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11. 发明申请

US20050049313A1 Electron mediator, electron mediator immobilized electrode, and biofuel cell using the electrode 有权
标题翻译：电子介体，电子介体固定电极和使用电极的生物燃料电池
公开(公告)号：US20050049313A1
公开(公告)日：2005-03-03
申请号：US10807489
申请日：2004-03-23
申请人： Matsuhiko Nishizawa , Tomokazu Matsue , Jun-ichi Kosuge , Noboru Fukasaku
发明人： Matsuhiko Nishizawa , Tomokazu Matsue , Jun-ichi Kosuge , Noboru Fukasaku
IPC分类号： C12M1/34 , C07C66/02 , C07C235/78 , H01M8/16 , A61K31/12
CPC分类号： C07C66/02 , C07C235/78 , H01M8/16 , Y02E60/527 , Y10S435/817
摘要： An object of the present invention is to provide a highly functional mediator capable of smoothly proceeding electron transfer between an electrode and a biocatalyst based on the premise that the mediator excels in safety and cost and to provide an electrode and a cell with sufficient amount of such a mediator molecule immobilized efficiently and strongly. The present invention provides a mediator mediating electron transfer between an enzyme and an electrode and containing a quinone molecule derivative, in particular, a mediator containing a VK3 derivative. In addition, the present invention provides an electrode and a biofuel cell to which those mediators are applied.
摘要翻译：本发明的目的是提供一种能够平稳地进行电极和生物催化剂之间的电子转移的高功能介体，其基于这样的前提，即介质优良的安全性和成本，并且提供具有足够量的这样的电极和电池一种有效强固地固定的介体分子。本发明提供介导酶和电极之间的电子转移并含有醌分子衍生物，特别是含有VK3衍生物的介体的介体。此外，本发明提供一种电极和生物燃料电池，其中应用这些介体。

12. 发明授权

US5866321A Analytical method and device for precise analysis with a simple sensor 失效
标题翻译：用简单传感器精确分析的分析方法和装置
公开(公告)号：US5866321A
公开(公告)日：1999-02-02
申请号：US738114
申请日：1996-10-25
申请人： Tomokazu Matsue , Hitoshi Shiku , Isamu Uchida
发明人： Tomokazu Matsue , Hitoshi Shiku , Isamu Uchida
IPC分类号： C12Q1/00 , G01N27/00 , G01N27/30 , G01N27/327 , G01N27/416 , G01N33/543 , G01N37/00 , G01Q30/02 , G01Q30/10 , G01Q60/60 , G01Q80/00 , G01Q90/00 , C12Q1/70 , C12Q1/68 , G01N33/53 , G01N33/554
CPC分类号： C12Q1/001 , C12Q1/004 , G01N33/54373 , G01N33/5438
摘要： An analyte and a reactant 3 that reacts with the analyte either directly or indirectly are allowed to react with each other on the analytical areas A of a substrate 1 and signals originating from the reaction are detected. In at least a signal detection step, either a signal generation-related portion 4x or a detector is provided in a portion that is opposed to the substrate 1 and high and low areas are formed in either the substrate 1 or the opposed portion or both in such a manner that the distance from each analytical area A of the substrate to the opposed portion is shorter than the distance from each of the non-analytical areas B of the substrate to the opposed portion, whereby signals originating from the reaction in the analytical areas A will be detected at higher intensities than signals originating from the reaction in the non-analytical areas B. The analyte can be quantitatively or qualitatively analyzed on the analytical areas of the substrate in high precision with reduced effects from the non-analytical areas of the substrate. Simultaneous analysis of multiple samples or simultaneous analysis for multiple items can also be accomplished with a simple sensor configuration.
摘要翻译：可以直接或间接地与分析物反应的分析物和反应物3在基板1的分析区域A上彼此反应，并且检测来自反应的信号。在至少信号检测步骤中，在与基板1相对的部分中设置信号生成相关部分4x或检测器，并且在基板1或相对部分中形成高低区域，从衬底的每个分析区域A到相对部分的距离比从衬底的非分析区域B到相对部分的距离短的方式，由此源于分析区域中的反应的信号将在比非分析区域B中的反应信号更高的强度下检测到A。可以在基板的分析区域上以高精度定量或定性地分析分析物，并且从非分析区域的非分析区域基质。同时分析多个样本或同时分析多个项目也可以通过简单的传感器配置来实现。

13. 发明授权

US4269674A Method of preparing para-chlorotoluene 失效
标题翻译：对氯甲苯的制备方法
公开(公告)号：US4269674A
公开(公告)日：1981-05-26
申请号：US101917
申请日：1979-12-10
申请人： Tetsuo Osa , Masamichi Fujihira , Tomokazu Matsue , Takashi Yamauchi
发明人： Tetsuo Osa , Masamichi Fujihira , Tomokazu Matsue , Takashi Yamauchi
IPC分类号： C07C17/00 , C07C17/12 , C07C25/02 , C07C67/00 , C25B3/06
CPC分类号： C25B3/06
摘要： A method of preparing para-chlorotoluene by the electrolytic chlorination of toluene in an aqueous solution of hydrogen chloride or a metal halide as an electrolyte by passing an electric current from a cathode to an anode, both of which are immersed in the electrolyte, in order to form an active chlorine species which then reacts with toluene to produce the desired para-toluene. The anode is made of a carbonaceous material having cyclodextrin or a derivative thereof bonded onto its surface. The toluene that is introduced into the aqueous solution of electrolyte is included as a clathrate compound within the cyclodextrin.
摘要翻译：通过使电流从阴极到阳极的电流通过将电流浸入电解液中的方式依次将氯化氢或金属卤化物的水溶液中的甲苯电解氯化成电解液，从而顺序地制备对氯甲苯的方法以形成活性氯物质，然后与甲苯反应产生所需的对甲苯。阳极由结合到其表面上的环糊精或其衍生物的碳质材料制成。引入电解质水溶液的甲苯作为环糊精中的包合物包含。

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