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    • 14. 发明授权
    • Fuel electrode of solid oxide fuel cell and process for the production of the same
    • 固体氧化物燃料电池的燃料电极及其制造方法
    • US06790474B1
    • 2004-09-14
    • US09319688
    • 1999-06-09
    • Masakazu HishinumaYoshio Matsuzaki
    • Masakazu HishinumaYoshio Matsuzaki
    • B05D512
    • H01M4/9066H01M2008/1293H01M2300/0074
    • There is disclosed a fuel electrode of solid oxide fuel cells which is made of a cermet composed of yttria-stabilized zirconia containing a transition metal dissolved therein and nickel (Ni) or a cermet composed of yttria-stabilized zirconia containing a transition metal dissolved therein, nickel (Ni) and cerium oxide containing a divalent or trivalent metal dissolved therein, and which can be obtained by adding a solution of a metallo-organic compound of yttrium (Y) and a solution of a metallo-organic transition-metal compound to a solution of a metallo-organic compound of zirconium (Zr) to prepare a mixed solution of metallo-organic compounds of Zr—Y-transition metal; adding NiO powder or a powder mixture of NiO powder with cerium oxide powder containing a divalent or trivalent metal oxide dissolved therein to the mixed solution of the metallo-organic compounds to prepare a slurry; and subjecting the slurry to hydrolysis, polycondensation, pyrolysis, annealing and reduction successively. The fuel electrode is formed on a solid electrolyte layer by a screen printing process.
    • 公开了一种固体氧化物燃料电池的燃料电极,其由包含溶解有过渡金属的氧化钇稳定的氧化锆和由镍(Ni)构成的金属陶瓷或由其中溶解有过渡金属的氧化钇稳定的氧化锆组成的金属陶瓷制成, 可以通过将钇(Y)的金属有机化合物和金属有机过渡金属化合物的溶液加入到金属 - 有机过渡金属化合物的溶液中而获得的镍(Ni)和含有二价或三价金属的氧化铈 锆(Zr)的金属有机化合物溶液制备Zr-Y-过渡金属的金属有机化合物的混合溶液; 将NiO粉末或NiO粉末与其中溶解有二价或三价金属氧化物的氧化铈粉末的粉末混合物加入到金属有机化合物的混合溶液中以制备浆料; 并对浆料进行水解,缩聚,热解,退火和还原。 燃料电极通过丝网印刷工艺形成在固体电解质层上。
    • 17. 发明申请
    • SEGMENTED-IN-SERIES SOLID OXIDE FUEL CELL
    • SEGMENTED-IN-SERIES固体氧化物燃料电池
    • US20100285387A1
    • 2010-11-11
    • US12735270
    • 2008-12-24
    • Kenjiro FujitaKazuo NakamuraYoshio MatsuzakiMakoto Koi
    • Kenjiro FujitaKazuo NakamuraYoshio MatsuzakiMakoto Koi
    • H01M8/24
    • H01M8/1213H01M8/0204H01M8/1286H01M8/2425H01M8/2428
    • There is obtained a segmented-in-series solid oxide fuel cell provided with a current turnaround structure and containing a porous electrically insulating substrate having a fuel flow path extending from a fuel feed port to a fuel discharge port, provided therein, and a pair of the top and back surfaces, in parallel with the fuel flow path, together with a pair of side-faces of the porous electrically insulating substrate, in the transverse direction thereof, provided on the exterior thereof, wherein solid oxide fuel cells made up by sequentially stacking an interconnector adjacent to a fuel electrode layer, the fuel electrode layer, an electrolyte layer, and an air electrode layer, and an interconnector adjacent to the air electrode layer in that order so as to be in parallel with the fuel flow path are disposed at intervals on the pair of the top and back surfaces, respectively.
    • 获得具有电流翻转结构的分段式串联固体氧化物燃料电池,并且包含具有从设置在其中的燃料供给口延伸到燃料排出口的燃料流路的多孔电绝缘基板和一对 与燃料流动路径平行的顶表面和后表面与多孔电绝缘基板的横向方向上的一对侧面一起设置在其外部,其中固体氧化物燃料电池依次构成 布置与燃料电极层相邻的互连器,燃料电极层,电解质层和空气电极层以及与空气电极层相邻的与金属流路平行的顺序的互连器 分别在一对顶表面和后表面上的间隔。