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11. 发明授权

US06740766B2 Preparation of organochlorosilanes by the silylation of conjugated dienes with trichlorosilane 失效
标题翻译：通过用三氯硅烷甲硅烷基化共轭二烯制备有机氯硅烷
公开(公告)号：US06740766B2
公开(公告)日：2004-05-25
申请号：US10385538
申请日：2003-03-11
申请人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Seung-Hyun Kang
发明人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Seung-Hyun Kang
IPC分类号： C07F708
CPC分类号： C07F7/14 , Y02P20/584
摘要： The present invention relates to a process for preparing organosilicon compounds by the silylation of conjugated dienes and more particularly, to the process for preparing organosilicon compounds expressed by the following Formulas 1a and 1b in high yield, comprising the steps of heating trichlorosilane in the presence of quaternary organophosphonium salt catalystto generate dichlorosilylene (:SiCl2); and silylating the result with linear or cyclic conjugated dienes, wherein R1, R2, R3, R4, R5 and R6 are independently a hydrogen atom, a C1-C6 alkyl, phenyl group, or two functional groups among R1, R2, R3, R4, R5 and R6 may be covalently bonded to each other to form a cyclic compound of C4-C8.
摘要翻译：本发明涉及通过共轭二烯的甲硅烷基化制备有机硅化合物的方法，更具体地说，涉及以高产率由下式1a和1b表示的制备有机硅化合物的方法，包括以下步骤：在存在下加热三氯硅烷季铵有机鏻盐催化剂生成二氯二甲苯（（SiCl2））; 并用线性或环状共轭二烯甲硅烷基化，其中R 1，R 2，R 3，R 4，R 5和R 6独立地是氢原子， R 1，R 2，R 3，R 4，R 5和R 6中的C 6烷基，苯基或两个官能团可以彼此共价键合形成 C4-C8的环状化合物。

12. 发明授权

US08129458B2 Functional reinforcing filler and method of preparing the same 有权
标题翻译：功能性增强填料及其制备方法
公开(公告)号：US08129458B2
公开(公告)日：2012-03-06
申请号：US12704359
申请日：2010-02-11
申请人： Bok Ryul Yoo , Joon Soo Han , Dong Euy Jung , Janghyun Yoo
发明人： Bok Ryul Yoo , Joon Soo Han , Dong Euy Jung , Janghyun Yoo
IPC分类号： B60C1/00 , B32B25/00
CPC分类号： C08K9/06 , B60C1/00 , C08K5/548 , Y02T10/862 , Y10T428/2995 , C08L21/00
摘要： Provided are a functional reinforcing filler and a method of preparing the same, and more particularly, a functional reinforcing filler including inorganic particles having a surface modified by an organic silanepolyol obtained by hydrolyzing an organic alkoxysilane compound and a method of preparing the sane. The functional reinforcing filler has hydrophobicity and reactivity. If the functional reinforcing filler is used to prepare rubber, a coupling agent is not required, and the rubber does not emit volatile organic compounds (VOCs). In particular, a tire prepared using the functional reinforcing filler may have low rolling resistance and excellent wet traction.
摘要翻译：提供功能性增强填料及其制备方法，更具体地，涉及包含通过水解有机烷氧基硅烷化合物而得到的有机硅烷多元醇表面改性的无机粒子的功能性增强填料及其制备方法。功能性增强填料具有疏水性和反应性。如果使用功能性增强填料来制备橡胶，则不需要偶联剂，并且橡胶不会挥发挥发性有机化合物（VOC）。特别地，使用功能性增强填料制备的轮胎可以具有低滚动阻力和优异的湿牵引力。

13. 发明授权

US08742104B2 Saturated N-heterocyclic carbene-ligand metal complex derivatives, preparing method thereof, and preparing method of silane compound by hydrosilylation reaction using the same as catalyst 有权
标题翻译：饱和N-杂环卡宾 - 配体金属络合物衍生物及其制备方法，通过使用与催化剂相同的氢化硅烷化反应制备硅烷化合物的方法
公开(公告)号：US08742104B2
公开(公告)日：2014-06-03
申请号：US12846554
申请日：2010-07-29
申请人： Bok Ryul Yoo , Joon Soo Han , Jang Hyun Yoo
发明人： Bok Ryul Yoo , Joon Soo Han , Jang Hyun Yoo
IPC分类号： C07F15/00 , C08G77/08 , C07D233/02 , C07D239/04 , C07F15/04
CPC分类号： C07F15/00 , C07D233/02 , C07D239/04 , C07F7/14 , C07F15/0006 , C07F15/0086 , C07F15/04 , C08G77/08
摘要： Provided are a saturated N-heterocyclic carbene-ligand metal complex derivative, a method for preparing the same, and a method for preparing a silane compound by hydrosilylation using the same as a catalyst. To describe in more detail, the metal complex derivative has a saturated N-heterocyclic carbene derivative and an olefin ligand at the same time. A silane compound is prepared by hydrosilylation in the presence of the metal complex derivative as a catalyst. The provided metal complex derivative of the present invention has superior stability during hydrosilylation reaction and is capable of effectively performing the hydrosilylation reaction at low temperature even with small quantity. Further, a product with superior regioselectivity may be obtained. In addition, after the hydrosilylation reaction is completed, the metal complex derivative may be recovered and recycled.
摘要翻译：提供饱和的N-杂环卡宾 - 配体金属络合物衍生物，其制备方法，以及通过使用其作为催化剂的氢化硅烷化制备硅烷化合物的方法。为了更详细地描述，金属络合物衍生物同时具有饱和的N-杂环卡宾衍生物和烯烃配体。在金属络合物衍生物作为催化剂存在下，通过氢化硅烷化制备硅烷化合物。所提供的本发明的金属络合物衍生物在氢化硅烷化反应中具有优异的稳定性，并且即使在少量的情况下也能够在低温下有效地进行氢化硅烷化反应。此外，可以获得具有优异区域选择性的产品。此外，氢化硅烷化反应完成后，金属络合物衍生物可以回收再循环。

14. 发明申请

US20110160454A1 SATURATED N-HETEROCYCLIC CARBENE-LIGAND METAL COMPLEX DERIVATIVES, PREPARING METHOD THEREOF, AND PREPARING METHOD OF SILANE COMPOUND BY HYDROSILYLATION REACTION USING THE SAME AS CATALYST 有权
标题翻译：饱和的N-杂环碳酸根配体金属络合物衍生物及其制备方法，以及使用其作为催化剂的硅氢化合物的制备方法
公开(公告)号：US20110160454A1
公开(公告)日：2011-06-30
申请号：US12846554
申请日：2010-07-29
申请人： Bok Ryul Yoo , Joon Soo Han , Jang Hyun Yoo
发明人： Bok Ryul Yoo , Joon Soo Han , Jang Hyun Yoo
IPC分类号： C07F15/00 , C07F7/14
CPC分类号： C07F15/00 , C07D233/02 , C07D239/04 , C07F7/14 , C07F15/0006 , C07F15/0086 , C07F15/04 , C08G77/08
摘要： Provided are a saturated N-heterocyclic carbene-ligand metal complex derivative, a method for preparing the same, and a method for preparing a silane compound by hydrosilylation using the same as a catalyst. To describe in more detail, the metal complex derivative has a saturated N-heterocyclic carbene derivative and an olefin ligand at the same time. A silane compound is prepared by hydrosilylation in the presence of the metal complex derivative as a catalyst. The provided metal complex derivative of the present invention has superior stability during hydrosilylation reaction and is capable of effectively performing the hydrosilylation reaction at low temperature even with small quantity. Further, a product with superior regioselectivity may be obtained. In addition, after the hydrosilylation reaction is completed, the metal complex derivative may be recovered and recycled.
摘要翻译：提供饱和的N-杂环卡宾 - 配体金属络合物衍生物，其制备方法，以及通过使用其作为催化剂的氢化硅烷化制备硅烷化合物的方法。为了更详细地描述，金属络合物衍生物同时具有饱和的N-杂环卡宾衍生物和烯烃配体。在金属络合物衍生物作为催化剂存在下，通过氢化硅烷化制备硅烷化合物。所提供的本发明的金属络合物衍生物在氢化硅烷化反应中具有优异的稳定性，并且即使在少量的情况下也能够在低温下有效地进行氢化硅烷化反应。此外，可以获得具有优异区域选择性的产品。此外，氢化硅烷化反应完成后，金属络合物衍生物可以回收再循环。

15. 发明授权

US06022987A Aryl substituted alkylsilanes and a preparation method thereof 失效
标题翻译：芳基取代烷基硅烷及其制备方法
公开(公告)号：US06022987A
公开(公告)日：2000-02-08
申请号：US997583
申请日：1997-12-23
申请人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Yeon Seok Cho
发明人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Yeon Seok Cho
IPC分类号： C07F7/12 , C07F7/08
CPC分类号： C07F7/12
摘要： Aryl substituted alkylsilanes represented by the formula I and a preparation method thereof by reacting substituted benzenes represented by the formula II with aryl substituted alkylsilanes represented by the formula III in the presence of Lewis acid catalysts such as aluminum chloride: ##STR1## wherein m, p, and q are 0 or 1, respectively; n and y are 0, 1, or 2, respectively; X.sup.1, X.sup.2, X.sup.3, X.sup.4, and X.sup.5 which are same or different represent hydrogen, fluoro, chloro; R represents C.sub.1 -C.sub.12 alkyl group; provided that if n is 0, m is 0 and if n is 1 or 2, at least two of X.sup.1, X.sup.2, X.sup.3, X.sup.4, and X.sup.5 represent chloro or fluoro group.
摘要翻译：由式I表示的芳基取代的烷基硅烷及其制备方法，其通过在路易斯酸催化剂如氯化铝存在下使由式II表示的取代的苯与式III表示的芳基取代的烷基硅烷反应：其中m，p和q 分别为0或1; n和y分别为0,1或2; 相同或不同的X 1，X 2，X 3，X 4和X 5表示氢，氟，氯; R代表C1-C12烷基; 条件是如果n是0，m是0，如果n是1或2，则X 1，X 2，X 3，X 4和X 5中的至少两个表示氯或氟基团。

16. 发明授权

US08278472B2 Method of preparing allylchlorosilane derivative 有权
标题翻译：烯丙基氯硅烷衍生物的制备方法
公开(公告)号：US08278472B2
公开(公告)日：2012-10-02
申请号：US12694723
申请日：2010-01-27
申请人： Bok Ryul Yoo , Joon Soo Han , Dong Won Lee
发明人： Bok Ryul Yoo , Joon Soo Han , Dong Won Lee
IPC分类号： C07F7/08
CPC分类号： C07F7/14
摘要： Provided is a method of preparing allylchlorosilane, and more particularly, a method of preparing allylchlorosilane with high yield by Si—C coupling reaction of an allyl chloride derivativce with a hydrosilane derivative under specific reaction conditions without using a catalyst.
摘要翻译：提供了制备烯丙基氯硅烷的方法，更具体地说，提供了一种通过烯丙基氯衍生物与氢硅烷衍生物在特定反应条件下的Si-C偶联反应而不使用催化剂以高产率制备烯丙基氯硅烷的方法。

17. 发明授权

US06251057B1 Dehydrohalogenative coupling reaction of organic halides with silanes 失效
标题翻译：有机卤化物与硅烷的脱卤化氢偶联反应
公开(公告)号：US06251057B1
公开(公告)日：2001-06-26
申请号：US09543546
申请日：2000-04-05
申请人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Seung-Hyun Kang , Yeon Seok Cho
发明人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Seung-Hyun Kang , Yeon Seok Cho
IPC分类号： C07F708
CPC分类号： C07F7/122
摘要： The present invention relates to methods for making the compounds of formula I which is a dehydrohalogenative coupling of hydrochlorosilanes of formula II with organic halides of formula III in the presence of a Lewis base catalyst. R3CH2SiR1Cl2 (I) HSiR1Cl2 (II) R2CH2X (III) In formulas I and II, R1 represents a hydrogen, chloro, or methyl; in formula III, X represents a chloro or bromo; in formula III, R2 can be selected from the group consisting of a C1-17 alkyl, a C1-10 fluorinated alkyl with partial or full fluorination, a C1-5 alkenyl groups, a silyl group containing alkyls, (CH2)nSiMe3-mClm wherein n is 0 to 2 and m is 0 to 3, aromatic groups, Ar(R′)1 wherein Ar is C6-14 aromatic hydrocarbon, R′ is a C1-4 alkyl, halogen, alkoxy, or vinyl, and q is 0 to 5, a haloalkyl group, (CH2)pX wherein p is 1 to 9 and X is a chloro or bromo; or an aromatic hydrocarbon, Ar CH2X wherein Ar is C6-14 aromatic hydrocarbon and X is a chloro or bromo. in formula I, R3 is the same as R2 in formula III and further, R3 can also be (CH2)pSiR1Cl2 or ArCH2SiR1Cl2 when R2 in formula III is (CH2)pX or ArCH2X, because of the coupling reaction of X with the compound of formula II.
摘要翻译：本发明涉及在路易斯碱催化剂存在下制备式I化合物的方法，其为式II的氢氯代硅烷与式III的有机卤化物的脱卤化氢偶联。在式I和II中，R 1表示氢，氯，或甲基; 在式III中，X表示氯或溴; 在式III中，R 2可以选自C1-17烷基，具有部分或全氟化的C1-10氟化烷基，C1-5链烯基，含甲硅烷基的烷基，（CH2）nSiMe3-mClm 其中n为0〜2，m为0〜3，芳基，Ar（R'）1其中Ar为C6-14芳族烃，R'为C1-4烷基，卤素，烷氧基或乙烯基，q为 0至5，卤代烷基，（CH 2）pX，其中p为1至9，X为氯或溴; 或芳族烃，Ar 2 OX，其中Ar为C 6-14芳族烃，X为氯或溴。在式I中，R 3与式III中的R 2相同，此外，R 3还可以是（CH 2）p SiRCl 2或ArCH 2 SiRCl 2，当式Ⅳ中的R 2为（CH 2）p X或ArCH 2 X时，由于X与公式二

18. 发明授权

US5847182A Fluorenyl substituted organosilanes and their preparation methods 失效
标题翻译：芴基取代的有机硅烷及其制备方法
公开(公告)号：US5847182A
公开(公告)日：1998-12-08
申请号：US44603
申请日：1998-03-19
申请人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Yeon Seok Cho
发明人： Il Nam Jung , Bok Ryul Yoo , Joon Soo Han , Yeon Seok Cho
IPC分类号： B01J27/125 , B01J21/02 , C07B61/00 , C07F7/12 , C07F7/08
CPC分类号： C07F7/12
摘要： The present invention relates to fluorenyl substituted organosilanes represented by the formula I and preparation methods thereof by reacting substituted biphenyls represented by the formul II with (dichloroalkyl)silanes represented by the formul III in the presence of Lewis acid catalysts such as aluminum chloride: ##STR1## (wherein m is 0 or 1 and n is 0, 1, or 2. y1 and y2 represent hydrogen, bromo, phenyl and they can be same or different. R represents hydrogen or methyl group. R.sub.j.sup.- can be dichloromethyl, 2,2-dichloroethyl, 3,3-dichloropropyl, 1,2-dichloroethyl, 2,3-dichloropropyl, 2,3-dichlorobutyl).
摘要翻译：本发明涉及由式I表示的芴基取代的有机硅烷及其制备方法，其通过在路易斯酸催化剂如氯化铝的存在下使由式II表示的取代的联苯与式III表示的（二氯烷基）硅烷反应：

19. 发明授权

US5760263A Alkylferrocenes containing chlorosilyl groups and their preparation methods 失效
标题翻译：含有氯代甲硅烷基的烷基二茂铁及其制备方法
公开(公告)号：US5760263A
公开(公告)日：1998-06-02
申请号：US880492
申请日：1997-06-23
申请人： Il Nam Jung , Sam Young Ahn , Bok Ryul Yoo , Joon Soo Han
发明人： Il Nam Jung , Sam Young Ahn , Bok Ryul Yoo , Joon Soo Han
IPC分类号： C07F17/02 , C07F15/02
CPC分类号： C07F17/02 , Y10S526/943
摘要： The present invention relates to ferrocenes containing silylalkyl groups, represented by formula(I) and their preparation methods by reacting ferrocene with allylchlorosilanes represented by formula(II) in the presence of Lewis acid catalysts such as aluminum chloride: ##STR1## wherein R.sup.1 represents hydrogen, C.sub.1 -C.sub.12 alkyl, or C.sub.1 -C.sub.12 alkyl containing phenyl group; R.sup.2 represents chloro, C.sub.1 -C.sub.12 alkyl, or C.sub.1 -C.sub.12 alkyl containing phenyl group; and n and m are 0, 1 or 2, respectively, and at least one of n and m is not zero.
摘要翻译：本发明涉及由式（I）表示的含有甲硅烷基烷基的二茂铁及其制备方法，该方法是在路易斯酸催化剂如氯化铝存在下，使二茂铁与由式（II）表示的烯丙基氯硅烷反应：式（I）式（II）其中R1表示氢，C1-C12烷基或含C1-C12烷基的苯基; R2表示氯，C1-C12烷基或含C1-C12烷基的苯基; n和m分别为0,1或2，并且n和m中的至少一个不为零。

20. 发明授权

US5726336A Polyalkylated benzenes containing chlorosilyl groups and their preparation methods 失效
标题翻译：含有氯代甲硅烷基的多烷基化苯及其制备方法
公开(公告)号：US5726336A
公开(公告)日：1998-03-10
申请号：US753749
申请日：1996-11-29
申请人： Il Nam Jung , Joon Soo Han , Eun Jeong Cho , Bok Ryul Yoo
发明人： Il Nam Jung , Joon Soo Han , Eun Jeong Cho , Bok Ryul Yoo
IPC分类号： C07F7/08 , C07F7/12
CPC分类号： C07F7/127 , C07F7/12
摘要： Polyalkylated benzenes containing chlorosilyl groups represented by formula III ##STR1## wherein R.sub.1 represents hydrogen or alkyl; R.sub.2 represents hydrogen or alkyl; R' represents methyl or chloro; and n=3-6.
摘要翻译：含有式III表示的氯代甲硅烷基的聚烷基化苯，其中R 1表示氢或烷基; R2代表氢或烷基; R'表示甲基或氯; 并且n = 3-6。

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