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11. 发明授权

US4208190A Diesel fuels having anti-wear properties 失效
标题翻译：具有抗磨损性能的柴油燃料
公开(公告)号：US4208190A
公开(公告)日：1980-06-17
申请号：US10524
申请日：1979-02-09
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： C10L1/02 , C10L1/222 , F02B3/06 , C10L1/18 , C10L1/22
CPC分类号： C10L10/08 , C10L1/026 , C10L1/2222 , F02B3/06
摘要： An anti-wear compression ignition fuel for use in diesel engines comprising (1) a monohydroxy alkanol having from 1 to 5 carbon atoms, and (2) a wear inhibiting amount of a straight chain aliphatic primary amine, e.g. oleyl amine. Optionally, said fuel composition may also contain an ignition accelerator such as an organic nitrate.It has recently been disclosed in Brazilian Patent Application No. P17700392 that alcohols, such as methanol and ethanol, can be substituted for conventional petroleum derived diesel fuels for burning in diesel engines, when used in combination with an ignition accelerator, such as ethyl nitrate or nitrite. Reportedly, the addition of alkyl nitrate or nitrite accelerators to the alcohol achieves a level of auto-ignition sufficient to operate in diesel engines. Unfortunately, these fuel compositions, devoid of any petroleum derived products, are notably deficient in lubricity or lubricating properties with the result that engine wear from the use of these fuels in internal combustion reciprocating diesel engines is a serious problem. Of particular concern are wear problems associated with the fuel injector mechanisms used in such engines. Wear problems have also been encountered in diesel engines operating on light diesel fuel oils are disclosed in U.S. Pat. No. 4,002,437.
摘要翻译：一种用于柴油发动机的抗磨压缩点火燃料，包括（1）具有1至5个碳原子的单羟基链烷醇，和（2）耐磨损量的直链脂族伯胺，例如，油胺。任选地，所述燃料组合物还可以含有点火促进剂，例如有机硝酸盐。最近在巴西专利申请P17700392中公开了，当与点燃促进剂如硝酸乙酯或硝酸乙酯组合使用时，诸如甲醇和乙醇的醇可以代替常规的柴油发动机燃烧柴油，亚硝酸盐据报道，向醇中加入硝酸烷基酯或亚硝酸盐促进剂达到足以在柴油发动机中运行的自动点火水平。不幸的是，没有任何石油衍生产品的这些燃料组合物显着地缺乏润滑性或润滑性能，结果是在内燃往复式柴油发动机中使用这些燃料的发动机磨损是严重的问题。特别令人关注的是与这种发动机中使用的燃料喷射器机构有关的磨损问题。在美国专利No.4,697,697中公开了在轻柴油燃料油上运行的柴油发动机中也遇到了磨损问题。第4,002,437号。

12. 发明授权

US4201684A Lubricant composition of improved friction reducing properties 失效
标题翻译：润滑剂组合物具有改善的减摩性能
公开(公告)号：US4201684A
公开(公告)日：1980-05-06
申请号：US959934
申请日：1978-11-13
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： C10M135/26 , C10M135/02 , C10N30/00 , C10N30/06 , C10N40/25 , C10M1/38
CPC分类号： C10M135/02 , C10M2219/02 , C10M2219/024 , C10M2221/04 , C10M2223/045 , C10N2210/02 , C10N2270/02
摘要： Lubricating oil adapted for use as a crankcase lubricant in internal combustion engines containing a friction-reducing amount of a sulfurized fatty acid amide, ester or ester-amide of an oxyalkylated amine.
摘要翻译：适用于含有减少摩擦量的硫化脂肪酸酰胺，烷氧基化胺的酯或酯 - 酰胺的内燃机中的曲轴箱润滑剂的润滑油。

13. 发明授权

US4117011A Additives 失效
标题翻译：添加剂
公开(公告)号：US4117011A
公开(公告)日：1978-09-26
申请号：US467051
申请日：1974-05-06
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： B01F17/00 , C10L1/22 , C10L10/08 , C10M159/16 , C10N20/04 , C10N30/04 , C10N40/25 , C07C87/28
CPC分类号： C10M159/16 , B01F17/0042 , C10L1/221 , C10M2203/06 , C10M2205/00 , C10M2205/026 , C10M2205/028 , C10M2205/04 , C10M2207/024 , C10M2207/027 , C10M2207/282 , C10M2207/30 , C10M2207/302 , C10M2207/304 , C10M2207/34 , C10M2209/084 , C10M2209/11 , C10M2215/04 , C10M2215/062 , C10M2215/26 , C10M2217/042 , C10M2217/043 , C10M2217/046 , C10M2217/06 , C10M2219/044 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10M2225/041 , C10N2210/02 , C10N2270/02
摘要： The reaction product of (a) high molecular weight hydrocarbon-substituted phenols, (b) aldehydes, (c) ammonia or amines having a reactive hydrogen atom, and (d) alkylene oxides are effective dispersants for lubricating oil and impart detergent properties to liquid hydrocarbon fuels such as gasoline.

14. 发明授权

US4058468A Lubricant composition 失效
标题翻译：润滑油组成
公开(公告)号：US4058468A
公开(公告)日：1977-11-15
申请号：US693473
申请日：1976-06-07
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： C10M159/16 , C10M1/48
CPC分类号： C10M159/16 , C10M2203/06 , C10M2205/00 , C10M2205/026 , C10M2205/028 , C10M2205/04 , C10M2207/027 , C10M2207/282 , C10M2207/30 , C10M2207/34 , C10M2209/084 , C10M2215/062 , C10M2219/044 , C10M2219/046 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10N2210/02
摘要： A dispersant-antiwear lubricating oil additive is made by reacting a high molecular weight hydrocarbon-substituted phenol with aldehyde and ammonia or amines having a reactive hydrogen atom to form a Mannich condensation product which is reacted with an alkylene oxide and P.sub.2 S.sub.5 to form the additive.
摘要翻译：分散剂 - 抗磨润滑油添加剂通过使高分子量烃取代的苯酚与醛和氨或具有反应性氢原子的胺反应而形成曼尼希缩合产物，其与烯化氧和P2S5反应形成添加剂。

15. 发明授权

US3992308A Lubricating oil composition containing sulfurized reaction product of mixed tertiary alkyl phenols with formaldehyde 失效
标题翻译：含有混合叔烷基酚与甲醛的硫化反应产物的润滑油组合物
公开(公告)号：US3992308A
公开(公告)日：1976-11-16
申请号：US546767
申请日：1975-02-03
申请人： Robert E. Malec , Larry Plonsker
发明人： Robert E. Malec , Larry Plonsker
IPC分类号： C08G8/28 , C08L101/00 , C09K15/08 , C09K15/14 , C10M169/00 , C10M1/38
CPC分类号： C10M1/08 , C08G8/28 , C08L101/00 , C09K15/14 , C10M2203/06 , C10M2205/00 , C10M2205/026 , C10M2205/028 , C10M2207/027 , C10M2207/04 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/30 , C10M2207/302 , C10M2207/304 , C10M2207/34 , C10M2209/00 , C10M2209/02 , C10M2209/084 , C10M2209/10 , C10M2215/04 , C10M2215/065 , C10M2215/26 , C10M2217/042 , C10M2217/043 , C10M2217/046 , C10M2217/06 , C10M2219/044 , C10M2219/046 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2221/00 , C10M2223/041 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10M2225/041 , C10M2227/02 , C10M2229/041 , C10N2210/02 , C10N2230/08 , C10N2240/12 , C10N2240/121
摘要： Organic material is stabilized by addition of a sulfurized product made by heating a mixture of (a) sulfur and (b) a reaction product formed by reacting in the presence of an alkali metal hydroxide catalyst (i) a mixture of at least two different alkylphenols, each having an unsubstituted ortho and/or para position, and (ii) formaldehyde. Preferably, the reaction product is formed in the presence of a small amount of primary lower alkanol such as methanol. When added to lubricating oil the sulfurized products also impart wear and corrosion inhibiting properties.
摘要翻译：通过加入通过加热（a）硫和（b）通过在碱金属氢氧化物催化剂（i）至少两种不同的烷基酚的混合物的存在下反应形成的反应产物而制备的硫化产物来稳定有机材料各自具有未取代的邻位和/或对位，和（ii）甲醛。优选地，反应产物在少量初级低级链烷醇如甲醇的存在下形成。当添加到润滑油中时，硫化产品也赋予耐磨和腐蚀抑制性能。

16. 发明授权

US4248182A Anti-wear additives in diesel fuels 失效
标题翻译：柴油燃料中的耐磨添加剂
公开(公告)号：US4248182A
公开(公告)日：1981-02-03
申请号：US72031
申请日：1979-09-04
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22 , F02B3/06
CPC分类号： C10L10/08 , C10L1/14 , C10L1/18 , C10L1/1824 , C10L1/1881 , C10L1/231 , F02B3/06
摘要： An anti-wear compression ignition fuel for use in diesel engines comprising (1) a monohydroxy alkanol having from 1 to 5 carbon atoms, and (2) a wear inhibiting amount of a C.sub.8 to C.sub.20 aliphatic monocarboxylic acid. Optionally, said fuel composition may also contain an ignition accelerator such as an organic nitrate.
摘要翻译：一种用于柴油发动机的抗磨压缩点火燃料，包括（1）具有1至5个碳原子的单羟基烷醇，和（2）耐磨损量为C8至C20脂族一元羧酸。任选地，所述燃料组合物还可以含有点火促进剂，例如有机硝酸盐。

17. 发明授权

US4242099A Fuel additive for diesel fuels 失效
标题翻译：柴油燃料添加剂
公开(公告)号：US4242099A
公开(公告)日：1980-12-30
申请号：US10523
申请日：1979-02-09
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： C10L1/02 , C10L1/14 , C10L1/18 , C10L1/22 , F02B3/06
CPC分类号： C10L10/08 , C10L1/026 , C10L1/14 , C10L1/18 , C10L1/1824 , C10L1/1883 , C10L1/231 , F02B3/06
摘要： An anti-wear compression ignition fuel for use in diesel engines comprising (1) a monohydroxy alkanol having from 1 to 5 carbon atoms, and (2) a wear inhibiting amount of a C.sub.12 to C.sub.30 hydrocarbyl succinic acid or anhydride, e.g. tetrapropenyl succinic acid. Optionally, said fuel composition may also contain an ignition accelerator such as an organic nitrate.It has recently been disclosed in Brazilian Patent Application No. P17700392 that alcohols, such as methanol and ethanol, can be substituted for conventional petroleum derived diesel fuels for burning in diesel engines, when used in combination with an ignition accelerator, such as ethyl nitrate or nitrite. Reportedly, the addition of alkyl nitrate or nitrite accelerators to the alcohol achieves a level of auto-ignition sufficient to operate in diesel engines. Unfortunately, these fuel compositions, devoid of any petroleum derived products, are notably deficient in lubricity or lubricating properties with the result that engine wear from the use of these fuels in internal combustion reciprocating diesel engines is a serious problem. Of particular concern are wear problems associated with the fuel injector mechanism used in such engines. Wear problems have also been encountered in diesel engines operating on light diesel fuel oils as disclosed in U.S. Pat. No. 4,002,437.
摘要翻译：一种用于柴油发动机的抗磨压缩点火燃料，包括（1）具有1至5个碳原子的单羟基链烷醇，和（2）耐磨损量的C 12至C 30烃基琥珀酸或酸酐，例如，四丙烯基琥珀酸。任选地，所述燃料组合物还可以含有点火促进剂，例如有机硝酸盐。最近在巴西专利申请P17700392中公开了，当与点燃促进剂如硝酸乙酯或硝酸乙酯组合使用时，诸如甲醇和乙醇的醇可以代替常规的柴油发动机燃烧柴油，亚硝酸盐据报道，向醇中加入硝酸烷基酯或亚硝酸盐促进剂达到足以在柴油发动机中运行的自动点火水平。不幸的是，没有任何石油衍生产品的这些燃料组合物显着地缺乏润滑性或润滑性能，结果是在内燃往复式柴油发动机中使用这些燃料的发动机磨损是严重的问题。特别令人关注的是与这种发动机中使用的燃料喷射器机构有关的磨损问题。美国专利公开中公开的在轻柴油燃料油的柴油发动机中也遇到磨损问题。第4,002,437号。

18. 发明授权

US4198931A Diesel fuel 失效
标题翻译：柴油染料
公开(公告)号：US4198931A
公开(公告)日：1980-04-22
申请号：US8752
申请日：1979-02-01
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： C10L1/02 , C10L1/14 , C10L1/18 , C10L1/22 , F02B3/06
CPC分类号： C10L10/08 , C10L1/026 , C10L1/14 , C10L1/1824 , C10L1/224 , C10L1/231 , F02B3/06
摘要： An anti-wear compression ignition fuel for use in diesel engines comprising (1) a monohydroxy alkanol having from 1 to 5 carbon atoms, and (2) a wear inhibiting amount of an N-hydroxy hydrocarbonamide, e.g. N-hydroxy oleamide. Optionally, said fuel composition may also contain an ignition accelerator such as an organic nitrate.
摘要翻译：一种用于柴油发动机的抗磨压缩点火燃料，包括（1）具有1至5个碳原子的单羟基烷醇，和（2）耐磨损量的N-羟基烃酰胺，例如， N-羟基油酰胺。任选地，所述燃料组合物还可以含有点火促进剂，例如有机硝酸盐。

19. 发明授权

US4186102A Lubricating oil composition 失效
标题翻译：润滑油组成
公开(公告)号：US4186102A
公开(公告)日：1980-01-29
申请号：US923070
申请日：1978-07-10
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： B01F17/00 , C10L1/22 , C10M159/16 , C10M3/26 , C07C87/28
CPC分类号： B01F17/0042 , C10L1/221 , C10M1/08 , C10M159/16 , C10M2203/06 , C10M2205/00 , C10M2205/026 , C10M2205/028 , C10M2205/04 , C10M2207/024 , C10M2207/027 , C10M2207/282 , C10M2207/30 , C10M2207/302 , C10M2207/304 , C10M2207/34 , C10M2209/084 , C10M2209/11 , C10M2215/04 , C10M2215/062 , C10M2215/26 , C10M2217/042 , C10M2217/043 , C10M2217/046 , C10M2217/06 , C10M2219/044 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10M2225/041 , C10N2210/02 , C10N2270/02
摘要： The reaction product of (a) high molecular weight hydrocarbon-substituted phenols, (b) aldehydes, (c) ammonia or amines having a reactive hydrogen atom, and (d) alkylene oxides are effective dispersants for lubricating oil and impart detergent properties to liquid hydrocarbon fuels such as gasoline.
摘要翻译：（a）高分子量烃取代的酚，（b）醛，（c）氨或具有反应性氢原子的胺的反应产物和（d）环氧烷烃是用于润滑油的有效分散剂并赋予液体洗涤剂性能烃燃料如汽油。

20. 发明授权

US4108858A Polyolefin quaternary pyridinium salts 失效
标题翻译：聚烯烃季吡啶鎓盐
公开(公告)号：US4108858A
公开(公告)日：1978-08-22
申请号：US736842
申请日：1976-10-29
申请人： Robert E. Malec
发明人： Robert E. Malec
IPC分类号： C07D213/20 , C07D487/18 , C10L1/2383 , C10L1/2387 , C10M133/52 , C07D213/04
CPC分类号： C10L1/2383 , C07D213/20 , C10L1/2387 , C10M133/52 , C10M2201/062 , C10M2203/06 , C10M2205/022 , C10M2205/024 , C10M2205/026 , C10M2205/028 , C10M2205/04 , C10M2205/14 , C10M2207/027 , C10M2207/04 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/30 , C10M2207/302 , C10M2207/34 , C10M2209/00 , C10M2209/02 , C10M2209/084 , C10M2209/10 , C10M2209/103 , C10M2211/02 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/062 , C10M2215/065 , C10M2215/066 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06 , C10M2219/044 , C10M2219/046 , C10M2219/068 , C10M2219/108 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/043 , C10M2223/045 , C10M2223/047 , C10M2223/065 , C10M2227/02 , C10M2227/061 , C10M2229/02 , C10M2229/041 , C10M2229/05 , C10N2210/02 , C10N2270/02
摘要： High molecular weight N-hydrocarbyl-substituted quaternary ammonium salts in which the hydrocarbyl group has a molecular weight of from about 350-3,000 such as a polybutene ammonium chloride are effective detergents and dispersants for gasoline and lubricating oils.
摘要翻译：高分子量N-烃基取代的季铵盐，其中烃基具有约350-3,000的分子量，例如聚丁烯氯化铵，是汽油和润滑油的有效洗涤剂和分散剂。

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