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11. 发明授权

US09221969B2 Thermally hardenable epoxy resin composition having an improved impact resistance at low temperatures 有权
标题翻译：在低温下具有改善的耐冲击性的热固化性环氧树脂组合物
公开(公告)号：US09221969B2
公开(公告)日：2015-12-29
申请号：US10538877
申请日：2003-12-17
申请人： Andreas Kramer , Jurgen Finter
发明人： Andreas Kramer , Jurgen Finter
IPC分类号： C08L63/00 , C08G59/28 , C09J163/00
CPC分类号： C08L63/00 , C08G59/28 , C08L2666/22 , C09J163/00
摘要： The invention relates to compositions containing at least one epoxide adduct A that comprises an average of more than one epoxide group per molecule, at least one polymer B of formula (I), at least one thixotropic agent C based on a urea derivative in a non-diffusing carrier material, and at least one hardener D for epoxy resins, which is activated at an increased temperature. Said composition is used especially as an adhesive and is provided with an extraordinarily high impact peel working value, especially at low temperatures. The invention further relates to epoxide group-terminal impact strength modifiers of formula (I), which significantly increase the impact resistance in epoxy resin compositions, particularly two-component epoxy resin compositions.
摘要翻译：本发明涉及至少一种包含至少一种环氧化物加合物A的组合物，其每分子平均含有多于一个环氧基团，至少一种式（I）的聚合物B，至少一种基于非衍生物的脲衍生物的触变剂C，以及至少一种用于环氧树脂的硬化剂D，其在升高的温度下被活化。所述组合物特别用作粘合剂，并且具有特别高的冲击剥离工作值，特别是在低温下。本发明还涉及式（I）的环氧基团 - 末端冲击强度改性剂，其显着提高了环氧树脂组合物，特别是双组分环氧树脂组合物的耐冲击性。

12. 发明申请

US20100256322A1 METHOD FOR PRODUCING HYDROXY-FUNCTIONAL POLYMERS, THE ISOCYANATE-GROUP-TERMINATED POLYADDITION PRODUCTS WHICH CAN BE OBTAINED THEREFROM, AND THE USE THEREOF 审中-公开
标题翻译：生产羟基官能聚合物的方法，可以从其获得的异氰酸酯基封端的多异氰酸酯产物及其用途
公开(公告)号：US20100256322A1
公开(公告)日：2010-10-07
申请号：US12746082
申请日：2008-12-15
申请人： Andreas Kramer , Jurgen Finter
发明人： Andreas Kramer , Jurgen Finter
IPC分类号： C08G18/16 , C08G18/08
CPC分类号： C08G59/4253 , C08G18/10 , C08G18/581 , C09J175/04 , C08G18/58
摘要： The invention relates to a method for producing polyurethanes, based on the reaction of a polymer, which has hydroxyl groups, and a polyisocyanate. Furthermore, the present invention relates to an isocyanate-group-terminated polyaddition product produced according to this method, an adhesive which contains such an isocyanate-group-terminated polyaddition product, and the use of the polyaddition product as a curing component in adhesives. The polyurethanes according to the invention are obtained by reacting at least one polymer (A), which has at least two hydroxyl groups and which is obtained by the reaction of a polymer having at least two carboxyl and/or phenol groups of the formula (I) or (II) with a least one compound having at least one glycidyl group, with at least one polyisocyanate (B).
摘要翻译：本发明涉及基于具有羟基的聚合物和多异氰酸酯的反应制备聚氨酯的方法。此外，本发明涉及根据该方法制造的异氰酸酯基封端的加聚产物，含有这种异氰酸酯基封端的加聚产物的粘合剂，以及在粘合剂中使用加聚产物作为固化组分。根据本发明的聚氨酯通过使至少一种具有至少两个羟基的聚合物（A）反应获得，该聚合物（A）通过具有式（I）的至少两个羧基和/或苯酚基的聚合物的反应获得）或（II）与至少一种具有至少一个缩水甘油基的化合物与至少一种多异氰酸酯（B）反应。

13. 发明申请

US20110130479A1 ADHESION PROMOTER COMPOUNDS FOR OILED STEEL 审中-公开
标题翻译：用于钢铁的粘合促进剂化合物
公开(公告)号：US20110130479A1
公开(公告)日：2011-06-02
申请号：US13054327
申请日：2009-07-17
申请人： Andreas Kramer , Jurgen Finter
发明人： Andreas Kramer , Jurgen Finter
IPC分类号： C09J163/00 , C07D303/40 , C07D303/46 , C07D407/12 , C08J9/04
CPC分类号： C08G18/10 , C08G59/4007 , C09J163/00 , C08G18/3228 , C08G18/7664 , C08G18/2855
摘要： Compounds of formula (I) in the field of heat-curing and two-component epoxy resin compositions, which may be used as adhesion promoters or adhesion promoter ingredients and methods of producing such compounds. Such compounds may be prepared as liquids. A heat-curing epoxy resin composition including at least one epoxy resin with more than one epoxy group per molecule on the average; at least one curing agent for epoxy resins, which is activated by elevated temperature; and at least one compound of formula (I).
摘要翻译：可用作粘合促进剂或粘合促进剂成分的热固化领域中的式（I）化合物和双组分环氧树脂组合物的化合物及其制备方法。这样的化合物可以制备成液体。一种热分解环氧树脂组合物，其平均每分子包含至少一种具有多于一个环氧基的环氧树脂; 至少一种用于环氧树脂的固化剂，其被升高的温度活化; 和至少一种式（I）的化合物。

14. 发明申请

US20110114257A1 REACTION PRODUCTS BASED ON AMPHIPHILIC BLOCK COPOLYMERS AND THEIR USE AS IMPACT MODIFIER 审中-公开
标题翻译：基于嵌段共聚物的反应产物及其作为冲击改性剂的应用
公开(公告)号：US20110114257A1
公开(公告)日：2011-05-19
申请号：US13054248
申请日：2009-07-17
申请人： Andreas Kramer , Jurgen Finter
发明人： Andreas Kramer , Jurgen Finter
IPC分类号： B32B38/16 , C08G63/91 , C08G81/00
CPC分类号： C08L71/02 , C08G2650/50 , C08G2650/58 , C08L63/00 , C08L2666/14 , C09J163/00 , C08L2666/22
摘要： Novel impact modifiers obtained by the reaction of amphiphilic block copolymers. These impact modifiers are suitable for use in thermosetting epoxy resin adhesives. The impact modifiers include a carboxylic acid group prepared from the reaction of an intramolecular anhydride of a di- or tricarboxylic acid with at least one amphiphilic block copolymer including at least one hydroxyl group. A method for adhesively binding heat-stable substrates includes applying a single-component thermosetting epoxy resin composition to the surface of a first heat-stable substrate; contacting the epoxy resin composition with the surface of second heat-stable substrate; heating the epoxy resin composition to 20-100° C.; bringing the two substrates and the epoxy resin composition into contact with a wash liquid; and heating the epoxy resin composition to 140-220° C.
摘要翻译：通过两亲嵌段共聚物的反应获得的新型冲击改性剂。这些抗冲改性剂适用于热固性环氧树脂粘合剂。抗冲改性剂包括由二羧酸或三羧酸的分子内酸酐与至少一种包含至少一个羟基的两亲嵌段共聚物的反应制备的羧酸基团。用于粘合结合热稳定基板的方法包括将单组分热固性环氧树脂组合物施加到第一热稳定基材的表面; 使环氧树脂组合物与第二热稳定基材的表面接触; 将环氧树脂组合物加热至20-100℃。使两个基板和环氧树脂组合物与洗涤液接触; 并将环氧树脂组合物加热至140-220℃

15. 发明申请

US20070105983A1 Thermally hardenable epoxy resin composition having an improved impact resistance at low temperatures 有权
标题翻译：在低温下具有改善的耐冲击性的热固化性环氧树脂组合物
公开(公告)号：US20070105983A1
公开(公告)日：2007-05-10
申请号：US10538877
申请日：2003-12-17
申请人： Andreas Kramer , Jurgen Finter
发明人： Andreas Kramer , Jurgen Finter
IPC分类号： C08K5/09
CPC分类号： C08L63/00 , C08G59/28 , C08L2666/22 , C09J163/00
摘要： The invention relates to compositions containing at least one epoxide adduct A that comprises an average of more than one epoxide group per molecule, at least one polymer B of formula (I), at least one thixotropic agent C based on a urea derivative in a non-diffusing carrier material, and at least one hardener D for epoxy resins, which is activated at an increased temperature. Said composition is used especially as an adhesive and is provided with an extraordinarily high impact peel working value, especially at low temperatures. The invention further relates to epoxide group-terminal impact strength modifiers of formula (I), which significantly increase the impact resistance in epoxy resin compositions, particularly two-component epoxy resin compositions.
摘要翻译：本发明涉及至少一种包含至少一种环氧化物加合物A的组合物，其每分子平均含有多于一个环氧基团，至少一种式（I）的聚合物B，至少一种基于非衍生物的脲衍生物的触变剂C，以及至少一种用于环氧树脂的硬化剂D，其在升高的温度下被活化。所述组合物特别用作粘合剂，并且具有特别高的冲击剥离工作值，特别是在低温下。本发明还涉及式（I）的环氧基团 - 末端冲击强度改性剂，其显着提高了环氧树脂组合物，特别是双组分环氧树脂组合物的耐冲击性。

16. 发明申请

US20070066721A1 Heat-curable compositions comprising low-temperature impact strength modifiers 有权
标题翻译：包含低温冲击强度改性剂的可热固化组合物
公开(公告)号：US20070066721A1
公开(公告)日：2007-03-22
申请号：US10564889
申请日：2004-07-16
申请人： Andreas Kramer , Jurgen Finter , Ulrich Gerber
发明人： Andreas Kramer , Jurgen Finter , Ulrich Gerber
IPC分类号： C08L63/00 , C08G18/06 , C08G59/00 , B32B27/38
CPC分类号： C09J175/04 , C07D303/24 , C08G18/10 , C08G18/4854 , C08G18/73 , C08G59/226 , C08G59/32 , C08G18/3215 , C08G18/2855 , C08G18/2845
摘要： The present invention relates to compositions which contain at least one epoxide adduct A having on average more than one epoxide group per molecule, at least one polymer B of the formula (I), at least one thixotropic agent C, based on a urea derivative in a nondiffusing carrier material, and at least one curing agent D for epoxy resins, which is activated by elevated temperature. This composition serves in particular as an adhesive and has an extremely high dynamic resistance to cleavage, in particular at low temperatures. The invention furthermore relates to impact strength modifiers terminated with epoxide groups and of the formula (I). It has been found that these novel impact strength modifiers result in a significant increase in impact strength in epoxy resin compositions, in particular in two-component epoxy resin compositions.
摘要翻译：本发明涉及含有至少一种每分子平均具有多于一个环氧基团的环氧化物加合物A的组合物，至少一种式（I）的聚合物B，至少一种触变剂C，基于脲衍生物非扩散载体材料和至少一种用于环氧树脂的固化剂D，其由升高的温度活化。该组合物特别用作粘合剂，并且具有极高的动态抗切割性，特别是在低温下。本发明还涉及用环氧基团和式（I）封端的冲击强度改性剂。已经发现，这些新的冲击强度改性剂导致环氧树脂组合物，特别是双组分环氧树脂组合物中冲击强度的显着增加。

17. 发明授权

US5482655A Electrically conductive thermoplastic polymer formulations and the use thereof 失效
标题翻译：导电热塑性聚合物配方及其用途
公开(公告)号：US5482655A
公开(公告)日：1996-01-09
申请号：US075658
申请日：1993-06-11
申请人： Thomas Vogel , Jurgen Finter , Hartmut Bleier , Patrice Bujard
发明人： Thomas Vogel , Jurgen Finter , Hartmut Bleier , Patrice Bujard
IPC分类号： C08G61/10 , C08G61/12 , C08L41/00 , C08L65/00 , H01B1/12 , H01B1/00 , H01B1/06
CPC分类号： C08G61/126 , C08L65/00 , H01B1/127 , H01G11/48 , H01G11/56 , C08G2261/1424 , C08G2261/3223 , Y02E60/13
摘要： A formulation comprisinga) at least one polythiophene in oxidised polycationic form and containing structural repeating units of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other linear or branched C.sub.1 -C.sub.18 alkyl or C.sub.2 -C.sub.18 alkoxyalkyl; or are C.sub.3 -C.sub.8 cycloalkyl, phenyl or benzyl which are unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy or halogen; or R.sub.1 and R.sub.2, taken together, are linear C.sub.1 -C.sub.8 alkylene which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, halogen, C.sub.3 -C.sub.8 cycloalkyl, phenyl, benzyl, C.sub.1 -C.sub.4 alkylphenyl, C.sub.1 -C.sub.4 alkoxyphenyl, halophenyl, C.sub.1 -C.sub.4 alkylbenzyl, C.sub.1 -C.sub.4 alkoxybenzyl or halobenzyl; andb) at least one polyanion of a film-forming thermoplastic polymer containing sulfated alcohol groups ##STR2## and/or sulfonatoalkylated alcohol groups ##STR3## in structural repeating units, wherein the group --(C.sub.n H.sub.2n)-- is linear or branched C.sub.2 -C.sub.12 alkylene which contains 2 to 5 carbon atoms in the carbon chain and is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy. The formulation is an intrinsically electrically conductive themoformable material.
摘要翻译：一种制剂，其包含a）至少一种氧化聚阳离子形式的聚噻吩，并含有另一个直链或支链C 1 -C 18烷基或C 2 -C 18烷氧基烷基的结构式I重复单元; 或未取代或被C 1 -C 6烷基，C 1 -C 6烷氧基或卤素取代的C 3 -C 8环烷基，苯基或苄基; 或者R 1和R 2一起是未被取代或被C 1 -C 6烷基，C 1 -C 6烷氧基，卤素，C 3 -C 8环烷基，苯基，苄基，C 1 -C 4烷基苯基，C 1 -C 4烷氧基苯基，卤代苯基，C 1 -C 4烷基苄基，C 1 -C 4烷氧基苄基或卤代苄基; 和b）在结构重复单元中含有硫酸化醇基团和/或磺化烷基化醇基团的成膜热塑性聚合物的至少一种聚阴离子，其中 - （C n H 2n） - 为直链或支链C 2 -C 12亚烷基其在碳链中含有2至5个碳原子且未被取代或被C 1 -C 4烷氧基取代。制剂是本征导电的可变形材料。

18. 发明授权

US5432049A Photochromic composition 失效
标题翻译：光致变色组合物
公开(公告)号：US5432049A
公开(公告)日：1995-07-11
申请号：US189822
申请日：1994-02-01
申请人： Evelyn Fischer , Walter Fischer , Jurgen Finter , Kurt Meier , Martin Roth
发明人： Evelyn Fischer , Walter Fischer , Jurgen Finter , Kurt Meier , Martin Roth
IPC分类号： G03F7/028 , C07D219/06 , C07D311/86 , C07D335/16 , C07D401/12 , C07D407/12 , C07D409/12 , C08F2/50 , C09K3/00 , C09K9/02 , G03F7/031 , G03F7/038 , H01R13/52 , G03C1/73 , G03F7/004
CPC分类号： C07D401/12 , C07D219/06 , C07D311/86 , C07D335/16 , C09K9/02 , G03F7/031 , G03F7/0388 , Y10S430/163
摘要： Compounds of the formula I ##STR1## in which X is O, S, SO, SO.sub.2 or NR.sub.13, R.sub.13 is, for example, methyl, and R.sub.1 to R.sub.12, independently of one another, are, for example, H, C.sub.1 -C.sub.12 alkyl, C.sub.1 14 C.sub.12 alkoxy, halogen or --CN. The compounds are photosensitive and photochromic and as suitable are photosensitizers and simultaneously as colour indicators, and as photoswitchable colour filters.
摘要翻译：其中X为O，S，SO，SO 2或NR 13的式I（I）化合物，R 13为例如甲基，R 1至R 12彼此独立地为H， C1-C12烷基，C114 C12烷氧基，卤素或-CN。这些化合物是光敏的和光致变色的，并且适合的是光敏剂，同时作为颜色指示剂，以及作为照片开关的滤色器。

19. 发明授权

US5177218A Photochromic benzothioxanthone oxides, process for their preparation and the use thereof 失效
标题翻译：光致变色二氧化硅氧化物，其制备方法及其用途
公开(公告)号：US5177218A
公开(公告)日：1993-01-05
申请号：US814945
申请日：1991-12-30
申请人： Walter Fischer , Jurgen Finter , Heinz Spahni
发明人： Walter Fischer , Jurgen Finter , Heinz Spahni
IPC分类号： C07D335/16 , C07D335/04 , C09B57/14 , C09K9/00 , C09K9/02 , G03C1/73 , G03F7/09 , G03F7/095 , G11B7/244
CPC分类号： G11B7/244 , C07D335/04 , C09B57/14 , G03C1/73 , G03F7/091 , G03F7/0952 , G11B7/2531 , G11B7/2533
摘要： Compounds of formula I or III or mixtures thereof ##STR1## wherein R is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.3, x is 1 or 2, and R.sub.1 is H, linear or branched C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or C.sub.2 -C.sub.12 alkynyl, C.sub.7 -C.sub.16 aralkyl, C.sub.8 -C.sub.16 alkaralkyl, --CH.sub.2 COOR.sub.3 or C.sub.1 -C.sub.12 acyl, wherein R.sub.3 is H, C.sub.1 -C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, are reversible photochromic systems which can be used for contrast formation, light absorption or for the reversible optical storage of information.
摘要翻译：式I或III的化合物或其混合物其中R是被C 1 -C 12烷基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，苯基，苄基，-CN - 取代的未取代的C 6 -C 14芳基或C 6 -C 14芳基， CF 3，卤素或-COOR 3，x是1或2，并且R 1是H，直链或支链C 1 -C 12烷基，C 2 -C 12烯基或C 2 -C 12炔基，C 7 -C 16芳烷基，C 8 -C 16烷基烷基，-CH 2 COOR 3或C 1 -C 12酰基，其中R 3 是H，C 1 -C 18烷基，环己基，环戊基，苯基，C 1 -C 12烷基苯基，苄基或C 1 -C 12烷基苄基，是可用于对比形成，光吸收或信息的可逆光学存储的可逆光致变色体系。

20. 发明授权

US5032488A Method of metalizing a surface using a mixture of olefin and dibenzalacetone palladium complex 失效
标题翻译：使用烯烃和二苯并丙酮钯络合物的混合物使表面金属化的方法
公开(公告)号：US5032488A
公开(公告)日：1991-07-16
申请号：US165448
申请日：1988-03-01
申请人： Jurgen Finter
发明人： Jurgen Finter
IPC分类号： C08K5/00 , C08F2/44 , C08F2/48 , C08K5/56 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L67/00 , C08L77/00 , C08L101/00 , C23C18/28 , C23C18/30
CPC分类号： C23C18/28 , C23C18/30
摘要： When irradiated, a mixture of (a) a non-volatile substance containing at least one olefinic double bond and (b) a dibenzalacetone palladium complex deposits zero-valent palladium. Electrically non-conductive carrier materials which have been coated with a layer of said mixture can, after irradiation, be metallized by metal deposition without current, with electrically conductive coatings or patterns being obtained.
摘要翻译：当照射时，（a）含有至少一个烯属双键的非挥发性物质和（b）二苄基丙酮钯络合物的混合物沉积零价钯。已经涂覆有所述混合物层的电非导电载体材料可以在照射之后通过没有电流的金属沉积进行金属化，获得导电涂层或图案。

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