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11. 发明申请

US20090131693A1 Process for Selective Oxidation of Olefins to Epoxides 有权
标题翻译：烯烃选择性氧化成环氧化物的方法
公开(公告)号：US20090131693A1
公开(公告)日：2009-05-21
申请号：US12206335
申请日：2008-09-08
申请人： Daryle H. Busch , Bala Subramaniam , Hyun-Jin Lee , Tie-Pan Shi
发明人： Daryle H. Busch , Bala Subramaniam , Hyun-Jin Lee , Tie-Pan Shi
IPC分类号： C07D301/03 , C07D301/12 , C09K3/00
CPC分类号： C07D301/12 , Y02P20/582
摘要： A process for the selective oxidation of olefins to epoxides comprising the step of contacting the olefin (propylene or ethylene) with an oxidant (hydrogen peroxide) in the presence of a Lewis acid oxidation catalyst (MTO), organic base (pyridine or its N-oxide), in a solvent system comprising an organic water-miscible solvent (methanol). The system is pressurized using either the olefin itself or by adding an inert pressurizing gas (nitrogen) to increase the pressure between 230 and 700 psi at a temperature between 0.7 and 1.3 times the critical temperature of the olefin. The resulting increased solubility of the olefin in the organic solvent system increases the selectivity and yield of the desired epoxide (propylene oxide or ethylene oxide).
摘要翻译：一种将烯烃选择性氧化成环氧化物的方法，包括在路易斯酸氧化催化剂（MTO），有机碱（吡啶或其N-氧化物）存在下使烯烃（丙烯或乙烯）与氧化剂（过氧化氢）接触的步骤，氧化物），在包含有机水混溶性溶剂（甲醇）的溶剂体系中。使用烯烃本身或通过加入惰性加压气体（氮气）来加压系统，以在烯烃的临界温度的0.7至1.3倍之间的温度下增加230至700psi之间的压力。所产生的烯烃在有机溶剂体系中的溶解度增加了所需环氧化物（环氧丙烷或环氧乙烷）的选择性和产率。

12. 发明授权

US06448454B1 Catalytic oxidation of organic substrates by transition metal complexes in organic solvent media expanded by supercritical or subcritical carbon dioxide 有权
标题翻译：通过过渡金属配合物在有机溶剂介质中通过超临界或亚临界二氧化碳膨胀来催化氧化有机底物
公开(公告)号：US06448454B1
公开(公告)日：2002-09-10
申请号：US09545214
申请日：2000-04-07
申请人： Bala Subramaniam , Daryle H. Busch , Ghezai T. Musie , Ming Wei
发明人： Bala Subramaniam , Daryle H. Busch , Ghezai T. Musie , Ming Wei
IPC分类号： C07C3700
CPC分类号： C07D303/04 , C07B41/00 , C07C27/12 , C07C29/50 , C07C45/34 , C07C46/08 , C07C2601/14 , C07C2601/16 , C07D301/06 , Y02P20/544 , C07C49/713 , C07C49/603 , C07C35/14 , C07C35/18
摘要： Improved oxidation methods are provided wherein a reaction mixture comprising a substrate to be oxidized (e.g., phenols, alkenes) and an oxidation catalyst (typically dispersed in an organic solvent system) is supplemented with a compressed gas which expands the reaction mixture, thus accelerating the oxidation reaction. In preferred practice pressurized subcritical or supercritical carbon dioxide is used as the expanding gas, which is introduced into the reaction mixture together with an oxidizing agent. The inventive methods improve the substrate conversion and product selectivity by increasing the solubility of the oxidizing agent in the reaction mixture.
摘要翻译：提供了改进的氧化方法，其中包含待氧化的基质（例如酚，烯烃）和氧化催化剂（通常分散在有机溶剂体系中）的反应混合物补充有膨胀反应混合物的压缩气体，从而加速氧化反应。在优选的实践中，使用加压亚临界或超临界二氧化碳作为膨胀气体，其与氧化剂一起引入反应混合物中。本发明的方法通过增加氧化剂在反应混合物中的溶解度来改善底物转化率和产物选择性。

13. 发明授权

US5250171A Sensor for carbon monoxide 失效
标题翻译：一氧化碳传感器
公开(公告)号：US5250171A
公开(公告)日：1993-10-05
申请号：US698169
申请日：1991-05-10
申请人： Piers R. G. Warburton , Daryle H. Busch
发明人： Piers R. G. Warburton , Daryle H. Busch
IPC分类号： G01N27/416 , G01N33/00 , G01N27/26
CPC分类号： G01N33/004 , G01N27/4045
摘要： An electrochemical carbon monoxide detecting method and apparatus (10, 46) is disclosed which can detect carbon monoxide levels as low as about 500 ppm and which has excellent selectivity and a linear response over a broad range of carbon monoxide concentrations. The apparatus (10, 46) employs an electrical cell assembly (12, 54) having an electrolyte (20, 60) containing hydrated Cu(II) ions therein; upon creation of a constant magnitude potential difference between the cell electrodes (22, 24) ranging from about +0.03-+0.15 V, the Cu(II) ions are reduced to Cu(I) ions, and the latter react with carbon monoxide to form Cu(I)-carbonyl complexes. Detection of an electrical parameter indicative of the Cu(II)-Cu(I) reduction permits quantitative carbon monoxide determinations. Preferably, the detecting apparatus (14) is amperometric, employing a potentiostat (28) and output device (38). Alternately, detection can be accomplished potentiometrically.
摘要翻译：公开了一种电化学一氧化碳检测方法和装置（10,46），其可以检测一氧化碳水平低至约500ppm，并且在一氧化碳浓度范围内具有优异的选择性和线性响应。装置（10,46）使用具有在其中含有水合的Cu（II）离子的电解质（20,60）的电池组件（12,54）在约+ 0.03- + 0.15V范围内的电池电极（22,24）之间产生恒定电位差时，Cu（II）离子被还原成Cu（I）离子，后者与一氧化碳反应形成Cu（I） - 羰基复合物。检测指示Cu（II）-Cu（I）还原的电参数允许定量一氧化碳测定。优选地，检测装置（14）是电流计，采用恒电位仪（28）和输出装置（38）。或者，可以通过电位法实现检测。

14. 发明授权

US5124308A Monosubstituted dithiooxamide compounds and their use 失效
标题翻译：单独使用的硫氧化物化合物及其用途
公开(公告)号：US5124308A
公开(公告)日：1992-06-23
申请号：US438776
申请日：1989-11-17
申请人： Loren D. Albin , David R. Boston , Derek R. Callaby , Jacqueline M. Furlong , Robert J. Lokken , Roger A. Mader , David B. Olson , Wayne O. Otteson , Norman P. Sweeny , Daryle H. Busch , Nusrallah Jubran
发明人： Loren D. Albin , David R. Boston , Derek R. Callaby , Jacqueline M. Furlong , Robert J. Lokken , Roger A. Mader , David B. Olson , Wayne O. Otteson , Norman P. Sweeny , Daryle H. Busch , Nusrallah Jubran
IPC分类号： C09K9/02 , B41M5/132 , C07C327/38 , C07C327/42 , C07F1/08 , C07F3/06 , C07F3/08 , C07F3/10 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C08G79/00 , C09D185/00
CPC分类号： B41M5/132 , C07C327/42
摘要： This invention concerns monosubstituted dithiooxamides, and a preferred class comprises those wherein the substituent is such that the resulting dithiooxamide derivative is substantially nonvolatile at about room temperature. Preferred materials are those for which when the monosubstituent dithiooxamide is complexed with a transition metal cation, the resulting polymer is substantially a dark, i.e., preferably blue or blue-black color. Carbonless paper constructions involving use of N-(monosubstituted)dithiooxamides to advantage are described.

15. 发明授权

US4888032A Salts of cationic-metal dry cave complexes 失效
标题翻译：阳离子金属干穴复合盐
公开(公告)号：US4888032A
公开(公告)日：1989-12-19
申请号：US571812
申请日：1984-01-18
申请人： Daryle H. Busch
发明人： Daryle H. Busch
IPC分类号： C01B13/02 , C07F1/00 , C07F13/00 , C07F15/02 , C07F15/06
CPC分类号： C01B13/0244 , C01B13/0285 , C07F1/005 , C07F13/005 , C07F15/025 , C07F15/065 , C01B2210/0046
摘要： Salts containing cations of the formula: ##STR1## (in which M is Co, Fe, Cr or Mn, X, Y, R.sub.1,The Government has rights in this invention pursuant to Contract Number CHE-75-14837 awarded by the National Science Foundation.
摘要翻译：含有下式阳离子的盐：其中M为Co，Fe，Cr或Mn，X，Y，R 1，R 2和R 4为氢，烷基或取代基，且两个R 3基团和/或两个 R6基团形成有机桥连基团），并且这些化合物的衍生物具有与金属原子连接的各种轴向配体，可逆地复合氧，因此可用于氧气清除和从空气中分离氧气。具有相似桥连基团的其它类型的化合物也可用于相同的目的。

16. 发明授权

US4735634A Pillared cobalt complexes for oxygen separation 失效
标题翻译：用于氧分离的柱状钴络合物
公开(公告)号：US4735634A
公开(公告)日：1988-04-05
申请号：US901481
申请日：1986-08-28
申请人： John A. T. Norman , Dorai Ramprasad , Daryle H. Busch
发明人： John A. T. Norman , Dorai Ramprasad , Daryle H. Busch
IPC分类号： B01D61/38 , C01B13/02 , C07F15/06 , H01M4/90 , H01M12/06 , B01D53/22 , B01D53/14
CPC分类号： C01B13/0262 , B01D61/38 , C01B13/0255 , C07F15/065 , H01M12/06 , H01M4/9008 , C01B2210/0046
摘要： The present invention is a cobalt complex having the structural formula: ##STR1## wherein each R.sub.1 is independently, a phenyl or a C.sub.1 -C.sub.6 alkyl group; each R.sub.2 is independently hydrogen, a phenyl, or a C.sub.1 -C.sub.6 alkyl group; R.sub.3 is either N-succinimido substituted with a C.sub.3 or greater hydrocarbon functionality at the carbon atoms .alpha. to the imido carbonyl carbons, or a carbonyl functionality having a C.sub.1 greater hydrocarbon substituent with the proviso that if said substituent is methyl, R.sub.2 cannot be hydrogen; and Y is o-phenylene, --CH.sub.2 --.sub.a, wherein "a" is 2 or 3, --CH.sub.2 --.sub.b NR.sub.4 --CH.sub.2 --.sub.c, wherein "b" and "c" are independently 2 or 3 and R.sub.4 is hydrogen or a C.sub.1 -C.sub.12 alkyl group.These complexes have the ability to selectively and reversibly bind oxygen, thus making them useful components of oxygen separation membranes and absorbents.
摘要翻译：本发明是具有以下结构式的钴络合物：其中每个R 1独立地为苯基或C 1 -C 6烷基; 每个R 2独立地是氢，苯基或C 1 -C 6烷基; R3是在亚氨基羰基碳的α原子上被C3或更高级烃官能团取代的N-琥珀酰亚胺基，或具有C1大烃取代基的羰基官能团，条件是如果所述取代基是甲基，则R 2不能是氢; Y是邻亚苯基，-CH 2-a，其中“a”是2或3，-CH 2-b NR 4 -CH 2 -C，其中“b”和“c”独立地是2或3，R4是氢或 C1-C12烷基。这些配合物具有选择性和可逆地结合氧的能力，从而使它们成为氧分离膜和吸收剂的有用组分。

17. 发明授权

US4680037A Lacunar cobalt complexes for oxygen separation 失效
标题翻译：柠檬酸钴络合物用于氧分离
公开(公告)号：US4680037A
公开(公告)日：1987-07-14
申请号：US900935
申请日：1986-08-28
申请人： Dorai Ramprasad , Daryle H. Busch
发明人： Dorai Ramprasad , Daryle H. Busch
IPC分类号： B01D53/14 , B01D61/38 , C01B13/02 , C07F1/00 , C07F15/04 , C07F15/06 , H01M4/90 , B01D53/22
CPC分类号： C07F15/065 , B01D53/1493 , B01D61/38 , C01B13/0255 , C01B13/0262 , C07F1/005 , C07F15/045 , H01M4/9008 , C01B2210/0046 , C01B2210/0082
摘要： The present invention is a cobalt complex having the structural formula: ##STR1## wherein each R.sub.1 is independently hydrogen, a phenyl or a C.sub.1 -C.sub.6 alkyl group; each R.sub.2 is independently hydrogen or a C.sub.1 -C.sub.6 alkyl group; R.sub.3 is a C.sub.4 -C.sub.30 hydrocarbyl radical connecting the two carbonyl carbons; and Y is o-phenylene, --CH.sub.2).sub.a wherein "a" is 2 or 3, --CH.sub.2).sub.b NR.sub.4 --CH.sub.2).sub.c, wherein "b" and "c" are independently 2 or 3 and R.sub.4 is hydrogen or a C.sub.1 -C.sub.12 alkyl group.These complexes have the ability to selectively and reversibly bind oxygen, thus making them useful components of oxygen separation membranes and absorbents.
摘要翻译：本发明是具有以下结构式的钴络合物：其中每个R 1独立地是氢，苯基或C 1 -C 6烷基; 每个R 2独立地是氢或C 1 -C 6烷基; R3是连接两个羰基碳的C4-C30烃基; 且Y为邻亚苯基，-CH2）a其中“a”为2或3，-CH2）bNR4-CH2）c，其中“b”和“c”独立为2或3，R4为氢或C1- C12烷基。这些配合物具有选择性和可逆地结合氧的能力，从而使它们成为氧分离膜和吸收剂的有用组分。

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