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    • 15. 发明授权
    • Process for desulfurizing combustion exhaust gases
    • 燃烧废气脱硫工艺
    • US4328195A
    • 1982-05-04
    • US130388
    • 1980-03-14
    • Toshikatsu MoriTeruo KumagaiShinpei MatsudaTsukasa NishimuraYasuyuki Nishimura
    • Toshikatsu MoriTeruo KumagaiShinpei MatsudaTsukasa NishimuraYasuyuki Nishimura
    • B01D53/50B01D53/68B01D53/77C01F11/46C01B17/00
    • C01F11/464B01D53/501B01D53/68
    • An improved process for desulfurizing combustion exhaust gases of mainly coal containing sulfur oxides, HF and dust containing Al is provided, which process consists of four steps; a first step of contacting the gases with calcium carbonate or hydroxide in the form of slurry to convert the sulfur oxides into CaSO.sub.3 ; a second step of contacting O.sub.2 with the resulting slurry to convert CaSO.sub.3 into CaSO.sub.4 ; a third step of separating CaSO.sub.4 and mother liquor from the resulting slurry; and a fourth step of preparing a slurry of calcium carbonate or hydroxide to be employed in the first step, from the mother liquor, the pHs of the slurry and the mother liquor in the first and fourth steps being adjusted to 5 or higher by adding alkali such as sodium carbonate.According to the present process, it is possible to prevent hindrance of HF and Al contained in dust to the reaction of SO.sub.2 -absorbent (CaCO.sub.3 or Ca[OH].sub.2) with SO.sub.2 gas, and thereby improve percentage desulfurization and also obtain a high quality gypsum.
    • 提供了一种改进的主要含硫硫氧化物,HF和含有Al的粉尘的燃烧废气脱硫方法,该方法由四个步骤组成: 将气体与浆料形式的碳酸钙或氢氧化物接触以将硫氧化物转化为CaSO 3的第一步骤; 使O 2与所得浆料接触以将CaSO 3转化为CaSO 4的第二步骤; 从所得浆料中分离出CaSO 4和母液的第三步骤; 以及在母液中制备第一步中使用的碳酸钙或氢氧化物浆料的第四步骤,通过加入碱将第一步骤和第四步骤中的浆料和母液的pH调节至5以上 如碳酸钠。 根据本方法,可以防止SO 2吸收剂(CaCO 3或Ca [OH] 2)与SO 2气体反应中灰尘中含有的HF和Al的阻碍,从而提高脱硫率并获得高质量 石膏