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    • 19. 发明授权
    • Process for liquefying a hydrocarbon-rich stream
    • 液化富烃流的方法
    • US06334334B1
    • 2002-01-01
    • US09629089
    • 2000-07-31
    • Rudolf StockmannManfred BöltManfred SteinbauerChristian PfeifferPentti PaurolaWolfgang FörgArne Olav FredheimOystein Sorensen
    • Rudolf StockmannManfred BöltManfred SteinbauerChristian PfeifferPentti PaurolaWolfgang FörgArne Olav FredheimOystein Sorensen
    • F25J100
    • F25J1/0291C09K5/04C09K5/042C09K2205/132F25B9/006F25J1/0022F25J1/0042F25J1/0055F25J1/0057F25J1/0092F25J1/0212F25J2240/40
    • In the liquefaction of a hydrocarbon by indirect heat exchange with the refrigerant mixture of a refrigerant mixture cycle, the refrigerant mixture being compressed in multiple stages, the compressed refrigerant mixture (23) is at least partially condensed (E4) downstream of the penultimate compressor stage and is fractionated (D4) into a higher-boiling liquid fraction (26) and a lower-boiling gas fraction (24). The lower-boiling gas fraction (24) is compressed to the final pressure, partially condensed (E5) and fractionated (D5) into a lower-boiling gas fraction (10) and a higher-boiling liquid fraction (27). The higher-boiling liquid fraction (27) is added to the partially condensed refrigerant mixture stream (23), and the gas fraction (10) forms the lower-boiling refrigerant mixture fraction and the liquid fraction (26) forms the higher boiling refrigerant mixture fraction of the refrigerant mixture cycle. Alternatively, the compressed refrigerant mixture (20, 31, 34) can be partially condensed (E3, E4, E5) after each compressor stage and fractionated in each case into a lower-boiling gas fraction (21, 32, 10) and a higher-boiling liquid fraction (30, 33, 35). Only the gas fraction (21, 32) from the partial condensation (E3, E4) in each case is further compressed and the liquid fractions (33, 35) from the second fractionation (D4, D5) are added to the partially condensed stream (20) from the first compressor stage upstream of its fractionation (D3). The gas fraction (10) from the final fractionation (D5) forms the lower-boiling refrigerant mixture fraction and the liquid fraction (30) from the first fractionation (D3) forms the higher-boiling refrigerant mixture fraction of the refrigerant mixture cycle.
    • 在通过与制冷剂混合循环的制冷剂混合物间接热交换的烃液化中,制冷剂混合物被多级压缩,压缩的制冷剂混合物(23)在倒数第二个压缩机级的下游至少部分地冷凝(E4) 并将其分馏成高沸点液体馏分(26)和低沸点气体馏分(24)。 将低沸点气体馏分(24)压缩至最终压力,部分冷凝(E5)并分馏(D5)成低沸点气体馏分(10)和较高沸点液体馏分(27)。 将较高沸点的液体馏分(27)加入到部分冷凝的制冷剂混合物流(23)中,并且气体馏分(10)形成低沸点制冷剂混合物馏分,液体馏分(26)形成较高沸点的制冷剂混合物 制冷剂混合循环的分数。 或者,压缩的制冷剂混合物(20,31,34)可以在每个压缩机级之后被部分冷凝(E3,E4,E5),并且在每种情况下分馏成低沸点气体馏分(21,32,10)和更高的 沸腾的液体馏分(30,33,35)。 在每种情况下,只有来自部分冷凝(E3,E4)的气体馏分(21,32)被进一步压缩,并且将来自第二分馏(D4,D5)的液体馏分(33,35)加入到部分冷凝的流中 20)从其分馏(D3)上游的第一压缩机级。 来自最终分馏(D5)的气体馏分(10)形成低沸点制冷剂混合物馏分,来自第一馏分(D3)的液体馏分(30)形成制冷剂混合循环的较高沸点的制冷剂混合物馏分。