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11. 发明申请

US20080146775A1 PROCESS FOR PRODUCING POLYESTER ETHER POLY- OR MONO-OL 有权
标题翻译：生产聚酯多元醇或单酚的方法
公开(公告)号：US20080146775A1
公开(公告)日：2008-06-19
申请号：US12032052
申请日：2008-02-15
申请人： Shigeki UEMORI , Shigeru Ikai , Chitoshi Suzuki
发明人： Shigeki UEMORI , Shigeru Ikai , Chitoshi Suzuki
IPC分类号： C08G63/82
CPC分类号： C08G63/823 , C08G18/4887 , C08G63/06 , C08G63/664
摘要： To provide a process for producing a polyester ether poly- or mono-ol having a narrow molecular weight distribution, which is obtained by copolymerizing an initiator having hydroxyl groups with a cyclic ester compound and an alkylene oxide.It is possible to produce a polyester ether poly- or mono-ol having a molecular distribution (Mw/Mn) of from 1.02 to 1.4 by copolymerizing a cyclic ester compound which carbon number is from 3 to 9 and an alkylene oxide which carbon number is from 2 to 20 with an initiator having from 1 to 12 hydroxyl groups and having a number average molecular weight (Mn) of from 18 to 20,000 in the presence of a double-metal cyanide complex catalyst is having tert-butyl alcohol as at least a part of an organic ligand.
摘要翻译：提供通过使具有羟基的引发剂与环状酯化合物和烯化氧共聚获得的具有窄分子量分布的聚酯醚聚 - 或一元醇的方法。可以通过共聚碳数为3〜9的环状酯化合物和碳原子数为3〜9的环氧烷烃来制造分子量分布（Mw / Mn）为1.02〜1.4的聚酯醚聚 - 或一元醇在双金属氰化物配合物催化剂的存在下，具有1至12个羟基并且数均分子量（Mn）为18至20,000的引发剂的2-20元素具有至少一种叔丁醇部分有机配体。

12. 发明授权

US07012164B2 Method for continuously producing a polyether 失效
标题翻译：连续生产聚醚的方法
公开(公告)号：US07012164B2
公开(公告)日：2006-03-14
申请号：US10895063
申请日：2004-07-21
申请人： Kazuhiko Yamada , Nobuyuki Kasahara , Yoshinori Toyota , Chitoshi Suzuki , Shigeru Ikai , Hiroshi Hatano
发明人： Kazuhiko Yamada , Nobuyuki Kasahara , Yoshinori Toyota , Chitoshi Suzuki , Shigeru Ikai , Hiroshi Hatano
IPC分类号： C08G65/28
CPC分类号： C08G65/2696 , C08G65/2663
摘要： A method for precisely producing a polyether having a relatively high molecular weight by means of a double metal cyanide complex catalyst is provided. A method for continuously producing a polyether, which comprises ring opening addition polymerization of an alkylene oxide in the presence of a double metal cyanide complex catalyst, wherein substantially no vapor phase part is present in a reactor.
摘要翻译：提供了一种通过双金属氰化物配合物催化剂精确生产具有较高分子量的聚醚的方法。一种连续生产聚醚的方法，其包括在双金属氰化物配位催化剂存在下环氧烷的开环加成聚合反应，其中在反应器中基本上不存在气相部分。

13. 发明申请

US20050267279A1 Polyether polyol composition and use thereof 失效
标题翻译：聚醚多元醇组合物及其用途
公开(公告)号：US20050267279A1
公开(公告)日：2005-12-01
申请号：US11188888
申请日：2005-07-26
申请人： Chitoshi Suzuki , Hiroki Fukuda , Shigeru Ikai
发明人： Chitoshi Suzuki , Hiroki Fukuda , Shigeru Ikai
IPC分类号： C08G18/48 , C08G65/26 , C08G65/333 , C08G18/30 , C07C41/03
CPC分类号： C08G18/4866 , C08G65/2663 , C08G65/33348
摘要： To provide a polyether polyol composition, whereby the reaction rate with a polyisocyanate can be controlled, and an isocyanate group-terminated prepolymer excellent particularly in storage stability can be given. A polyether polyol composition comprising a polyether polyol obtained by ring-opening polymerization of an alkylene oxide in the presence of a composite metal cyanide complex catalyst, and a phosphoric acid compound comprising a phosphoric acid selected from orthophosphoric acid, polyphosphoric acid and polymetaphosphoric acid, and/or a partial ester of such a phosphoric acid, characterized in that the polyether polyol composition contains metals derived from the composite metal cyanide complex catalyst in an amount of from 1 to 30 ppm based on the polyether polyol, and the above phosphoric acid compound in an amount of from 0.5 to 100 ppm based on the polyether polyol.
摘要翻译：提供一种聚醚多元醇组合物，由此可以控制与多异氰酸酯的反应速率，并且可以给出特别优异的储存稳定性优异的异氰酸酯基封端的预聚物。一种聚醚多元醇组合物，其包含在复合金属氰化物配合物催化剂存在下通过烯化氧的开环聚合获得的聚醚多元醇和包含选自正磷酸，多磷酸和聚偏磷酸的磷酸的磷酸化合物，和 /或这种磷酸的偏酯，其特征在于，所述聚醚多元醇组合物含有以所述聚醚多元醇为基准计，所述金属氰化物配合物催化剂的量为1〜30ppm，上述磷酸化合物为相对于聚醚多元醇为0.5〜100ppm的量。

14. 发明申请

US20100041864A1 DOUBLE METAL CYANIDE COMPLEX CATALYST HAVING ORGANIC LIGAND, PROCESS FOR ITS PRODUCTION AND METHOD FOR PRODUCING POLYETHER POLYOL 审中-公开
标题翻译：具有有机配体的双金属氰化物复合催化剂及其生产方法及其生产聚醚多元醇的方法
公开(公告)号：US20100041864A1
公开(公告)日：2010-02-18
申请号：US12575501
申请日：2009-10-08
申请人： Yoshinobu KADOWAKI , Shigeru Ikai , Yasuyuki Sasao , Kazuhiko Yamada , Kenji Yamada
发明人： Yoshinobu KADOWAKI , Shigeru Ikai , Yasuyuki Sasao , Kazuhiko Yamada , Kenji Yamada
IPC分类号： C08G65/02 , B01J31/12
CPC分类号： C08G65/2663 , B01J27/26 , B01J31/2226 , B01J31/26 , B01J37/031
摘要： To provide a process for producing, simply and with high reproducibility, a double metal cyanide complex catalyst having an organic ligand, which has a high catalytic activity, a small particle size and a high particle size uniformity.A process for producing a double metal cyanide complex catalyst having an organic ligand, comprising (a) a step of contacting an aqueous metal halide compound solution and an aqueous transition metal cyanide compound solution in a laminar flow state to obtain a liquid containing a double metal cyanide complex, and (b) a step of mixing the liquid containing a double metal cyanide complex, and an organic ligand, to obtain a dispersion containing a double metal cyanide complex catalyst having an organic ligand.
摘要翻译：为了提供具有高催化活性，小粒度和高粒度均匀性的具有有机配体的双金属氰化物配合物催化剂，简单且高重现性的方法。一种制备具有有机配体的双金属氰化物配合物催化剂的方法，包括（a）以层流状态接触含水金属卤化物化合物溶液和过渡金属氰化物水溶液的步骤，以获得含有双金属的液体氰化物络合物，和（b）混合含有双金属氰化物络合物和有机配体的液体的步骤，以获得含有具有有机配体的双金属氰化物配合物催化剂的分散体。

15. 发明授权

US4365048A Method for polymerizing .alpha.-olefin 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US4365048A
公开(公告)日：1982-12-21
申请号：US263573
申请日：1981-05-14
申请人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
发明人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
IPC分类号： C08F4/00 , C08F4/02 , C08F4/50 , C08F4/58 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00
摘要： Poly.alpha.-olefin, for example, polypropylene, is produced with an excellent yield by bringing, in the presence of an organic acid ester, a feed, containing at least one .alpha.-olefin having 3 or more carbon atoms, for example, propylene, into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound of the formula, R.sup.3 MgX wherein R.sup.3 =C.sub.1-8 alkyl and X=halogen, with a reaction product of an aluminium halide with an organic silicon compound of the formula, R.sub.n.sup.1 Si(OR.sup.2).sub.4-n, wherein R.sup.1 =C.sub.1-8 alkyl or phenyl, R.sup.2 =C.sub.1-8 alkyl, n=1, 2 or 3, (b) bringing the resultant reaction product into a first contact with titanium tetrahalide, (c) treating the resultant titanium-containing solid product with an organic acid ester, and, finally, (d) bringing the treated solid product into a second contact with titanium tetrahalide, and; (B) another catalytic ingredient consisting of a trialkyl aluminium of the formula, AlR.sub.3.sup.4 wherein R.sup.4 =C.sub.2-6 alkyl.
摘要翻译：通过在有机酸酯的存在下，含有至少一种具有3个或更多个碳原子的α-烯烃的进料，例如丙烯，丙烯，与催化剂接触，该催化剂包含（A）通过使下式的格利雅化合物，其中R3 = C1-8烷基和X =卤素的R3MgX与卤化铝的反应产物与 Rn1Si（OR2）4-n的有机硅化合物，其中R1 = C1-8烷基或苯基，R2 = C1-8烷基，n = 1,2或3，（b）将所得反应产物置于首先与四卤化钛接触，（c）用有机酸酯处理所得的含钛固体产物，最后，（d）使经处理的固体产物与四卤化钛进行第二次接触; （B）由下式的三烷基铝，其中R 4 = C 2-6烷基的AlR 34组成的另一种催化成分。

16. 发明授权

US4324877A Method for polymerizing .alpha.-olefin 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US4324877A
公开(公告)日：1982-04-13
申请号：US208302
申请日：1980-11-19
申请人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Masanori Tamura , Sakae Yuasa
发明人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Masanori Tamura , Sakae Yuasa
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F4/02 , C08F10/06
CPC分类号： C08F10/00
摘要： An .alpha.-olefin polymer having an excellent H.I. is produced with a high yield by bringing, in the presence of an organic acid ester, a feed containing at least one .alpha.-olefin, having 3 or more carbon atoms, into contact with a catalyst composed of:a solid catalytic ingredient which has been prepared in such a manner that an aluminosiloxy compound of the formula, ##STR1## wherein X.sup.1 represents a chlorine atom, a bromine atom or an iodine atom, is reacted with a Grignard compound of the formula R.sup.1 MgX.sup.2 [II] wherein R.sup.1 represents an alkyl radical having 1 to 8 carbon atoms and X.sup.2 represents a halogen atom, the resultant solid reaction product is brought into contact with a titanium tetrahalide, the resultant titanium-containing solid product is treated with an organic acid ester, and the treated solid product is brought into contact with a titanium tetrahalide; anda trialkyl aluminum.
摘要翻译：具有优异的H.I.的α-烯烃聚合物。通过在有机酸酯的存在下，将含有至少一种具有3个或更多个碳原子的α-烯烃的进料与由以下物质组成的催化剂接触来制备：高固含量的固体催化成分以如下方式制备：其中X1表示氯原子，溴原子或碘原子的下式的铝硅氧烷化合物，其中X1表示氯原子，溴原子或碘原子，与式R1MgX2 [II]的格利雅化合物反应，其中R1表示具有1至8个碳原子的烷基，X 2表示卤素原子，使所得固体反应产物与四卤化钛接触，所得含钛固体产物用有机酸酯处理，并将处理过的固体产物与四卤化钛接触; 和三烷基铝。

17. 发明授权

US06627576B2 Double metal cyanide complex catalyst for ring opening polymerization of alkylene oxide and its production process 失效
公开(公告)号：US06627576B2
公开(公告)日：2003-09-30
申请号：US10228919
申请日：2002-08-28
申请人： Kayoko Sugiyama , Shigeru Ikai
发明人： Kayoko Sugiyama , Shigeru Ikai
IPC分类号： B01J2726
CPC分类号： C08G65/2663 , B01J27/26
摘要： A process for producing a double metal cyanide complex catalyst for ring opening polymerization of alkylene oxide, which comprises subjecting a substantially crystalline double metal cyanide compound to a contact treatment by heating at from 45 to 125° C. with an aqueous solution containing an organic ligand and a metal salt, and then separating the resulting solid from the obtained slurry.

18. 发明授权

US6071845A Catalyst for producing conjugated diene polymer 失效
标题翻译：用于制备共轭二烯聚合物的催化剂
公开(公告)号：US6071845A
公开(公告)日：2000-06-06
申请号：US761697
申请日：1996-12-06
申请人： Nobuhiro Tsujimoto , Michinori Suzuki , Kei Tsukahara , Shigeru Ikai , Koji Imaoka , Yoshiyuki Kai , Jun Yamashita
发明人： Nobuhiro Tsujimoto , Michinori Suzuki , Kei Tsukahara , Shigeru Ikai , Koji Imaoka , Yoshiyuki Kai , Jun Yamashita
IPC分类号： C07F17/00 , C08F4/625 , C08F4/639 , C08F4/6392 , C08F4/68 , C08F10/00 , C08F36/04
CPC分类号： C08F10/00 , C07F17/00 , C08F36/04 , C08F4/68 , C08F4/63908 , C08F4/63912 , C08F4/6392 , Y10S526/943
摘要： A catalyst obtained by contacting (A) a compound of a transition metal of the group V of the Periodic Table represented by formula (I):R.sub.n M(O).sub.m X.sub.p .cndot.L.sub.a (I)wherein M represents a transition metal of the group V of the Periodic Table; R represents a cyclopentadienyl group, a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a fluorenyl group or a substituted fluorenyl group; O represents an oxygen atom; X represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group, an aryloxy group or an amido group; L represents a Lewis basic compound; n, m, and p each represent an integer selected to make a combination of (n=1, m=1, p=2), (n=1, m=0, p=3), (n=2, m=0, p=1) or (n=1, m=0, p=2); and a represents 0, 1 or 2, and (B) at least one of (B1) an ionic compound comprising a non-coordinating anion and a cation and (B2) an aluminoxane, provided that the component (B) is an ionic compound comprising a non-coordinating anion and a cation (B1) when the combination of n, m, and p of the component (A) is (n=2, m=0, p=1) or (n=1, m=0, p=2).
摘要翻译：通过使（A）由式（I）表示的周期表的第V族的过渡金属的化合物：RnM（O）m X pLa（I）与M表示第V族的过渡金属周期表; R表示环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基或取代的芴基; O表示氧原子; X表示氢原子，卤素原子，碳原子数1〜20的烃基，烷氧基，芳氧基或酰胺基; L代表路易斯碱性化合物; n，m和p各自表示选择以使（n = 1，m = 1，p = 2），（n = 1，m = 0，p = 3），（n = = 0，p = 1）或（n = 1，m = 0，p = 2）; 和（B）包含非配位阴离子和阳离子的离子化合物和（B2）铝氧烷中的至少一种，（B）组分（B）是离子化合物当组分（A）的n，m和p的组合为（n = 2，m = 0，p = 1）或（n = 1，m = 1）时，包含非配位阴离子和阳离子（B1） 0，p = 2）。

19. 发明授权

US5939573A Process for preparing di (polycyclic amino) dialkoxysilane 失效
标题翻译：制备二（多环氨基）二烷氧基硅烷的方法
公开(公告)号：US5939573A
公开(公告)日：1999-08-17
申请号：US176539
申请日：1998-10-21
申请人： Shigeru Ikai , Yasuhisa Sakakibara , Toshifumi Fukunaga
发明人： Shigeru Ikai , Yasuhisa Sakakibara , Toshifumi Fukunaga
IPC分类号： C07F7/18 , C07F7/10
CPC分类号： C07F7/1888 , C07F7/1868
摘要： A di(polycyclic amino)dialkoxysilane which is of value as an auxiliary catalyst component for polymerizing an .alpha.-olefin to produce an .alpha.-olefin polymer having a high stereoregularity and a broad molecular weight distribution is prepared by reacting a secondary polycyclic-amine compound with an organomagnesium compound in an ether solvent, to produce a polycyclic-amido magnesium compound, and reacting the polycyclic-amido magnesium compound with a tetraalkoxysilane in a solvent mixture of an ether solvent and an inert hydrocarbon solvent.
摘要翻译：作为用于聚合α-烯烃以产生具有高立构规整性和宽分子量分布的α-烯烃聚合物的辅助催化剂组分的二（多环氨基）二烷氧基硅烷通过使仲多环胺化合物与在醚溶剂中的有机镁化合物，以产生多环酰胺镁化合物，并使多环酰氨基镁化合物与四烷氧基硅烷在醚溶剂和惰性烃溶剂的溶剂混合物中反应。

20. 发明授权

US4435550A Method for polymerizing .alpha.-olefin 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US4435550A
公开(公告)日：1984-03-06
申请号：US356475
申请日：1982-03-09
申请人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
发明人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F4/02 , C08F10/04
CPC分类号： C08F10/00 , Y10S526/904
摘要： Poly-.alpha.-olefin, for example, polypropylene, is produced by subjecting a feed containing an .alpha.-olefin having 3 or more carbon atoms, to a preliminary polymerization at 40.degree. C. or less in the presence of a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound of the formula, R.sup.3 MgX wherein R.sup.3 =C.sub.1-8 alkyl and X=halogen, with a reaction product of an aluminium halide with an organic silicon compound of the formula, R.sub.n.sup.1 Si(OR.sup.2).sub.4-n, wherein R.sup.1 =C.sub.1-8 alkyl or phenyl, R.sup.2 =C.sub.1-8 alkyl, n=0, or 1 to 3, (b) bringing the resultant solid carrier into a first contact with titanium tetrahalide, (c) treating the resultant titanium-containing solid product with an organic acid ester, and, finally, (d) bringing the treated solid product into a second contact with titanium tetrahalide; (B) another catalytic ingredient consisting of a trialkyl aluminium of the formula, AlR.sub.3.sup.4 wherein R.sup.4 =C.sub.2-6 alkyl; and a further catalytic ingredient consisting of an organic acid ester, and then, by subjecting a polymerization mixture containing the above-mentioned catalyst, the preliminary polymer and free .alpha.-olefin to a final polymerization at a temperature above 40.degree. C.
摘要翻译：聚-α-烯烃，例如聚丙烯，是通过使含有3个或更多个碳原子的α-烯烃的原料在40℃或更低的预聚合下，在含有（A ）固体催化成分（a）通过使下式的格利雅化合物，其中R3 = C1-8烷基和X =卤素的R3MgX与卤化铝与下式的有机硅化合物的反应产物Rn1Si（ OR 2）4-n，其中R 1 = C 1-8烷基或苯基，R 2 = C 1-8烷基，n = 0或1至3，（b）使所得固体载体与四卤化钛进行第一次接触，（c ）用有机酸酯处理得到的含钛固体产物，最后（d）使经处理的固体产物与四卤化钛进行第二次接触; （B）由下式的三烷基铝，其中R 4 = C 2-6烷基的AlR 34组成的另一种催化成分; 和由有机酸酯组成的另外的催化成分，然后通过使含有上述催化剂的聚合混合物，预聚合物和游离α-烯烃在40℃以上的温度下进行最终聚合。

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