/84 , C10J2300/0906 , C10J2300/093 , C10J2300/0943 , C10J2300/0956 , C10J2300/0959 , C10J2300/0976 , C10J2300/0986 , C10J2300/1807 , C10J2300/1884 , C10J2300/1892
摘要： A combination slurry hydroconversion, coking and coke gasification process is provided wherein solid fines having an average particle size of less than 10 microns in diameter or the ashes thereof recovered from a gaseous product derived from the coke gasification are used as a catalyst in the hydroconversion stage in combination with a catalyst produced from an oil soluble metal compound in situ in the chargestock of the hydroconversion zone.
摘要翻译：提供了一种组合浆料加氢转化，焦化和焦炭气化方法，其中直径小于10微米的固体细粉或其衍生自焦炭气化的气态产物回收的灰分在加氢转化阶段用作催化剂与在加氢转化区的原料中原位由油溶性金属化合物制备的催化剂组合。

16. 发明授权

US4036750A Use of activated fluid coke to remove organic contaminants from waste waters 失效
标题翻译：使用活性流体焦炭从废水中去除有机污染物
公开(公告)号：US4036750A
公开(公告)日：1977-07-19
申请号：US542587
申请日：1975-01-20
申请人： Stanley E. Jaros , William J. Metrailer
发明人： Stanley E. Jaros , William J. Metrailer
IPC分类号： B01D15/02 , B01D17/02 , C01B31/08 , C01B31/10 , C02F1/28
CPC分类号： B01D17/0202 , B01D15/02 , C01B31/087 , C01B31/10 , C02F1/283
摘要： This invention relates to a novel activated fluid coke composition, a method for forming same, and an improved process for removing organic material from waste water by contacting said waste water under adsorption conditions with said activated fluid coke. The activated fluid coke may be prepared by contacting fluid coke with a gaseous mixture containing steam at temperatures of at least about 1500.degree. F. for a period of time sufficient to convert at least 35 weight % of the fluid coke to gaseous products. The activated fluid coke so formed preferably has a total surface area of at least 400 square meters per gram, and a pore volume of at least 0.20 cubic centimeters per gram. The large pore volume and large total surface area, along with the particle size, particle size distribution, particle shape, particle density and attrition resistance of the activated fluid coke, result in said activated fluid coke exhibiting excellent properties as an adsorbent, particularly for removing organic materials from waste water streams.
摘要翻译：本发明涉及一种新型的活化流体焦炭组合物，其形成方法，以及通过使吸附条件下的所述废水与所述活化的流体焦炭接触而从废水中除去有机材料的改进方法。活化的流体焦炭可以通过使流体焦炭与至少约1500°F温度的蒸汽的气体混合物接触足以将至少35重量％的流体焦炭转化为气体产物的时间来制备。所形成的活化流体焦炭优选具有至少400平方米/克的总表面积，和至少0.20立方厘米/克的孔体积。大的孔体积和大的总表面积以及活性流体焦炭的粒度，粒度分布，颗粒形状，颗粒密度和耐磨性导致所述活化流体焦炭作为吸附剂显示出优异的性能，特别是用于除去来自废水流的有机物质。

17. 发明授权

US4007092A Process for producing low sulfur coke 失效
标题翻译：生产低硫焦炭的方法
公开(公告)号：US4007092A
公开(公告)日：1977-02-08
申请号：US559588
申请日：1975-03-18
申请人： William J. Metrailer , Walter Weissman
发明人： William J. Metrailer , Walter Weissman
IPC分类号： C10B55/10
CPC分类号： C10B55/10
摘要： A low sulfur coke product is obtained in an integrated fluid coking and gasification process in which an oxygen-containing gas is introduced into the upper portion of the gasification zone and steam is introduced into the lower portion of the gasification zone. The desired degree of coke desulfurization is controlled by controlling the thickness of the gasifier coke layer on the gaseous reactor leaving solids per pass.
摘要翻译：在其中将含氧气体引入气化区的上部并将蒸汽引入气化区的下部的集成流体焦化和气化过程中获得低硫焦炭产物。焦炭脱硫的期望程度通过控制气态反应器上的气化器焦炭层的厚度来控制，每次通过留下固体。

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