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    • 15. 发明申请
    • Electrolyte membrane using polybenzoxazine based compound
    • 使用聚苯并恶嗪的化合物的电解质膜
    • US20110196051A1
    • 2011-08-11
    • US12929009
    • 2010-12-22
    • Myung-jin LEESeong-woo CHOIHee-young SUNWoo-sung JEON
    • Myung-jin LEESeong-woo CHOIHee-young SUNWoo-sung JEON
    • C08J5/22C08G73/06B29D7/01
    • C08J5/22C08J2379/06H01M4/921H01M8/1027H01M8/103H01M8/1032H01M8/1039H01M8/1072H01M2300/0082Y02P70/56
    • An electrolyte membrane includes a cross-linked reaction product of a benzoxazine monomer and a cross-linkable compound. The electrolyte membrane is impregnated with 300 to 600 parts by weight of phosphoric acid based on 100 parts by weight of the electrolyte membrane, and has a yield strain 0.5% or less, and a yield stress 0.3 Mpa or less. The cross-linked material has a strong acid trapping ability with respect to the benzoxazine compound and excellent mechanical properties due to a cross-linkage. Also, the solubility of the cross-linked material in polyphosphoric acid is low, thereby showing excellent chemical stability. Accordingly, when the cross-linked material is used, an electrolyte membrane having an excellent liquid supplementing ability and excellent mechanical and chemical stability at a high temperature can be obtained. The cross-linked material can be obtained by a simple polymerization process by combining a benzoxazine monomer and a crosslinkable compound and by using heat instead of using a polymerization initiator or a cross-linking agent.
    • 电解质膜包括苯并恶嗪单体和可交联化合物的交联反应产物。 基于100重量份的电解质膜,以300重量份的磷酸浸渍电解质膜,其屈服应变为0.5%以下,屈服应力为0.3Mpa以下。 交联材料相对于苯并恶嗪化合物具有强的酸捕获能力,并且由于交联而具有优异的机械性能。 此外,交联材料在多磷酸中的溶解度低,因此表现出优异的化学稳定性。 因此,当使用交联材料时,可以获得在高温下具有优异的液体补充能力和优异的机械和化学稳定性的电解质膜。 交联材料可以通过简单的聚合方法通过组合苯并恶嗪单体和可交联化合物,并且通过使用热代替聚合引发剂或交联剂来获得。