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    • 11. 发明授权
    • Electrophotographic image forming apparatus using photoconductive toner
    • 使用光电导体的电子图像形成装置
    • US5053821A
    • 1991-10-01
    • US479001
    • 1990-02-12
    • Masanao KunugiHajime KuriharaTeruyuki Mizumoto
    • Masanao KunugiHajime KuriharaTeruyuki Mizumoto
    • G03G9/09G03G13/01G03G15/34
    • G03G13/016G03G15/344G03G9/091G03G9/0916G03G9/0926G03G2215/0497G03G2217/0091
    • A photoconductive image forming apparatus in which charged photoconductive toner contacts a transparent insulating substrate and is exposed from within the substrate. Exposure reduces the resistivity of the toner so that its charge can be reversed by a bias voltage and the exposed toner will adhere to the image forming substrate simultaneously with exposure and then transfer to a transfer medium. In an alternative embodiment of the invention, a layer of toner is applied to an electroconductive substrate and the toner layer is exposed with a latent image. The charge of the exposed toner is reversed and the exposed toner is removed by an intermediate toner removal device. The remaining toner is then transferred to a transfer medium. Toner suitable for use includes azo-type metal containing black dyes which do not absorb the exposure and can be sensitized to the near infrared region. Multicolor toners, each sensitized to a different exposure wavelength are provided so that a single multiple wavelength exposure and a single development can be used to form multicolor images.
    • 一种感光图像形成装置,其中带电的光电导调色剂接触透明绝缘基板并从基板内露出。 曝光降低了调色剂的电阻率,使得其电荷可以通过偏置电压反转,并且暴露的调色剂将在曝光的同时粘附到成像基板上,然后转印到转印介质上。 在本发明的替代实施例中,将一层调色剂施加到导电基底上,并且调色剂层用潜像曝光。 曝光的调色剂的电荷反转,并且通过中间调色剂去除装置去除曝光的调色剂。 然后将剩余的调色剂转移到转印介质。 适合使用的调色剂包括不吸收曝光并且可以对近红外区域敏化的偶氮型金属黑色染料。 提供每种对不同曝光波长敏感的多色调色剂,使得可以使用单次多波长曝光和单次显影来形成多色图像。
    • 16. 发明授权
    • Developing method and image forming method
    • 开发方法和图像形成方法
    • US07041423B2
    • 2006-05-09
    • US10670798
    • 2003-09-26
    • Masanao KunugiAtsunori KitazawaHiroshi Toyama
    • Masanao KunugiAtsunori KitazawaHiroshi Toyama
    • G03G15/08
    • G03G15/0812G03G2215/0617
    • A developing method, including the steps of: carrying one-component non-magnetic toner on a developer carrier; pressing the one-component non-magnetic toner by a regulating member so as to regulate a transporting quantity of the one-component non-magnetic toner so that the one-component non-magnetic toner is charged; forming an electrostatic latent image on an image carrier; providing the one-component non-magnetic toner to the electrostatic latent image so as to convert the electrostatic latent image into a visible toner image; and controlling the one-component non-magnetic toner so that the one-component non-magnetic toner pressed by the regulating member satisfies the following relationship: B/A≦1, where A represents a width [μm] of a particle size distribution of the one-component non-magnetic toner; and B represents a width [fC] of a charge quantity distribution of the one-component non-magnetic toner.
    • 一种显影方法,包括以下步骤:在显影剂载体上携带单组分非磁性调色剂; 通过调节构件按压单组分非磁性调色剂,以调节单​​组分非磁性调色剂的输送量,使单组分非磁性调色剂充电; 在图像载体上形成静电潜像; 将所述单组分非磁性调色剂提供给所述静电潜像,以便将所述静电潜像转化为可见的调色剂图像; 并且控制单组分非磁性调色剂使由调节构件按压的单组分非磁性调色剂满足以下关系:B / A <= 1,其中A表示粒度分布的宽度[mum] 的单组分非磁性调色剂; B表示单组分非磁性调色剂的电荷量分布的宽度[fC]。
    • 17. 发明申请
    • Toner quantity measuring device, method of measuring toner quantity and image forming apparatus
    • 调色剂量测量装置,测量调色剂量的方法和图像形成装置
    • US20050196188A1
    • 2005-09-08
    • US11070409
    • 2005-03-01
    • Masanao KunugiMitsutaka Nishikawa
    • Masanao KunugiMitsutaka Nishikawa
    • G03G15/00G03G15/08
    • G03G15/0862G03G15/5041G03G15/5054G03G15/556
    • A toner quantity measuring device, a method of measuring toner quantity and an image forming apparatus are provided that can accurately measure the toner quantity in an environmentally friendly manner, without having to make contact with a toner carrier and within a shortened period of time. The toner quantity measuring device is designed to measure the quantity of the toner T on a developing roller 510 which carries coloring agent-containing toner T in the form of a thin layer. The toner quantity measuring device is provided with a chromaticity detector 3 for detecting average chromaticity of the light which is irradiated from a light source 2 onto the developing roller 510 and then reflected by the developing roller 510, and a calculator 4 for calculating the toner quantity based on the average chromaticity detected by the chromaticity detector 3.
    • 提供了一种调色剂量测量装置,一种测量调色剂量的方法和一种图像形成装置,其可以以无害环境的方式精确地测量调色剂量,而不必与调色剂载体接触并且在缩短的时间段内。 调色剂量测量装置被设计成测量携带着色剂的调色剂T以薄层形式的显影辊510上的调色剂T的量。 调色剂量测量装置设置有用于检测从光源2照射到显影辊510上然后被显影辊510反射的光的平均色度的色度检测器3和用于计算调色剂量的计算器4 基于由色度检测器3检测出的平均色度。
    • 18. 发明授权
    • Non-magnetic single-component toner, method of preparing the same, and image forming apparatus using the same
    • 非磁性单组分调色剂,其制备方法和使用其的成像装置
    • US06875550B2
    • 2005-04-05
    • US10191752
    • 2002-07-10
    • Nobuhiro MiyakawaTakuya KadotaHidehiro TakanoShinji YasukawaMasanao Kunugi
    • Nobuhiro MiyakawaTakuya KadotaHidehiro TakanoShinji YasukawaMasanao Kunugi
    • G03G9/08G03G9/087G03G9/097
    • G03G9/09708G03G9/0819G03G9/08711G03G9/08755G03G9/09716G03G9/09725
    • A non-magnetic single-component toner 8 of the present invention has toner mother particles 8a, and external additives 12 comprising: two hydrophobic silicas 13, 14 of which particle diameters are different from each other, i.e. a mean primary particle diameter of 7 nm to 12 nm and a mean primary particle diameter of 40 nm to 50 nm, and a hydrophobic rutile/anatase type titanium oxide 15 having a spindle shape of which major axial diameter is in a range from 0.02 nm to 0.10 nm and the ratio of the major axial diameter to the minor axial diameter is set to be 2 to 8, wherein the external additives 12 adhere to the toner mother particles 8a. By the hydrophobic silicas 13, 14 having work function smaller than the work function of the toner mother particles 8a, the negative charging property is imparted to the toner mother particles 8a and the fluidity is also insured. On the other hand, by mixing and using hydrophobic rutile/anatase type titanium oxide particles 15 having work function larger than or equal to the work function of the toner mother particles 8a together with the hydrophobic silicas 13, 14, the non-magnetic single-component toner 8 is prevented from excessively charged. Therefore, the amount of fog toner on non-image portions is reduced, the transfer efficiency is further improved, the charging property is further stabilized, and the production of reverse transfer toner is further inhibited.
    • 本发明的非磁性单组分调色剂8具有调色剂母粒子8a和外部添加剂12,其包含:两个粒径彼此不同的疏水性二氧化硅13,14,即平均一次粒径为7nm 平均一次粒径为40nm〜50nm的疏水性金红石/锐钛矿型氧化钛15,主轴的直径为0.02nm〜0.10nm的主轴形状, 小轴向直径的主轴径设定为2〜8,其中外部添加剂12粘附到调色剂母粒8a上。 通过具有小于调色剂母粒子8a的功函数的功函数的疏水性二氧化硅13,14赋予调色剂母粒子8a的负带电性,并且还保证了流动性。 另一方面,通过将功能大于或等于调色剂母粒8a的功函数的疏水性金红石/锐钛矿型氧化钛粒子15与疏水性二氧化硅13,14混合并使用, 防止组分调色剂8过度充电。 因此,非图像部分上的雾化调色剂的量减少,转印效率进一步提高,充电性能进一步稳定,并进一步抑制反转印调色剂的生产。
    • 19. 发明授权
    • Image receiving sheet and image receiving apparatus using the same
    • 图像接收片和使用其的图像接收装置
    • US06312788B1
    • 2001-11-06
    • US08861655
    • 1997-05-22
    • Shuhei MohriTahei IshiwatariMasanao Kunugi
    • Shuhei MohriTahei IshiwatariMasanao Kunugi
    • B32B300
    • G03G7/0046B41M5/52B41M5/5272G03G7/0006G03G7/002Y10T428/24802
    • An image is formed in a receiving sheet by embedding toner in an image receiving layer on a base. The distribution of molecular weight of resin in the image receiving layer measured by gel permeation chromatography (GPC) of soluble matters of tetrahydrofuran (THF) has at least two peaks or shoulders. And the critical surface tension of the image receiving layer is made to be smaller than the critical surface tension of external additive. Further, the image receiving layer has a thermal characteristic such that a storage modulus (G′) of 1×102 Pa to 1×105 Pa and a loss modulus (G″) of 1×102 Pa to 1×105 Pa at temperatures at which the toner is fixed. Furthermore, the image receiving layer contains an aromatic ester compound, more preferably the aromatic polyester compound being dialkyl phthalate. Still further, the image receiving layer has a Rockwell hardness (R scale) HRa of 121 or lower.
    • 通过将调色剂嵌入到基底上的图像接收层中,在接收片中形成图像。 通过四氢呋喃(THF)的可溶性物质的凝胶渗透色谱(GPC)测量的图像接收层中树脂的分子量分布至少具有两个峰或多个肩峰。 使图像接收层的临界表面张力小于外部添加剂的临界表面张力。 此外,图像接收层具有使得在调色剂固定的温度下,1x102Pa至1×105Pa的储能模量(G')为1×102Pa至1×105Pa的损耗模量(G“)的热特性。 此外,图像接收层含有芳族酯化合物,更优选芳族聚酯化合物为邻苯二甲酸二烷基酯。 此外,图像接收层的洛氏硬度(R刻度)HRa为121以下。