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    • 12. 发明申请
    • LIGHT EMITTING ELEMENT
    • 发光元件
    • US20130105787A1
    • 2013-05-02
    • US13809798
    • 2011-06-24
    • Daisaku TanakaShinichi MatsukiTsuyoshi Tominaga
    • Daisaku TanakaShinichi MatsukiTsuyoshi Tominaga
    • H01L51/00
    • H01L51/0072C07D209/86H01L51/5004H01L51/5056
    • Provided is an organic thin film light emitting element which has achieved all of improved luminous efficiency, improved driving voltage and improved durability life. Specifically provided is a light emitting element which comprises a hole transport layer and an electron transport layer between a positive electrode and a negative electrode and emits light by means of electrical energy. The light emitting element is characterized in that: the hole transport layer of the light emitting element contains a compound represented by general formula (1); the electron transport layer contains a donor compound; and the donor compound is an alkali metal, an inorganic salt containing an alkali metal, a complex of an alkali metal and an organic substance, an alkaline earth metal, an inorganic salt containing an alkaline earth metal, or a complex of an alkaline earth metal and an organic substance. (In the formula, R1-R20 each represents one group selected from the group consisting of hydrogen, deuterium, an alkyl group, a cycloalkyl group, an amino group, an aryl group, a heterocyclic group, a heteroaryl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, analkoxy group, an alkylthio group, an arylether group, an arylthioether group, a halogen, a cyano group, a —P(═O)R24R25 group and a silyl group; R24 and R25 each represents an aryl group or a heteroaryl group; and these substituents may be further substituted, or adjacent two substituents may combine together to form a ring. Meanwhile, R21-R23 may be the same or different and each represents one group selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a heteroaryl group; and these substituents maybe further substituted.)
    • 提供了一种有机薄膜发光元件,其实现了所有的改进的发光效率,改善的驱动电压和改善的耐久寿命。 具体地提供了一种发光元件,其包括在正极和负极之间的空穴传输层和电子传输层,并且通过电能发光。 发光元件的特征在于:发光元件的空穴传输层含有通式(1)表示的化合物。 电子传输层含有供体化合物; 供体化合物为碱金属,含有碱金属的无机盐,碱金属和有机物的配合物,碱土金属,含有碱土金属的无机盐或碱土金属的络合物 和有机物质。 (式中,R 1 -R 20各自表示选自氢,氘,烷基,环烷基,氨基,芳基,杂环基,杂芳基,烯基, 环烯基,炔基,苯氧基,烷硫基,芳基醚基,芳硫醚基,卤素,氰基,-P(= O)R24R25基和甲硅烷基; R24和R25各自表示 芳基或杂芳基;这些取代基可以进一步被取代,或者相邻的两个取代基可以组合在一起形成环,而R 21 -R 23可以相同或不同,各自表示选自 烷基,环烷基,芳基和杂芳基;这些取代基可以进一步被取代。)