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11. 发明申请

US20090156755A1 Crosslinkable Silicone Coating Compositions 审中-公开
标题翻译：可交联硅氧烷涂料组合物
公开(公告)号：US20090156755A1
公开(公告)日：2009-06-18
申请号：US12328795
申请日：2008-12-05
申请人： Christian Herzig , Martina Joachimbauer , Hans Lautenschlager
发明人： Christian Herzig , Martina Joachimbauer , Hans Lautenschlager
IPC分类号： B05D3/10 , C08G77/38
CPC分类号： C08G77/50 , C08L83/04 , C08L83/14 , C09D183/04 , C09D183/14 , C08L83/00
摘要： Crosslinkable silicone coating compositions are prepared from (1) organopolysiloxanes containing alkenyl groups and containing per molecule at least one unit O3-n/2RnSi—Y(SiRnO3-n/2)a (I), at least 2 units R1RbSiO(3-b)/2 (II), and units RcSiO(4-c)/2 (III), where R is a monovalent, SiC-bonded organic radical having 1 to 30 C atoms free from aliphatic carbon-carbon multiple bonds, R1 is an alkenyl radical having 2 to 4 C atoms, and Y is a divalent or trivalent organic radical having 1 to 30 C atoms, with the proviso that the organopolysiloxanes (1) contain units (II) in amounts wherein the concentration of alkenyl radicals R1 is less than 2 meq/g, (2) organopolysiloxanes containing Si-bonded hydrogen atoms, (3) a hydrosilylation catalyst, and (4) optionally, inhibitors. The compositions cure rapidly with few extractables and are very useful in preparing release coatings.
摘要翻译：可交联的硅氧烷涂料组合物由（1）含烯基的有机聚硅氧烷制备，每分子含有至少一个单位<？在线式描述=“在线式”末端=“铅”→O 3 -n / Y（SiRnO3-n / 2）a（I），<？in-line-formula description =“In-line formula”end =“tail”？>至少2个单位<？in-line-formula description =“In 线性公式“end =”lead“？> R1RbSiO（3-b）/ 2（II），<？in-line-formula description =”In-line Formulas“end =”tail“？> and units < -line-formula description =“In-line Formulas”end =“lead”？> RcSiO（4-c）/ 2（III），<？in-line-formula description =“In-line Formulas”end =“tail 其中R是不含脂肪碳 - 碳多重键的1至30个碳原子的一价SiC键合有机基团，R 1是具有2至4个C原子的烯基，Y是二价或三价有机基团具有1至30个C原子，条件是有机聚硅氧烷（1）含有单元（II），其中烯基的浓度 R1小于2meq / g，（2）含有Si键合氢原子的有机聚硅氧烷，（3）氢化硅烷化催化剂和（4）任选的抑制剂。组合物用很少的可萃取物快速固化，并且在制备脱模涂层中非常有用。

12. 发明申请

US20080275205A1 Process For Preparing Aminoalkylpolysiloxanes 审中-公开
公开(公告)号：US20080275205A1
公开(公告)日：2008-11-06
申请号：US12111287
申请日：2008-04-29
申请人： Christian Herzig , Daniel Schildbach
发明人： Christian Herzig , Daniel Schildbach
IPC分类号： C08G77/06 , C08G77/08
CPC分类号： C08G77/388 , C08G77/16
摘要： A process for preparing aminoalkylpolysiloxanes involves (i) mixing (1) aminoalkylsilane hydrolyzate (ARaSiO(3-a)/2)m(R1O1/2)p with (I) (2) linear and/or branched organopolysiloxanes R x  ( OR 1 ) y  SiO 4 - ( x + y ) 2 ( II ) until a dispersion is obtained, where A is a monovalent SiC-bonded hydrocarbon radical containing at least one amino group, a is 0 or 1, m is from 2 to 500, p is at least 2, x is 0, 1, 2 or 3, and y is 0 or 1, and at least 10 silicon atoms on average per molecule are present in the organopolysiloxane (2), (ii) reacting (1) and (2) in dispersion in the presence of a basic catalyst until a substantially clear mixture is obtained, and (iii) neutralizing the basic catalyst.

13. 发明申请

US20080075683A1 Method for Modifying Fibrous Substrates with Siloxan Copolymers 审中-公开
标题翻译：用硅氧烷共聚物改性纤维底物的方法
公开(公告)号：US20080075683A1
公开(公告)日：2008-03-27
申请号：US11570057
申请日：2005-06-02
申请人： Christian Herzig , Richard Becker , Willibald Burger , Thomas Hohberg
发明人： Christian Herzig , Richard Becker , Willibald Burger , Thomas Hohberg
IPC分类号： A61Q5/12 , D06M15/643 , D06M19/00
CPC分类号： A61K8/898 , A61K8/068 , A61K8/893 , A61Q5/02 , A61Q5/06 , A61Q5/12 , C08G77/388 , C08G77/458 , D06M15/3568 , D06M15/643 , D06M15/6436 , D06M15/647 , D06M15/653 , D06M2200/50 , D21H19/32
摘要： Fibrous substrates with exacted properties are copolymer prepared by reacting an Si-H bearing polysiloxane with a compound containing both a hydrosilylatable group and an isocyanate reactive group, followed by reaction with di- or polyisocyanate used at or below the stoichiometric amount of NCO groups.
摘要翻译：具有严格性能的纤维基材是通过使含Si-H的聚硅氧烷与含有可硅烷基化基团和异氰酸酯反应性基团的化合物反应，随后与化学计量量的NCO基团使用的二 - 或多异氰酸酯反应而制备的共聚物。

14. 发明授权

US07319120B2 Hydrophilic copolysiloxanes and method for the production thereof 有权
标题翻译：亲水性共聚硅氧烷及其制造方法
公开(公告)号：US07319120B2
公开(公告)日：2008-01-15
申请号：US10539331
申请日：2003-12-18
申请人： Christian Herzig , Siegfried Dormeier
发明人： Christian Herzig , Siegfried Dormeier
IPC分类号： C08G77/42
CPC分类号： C08G77/46 , C08G18/3275 , C08G18/61 , C08G18/73 , C08G77/452 , C08G77/458
摘要： Easily emulsified hydrophilic copolysiloxanes may be prepared by hydrosilylation employing an Si—H-functional organosiloxane with a compound containing both a hydrosilylatable group and an active hydrogen, and reacting the intermediate thus formed with a di- or polyisocyanate, wherein the reactants employed to produce the intermediate contain less than 2000 ppm water.
摘要翻译：容易乳化的亲水性共聚硅氧烷可以通过使用Si-H官能的有机硅氧烷与含有可氢化可硅烷基的基团和活性氢的化合物进行氢化硅烷化反应制备，并使由此形成的中间体与二异氰酸酯或多异氰酸酯反应，其中用于制备中间体含有少于2000ppm的水。

15. 发明授权

US07074950B2 Process for preparing organosilicon compounds 有权
标题翻译：制备有机硅化合物的方法
公开(公告)号：US07074950B2
公开(公告)日：2006-07-11
申请号：US11007423
申请日：2004-12-08
申请人： Christian Ochs , Christian Herzig
发明人： Christian Ochs , Christian Herzig
IPC分类号： C07F7/04
CPC分类号： C08G77/38 , C08G77/06 , C08G77/46
摘要： The present invention relates to a process for adding Si-bonded hydrogen to aliphatically unsaturated compounds containing carbon-carbon multiple bonds and ether oxygen atoms in the presence of carbinol groups, wherein the reaction mixture comprises, as a further component, at least one cyclic ether.
摘要翻译：本发明涉及在甲醇基团存在下，将含硅键合氢加成到含有碳 - 碳多键和醚氧原子的脂族不饱和化合物的方法，其中反应混合物作为另外的组分包含至少一种环醚。

16. 发明申请

US20060020082A1 Defoamer compositions 失效
标题翻译：消泡剂组合物
公开(公告)号：US20060020082A1
公开(公告)日：2006-01-26
申请号：US11176617
申请日：2005-07-07
申请人： Holger Rautschek , Christian Herzig , Richard Becker
发明人： Holger Rautschek , Christian Herzig , Richard Becker
IPC分类号： C08L83/04 , C09K3/00 , B01D19/04
CPC分类号： B01D19/0409 , C11D3/0026 , C11D3/373
摘要： Compositions comprising (A) an organosilicon compound of the formula Ra(R1O)bR2cSiO(4-a-b-c)/2 (I) in which R2 independently denotes a monovalent, SiC-bonded, optionally substituted, aliphatic cyclic or aliphatic branched hydrocarbon radical having at least 3 carbon atoms, R, and R1 are hydrogen or hydrocarbon radicals, the sum a+b+c≦3, the organosilicon compound has at least one unit of the formula (I) with c other than 0, and in at least 50% of all of the units of the formula (I) in the organosilicon compound the sum a+b+c is 2; at least one additive (B) selected from (B1) filler particles and/or (B2) organopolysiloxane resin(s) and optionally (C) an organosilicon compound which has units of the formula (III), R5g(R6O)hSiO(4-g-h)/2 where R5 and R6 are hydrogen or a hydrocarbon radical, g+h≦3 and in at least 50% of the units (III), g+h=2, are highly effective and long lasting defoamers.
摘要翻译：包含（A）式（Ⅳ）的有机硅化合物的组合物，其中式（？）在线式描述=“在线式” （4-abc）/ 2（ⅰ）？in in in in in in in in in in in in in in in in in in in in in in in in in in in in in in in in in in -line-formula description =“In-line Formulas”end =“tail”？>其中R 2独立地表示一价，SiC键合的任选取代的脂族环状或脂肪族支链烃基，其具有至少3个碳原子，R 1和R 1是氢或烃基，总和a + b + c <3，有机硅化合物具有至少一个式（I）单元与 c以外，在有机硅化合物中，所有式（I）的单元的至少50％的总和a + b + c为2; 至少一种选自（B1）填料颗粒和/或（B2）有机聚硅氧烷树脂的添加剂（B）和（C）具有式（III）单元的有机硅化合物，描述=“在线公式”end =“lead”？> 5 > 其中R 5和 R 6是氢或烃基，g + h <3，并且在至少50％的单元（III）中，g + h = 2是高效且持久的消泡剂。

17. 发明申请

US20050131243A1 Process for preparing highly viscous organopolysiloxanes 有权
公开(公告)号：US20050131243A1
公开(公告)日：2005-06-16
申请号：US11007387
申请日：2004-12-08
申请人： Christian Herzig , Siegfried Dormeier
发明人： Christian Herzig , Siegfried Dormeier
IPC分类号： C08G77/26 , C07F7/08 , C07F9/02 , C07F7/21
CPC分类号： C08G77/26 , C07F7/0874
摘要： Process for preparing highly viscous organopolysiloxanes by reacting siloxanes (1) composed of units of the general formula A a ⁢ R c ⁡ ( OR 1 ) d ⁢ SiO 4 - ( a + c + d ) 2 ( I ) where A is a nitrogen-containing Si—C-bonded radical, R is a C1-18 hydrocarbon radical R1 is hydrogen or a C1-8 alkyl radical, a and d are 0 or 1, c is 0, 1, 2 or 3, a+c+d is

18. 发明授权

US5985462A Organosilicon compounds having Si-bonded hydrogen atoms in crosslinkable compositions 失效
标题翻译：在可交联组合物中具有Si键合的氢原子的有机硅化合物
公开(公告)号：US5985462A
公开(公告)日：1999-11-16
申请号：US881410
申请日：1997-06-24
申请人： Christian Herzig , Elfriede Rieger
发明人： Christian Herzig , Elfriede Rieger
IPC分类号： C08G77/50 , C08L83/04 , C09D183/04 , B32B9/04
CPC分类号： C08G77/50 , C08L83/04 , C09D183/04 , C08G77/12 , C08G77/20 , Y10T428/31663
摘要： A novel crosslinkable composition comprising(A) an organosilicon compound having radicals containing aliphatic carbon-carbon multiple bonds,(B) an organosilicon compound having Si-bonded hydrogen atoms,(C) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bonds and, optionally,(D) agents which retard the addition of Si-bonded hydrogen onto aliphatic multiple bonds at room temperature,wherein the organosilicon compounds having Si-bonded hydrogen atoms (B) used are ones comprising(a) on average per molecule, at least one structural unit of the formula--Z--SiR.sub.x (OSiR.sub.3-a H.sub.a).sub.3-x (I), whereR is an identical or different monovalent, optionally halogenated hydrocarbon radical which is free of aliphatic multiple bonds and has from 1 to 8 carbon atoms per radical,Z is a divalent aliphatic hydrocarbon radical having from 2 to 12 carbon atoms per radical,a is 1, 2 or 3, andx is 0 or 1.
摘要翻译：一种新型的可交联组合物，其包含（A）具有含有脂族碳 - 碳多重键的基团的有机硅化合物，（B）具有Si键合氢原子的有机硅化合物，（C）促进将Si键合的氢加成到脂族多个键和任选的（D）试剂，其阻止在室温下将Si键合的氢加成到脂族多重键上，其中所用的具有Si键合的氢原子的有机硅化合物（B）是包含（a）平均每个分子，式-Z-SiRx（OSiR 3-aHa）3-x（I）的至少一个结构单元，其中R是不含脂族多键的相同或不同的单价卤代烃基，并且具有1 每个基团为8个碳原子，Z为每个基团具有2至12个碳原子的二价脂族烃基，a为1,2或3，x为0或1。

19. 发明授权

US5474709A Process for defoaming and/or degassing organic systems 失效
标题翻译：消泡和/或脱气有机系统的工艺
公开(公告)号：US5474709A
公开(公告)日：1995-12-12
申请号：US975942
申请日：1993-02-24
申请人： Christian Herzig , Willibald Burger , Ernst Innertsberger , Peter Huber , Martina Blochl
发明人： Christian Herzig , Willibald Burger , Ernst Innertsberger , Peter Huber , Martina Blochl
IPC分类号： B01D19/04 , C08G77/22 , C08G77/38 , C08G77/46
CPC分类号： B01D19/0409 , C08G77/38 , C08G77/46
摘要： A process for defoaming and/or degassing organic systems by addition of an organopolysiloxane-containing anti-foaming agent to the organic system is characterized by the fact that the organopolysiloxane used is one composed of siloxane units having the general formulae (I) and (II), in which R is a univalent hydrocarbon residue with 1 to 18 carbon atoms per residue; A is a residue having the general formula (a), in which R.sup.1 is a residue having the formula --CR.sup.3 H--, where R.sup.3 stands for a hydrogen atom or a univalent organic residue; R.sup.2 is a residue having the formulae --CR.sup.4 H--CH.sub.2 -- or --CH.sub.2 CH.sub.2 CH.sub.2 -- where R.sup.4 stands for a hydrogen atom or a univalent organic residue; v and w represent each O or an integer, the sum of v+w being in average 0 to 16; x and y represent each 0 or 1, the sum x+y being 1 or 2; a equals 1,2 or 3; b equals 0, 1 or 2 and c equals 1 or 2, the sum b+c not exceeding 3.
摘要翻译： PCT No.PCT / EP91 / 01896 Sec。 371日期：1993年2月24日 102（e）日期1993年2月24日PCT 1991年10月4日PCT PCT。出版物WO92 / 05854 日期为1992年04月16日。通过向有机体系中加入含有机聚硅氧烷的消泡剂来消除和/或脱气有机体系的方法的特征在于所使用的有机聚硅氧烷是由具有一般性的硅氧烷单元式（I）和（II），其中R是每个残基具有1至18个碳原子的一价烃残基; A是具有通式（a）的残基，其中R1是具有式-CR3H-的残基，其中R3代表氢原子或一价有机残基; R2是具有式-CR4H-CH2-或-CH2CH2CH2-的残基，其中R4代表氢原子或一价有机残基; v和w表示每个O或整数，v + w的和平均为0至16; x和y表示0或1，x + y之和为1或2; a等于1,2或3; b等于0,1或2，c等于1或2，总和b + c不超过3。

20. 发明授权

US5231157A Siloxane copolymers containing alkenyloxy groups, a process for preparing the same and their use 失效
标题翻译：含有烯烃基团的硅氧烷共聚物，其制备方法及其使用方法
公开(公告)号：US5231157A
公开(公告)日：1993-07-27
申请号：US648107
申请日：1991-01-31
申请人： Christian Herzig , Doris Gilch
发明人： Christian Herzig , Doris Gilch
IPC分类号： C08G77/20 , C08F290/00 , C08F299/08 , C08G77/22 , C08G77/38 , C08G77/48 , C08L83/04 , C08L83/14 , C09D183/04 , C09D183/07 , C09D183/14
CPC分类号： C09D183/14 , C08G77/38 , C08G77/48 , C08L83/14 , Y10T428/31663
摘要： Novel siloxane copolymers are described having an average of at least two alkenyloxy groups of the formula--OCR.sup.2 .dbd.CH.sup.2 CH.sub.3,in which R.sup.2 represents hydrogen or a methyl radical.These siloxane copolymers are prepared by reacting in a first stage, an organic compound (1) containing more than two aliphatic double bonds of the formula OCHR.sup.2 CR.sup.2 =CH.sub.2 where R.sup.2 is the same as above, with an organopolysiloxane (2) having at least one Si-bonded hydrogen atom per molecule in the presence of a catalyst (3) which promotes addition of the Si-bonded hydrogen to an aliphatic double bond and in a second stage heating the siloxane copolymer in the presence of a catalyst (4) which promotes shifting of the terminal double bond to form copolymers having an internal double bond.
摘要翻译：描述了新的硅氧烷共聚物，其平均具有式-OCR 2 = CH 2 CH 3的至少两个烯氧基，其中R 2表示氢或甲基。这些硅氧烷共聚物通过在第一阶段中与含有至少一个Si的有机聚硅氧烷（2）在第一阶段中反应，所述有机化合物（1）含有多于两个式OCHR2CR2 = CH2的脂族双键，其中R2与上述相同，在催化剂（3）的存在下，每个分子中键合氢原子，其促进将Si键合的氢添加到脂族双键，并且在第二阶段中，在催化剂（4）的存在下加热硅氧烷共聚物，催化剂（4）促进转移的末端双键形成具有内部双键的共聚物。

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