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11. 发明授权

US09150755B2 Silicone composition that can be cross-linked by means of dehydrogenative condensation in the presence of a carbene-type catalyst 有权
标题翻译：可在卡宾型催化剂存在下通过脱氢缩合交联的硅氧烷组合物
公开(公告)号：US09150755B2
公开(公告)日：2015-10-06
申请号：US14130746
申请日：2012-07-06
申请人： Christian Maliverney , Laurent Saint-Jalmes
发明人： Christian Maliverney , Laurent Saint-Jalmes
IPC分类号： C08G77/08 , C09D183/06 , C08L83/04 , C09D183/04 , C08F4/00 , C08J9/00 , C08J9/02 , C08G77/12 , C08G77/16
CPC分类号： C08K3/0033 , C08F4/00 , C08G73/0616 , C08G77/08 , C08G77/12 , C08G77/16 , C08J9/0023 , C08J9/02 , C08J2201/026 , C08J2383/04 , C08J2383/05 , C08J2383/06 , C08K3/013 , C08L83/04 , C09D183/04 , C09D183/06 , Y10T428/31663
摘要： The invention relates to a silicone composition comprising components bearing ≡SiH/≡SiOH groups, which can be polymerized/cross-linked by means of a dehydrogenative condensation reaction in the presence of a carbene-type catalyst in solution.
摘要翻译：本发明涉及含有≡SiH/≡SiOH基团的组分的硅氧烷组合物，其可以在溶液中的卡宾型催化剂存在下通过脱氢缩合反应进行聚合/交联。

12. 发明授权

US08835590B2 Room temperature vulcanizable organopolysiloxane compound to give an elastomer and novel organopolysiloxane polycondensation catalysts 有权
标题翻译：室温硫化有机聚硅氧烷化合物，得到弹性体和新型有机聚硅氧烷缩聚催化剂
公开(公告)号：US08835590B2
公开(公告)日：2014-09-16
申请号：US12809552
申请日：2008-12-18
申请人： Christian Maliverney , Laurent Saint-Jalmes
发明人： Christian Maliverney , Laurent Saint-Jalmes
IPC分类号： C08L83/04 , C08G77/08 , C08G77/18 , C08G77/14
CPC分类号： C08L83/04 , C08G77/08 , C08G77/14 , C08G77/18
摘要： The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.
摘要翻译：本发明涉及可在室温下硫化成通过缩聚交联并且不含烷基锡基催化剂的弹性体以及新型有机聚硅氧烷缩聚催化剂的有机聚硅氧烷组合物。

13. 发明申请

US20110065955A1 Method For Preparing Difluoroacetic Acid and Salts Thereof 失效
标题翻译：二氟乙酸及其盐的制备方法
公开(公告)号：US20110065955A1
公开(公告)日：2011-03-17
申请号：US12933646
申请日：2009-03-09
申请人： François Metz , Laurent Saint-Jalmes
发明人： François Metz , Laurent Saint-Jalmes
IPC分类号： C07C53/21 , C07C45/00
CPC分类号： C07C51/04 , C07C51/58 , C07C53/18 , C07C53/48
摘要： The invention relates to a method for preparing difluoroacetic acid and the salts thereof. The invention also relates to the preparation of difluoroacetyl fluoride used as an intermediate product in the preparation of difluoroacetic acid. The method for preparing difluoroacetic acid according to the invention is characterised in that the same comprises the step of preparing difluoroacetyl fluoride by reacting dichloroacetyl chloride with hydrofluoric acid in a gaseous phase and in the presence of a chromium-based catalyst, followed by the step of hydrolysing the difluoroacetyl fluoride thus obtained.
摘要翻译：本发明涉及二氟乙酸及其盐的制备方法。本发明还涉及在二氟乙酸的制备中用作中间产物的二氟乙酰氟的制备。根据本发明的制备二氟乙酸的方法的特征在于，其包括通过使二氯乙酰氯与氢氟酸在气相中和在铬基催化剂存在下反应制备二氟乙酰氟的步骤，接着是水解由此获得的二氟乙酰氟。

14. 发明申请

US20110040033A1 ROOM TEMPERATURE VULCANISABLE ORGANOPOLYSILOXANE COMPOUND TO GIVE AN ELASTOMER AND NOVEL ORGANOPOLYSILOXANE POLYCONDENSATION CATALYSTS 有权
公开(公告)号：US20110040033A1
公开(公告)日：2011-02-17
申请号：US12809532
申请日：2008-12-18
申请人： Christian Maliverney , Laurent Saint-Jalmes
发明人： Christian Maliverney , Laurent Saint-Jalmes
IPC分类号： C08L83/04 , C08G77/04 , C07F1/08 , C07F9/94
CPC分类号： C08K5/42 , C08K5/0091 , C08K5/56 , C08L83/04
摘要： The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.

15. 发明申请

US20090299024A1 METHOD FOR CONDENSING SILYL UNITS USING A CARBENE CATALYST 有权
标题翻译：使用碳酸酯催化剂冷凝硅烷单体的方法
公开(公告)号：US20090299024A1
公开(公告)日：2009-12-03
申请号：US12297754
申请日：2007-04-20
申请人： Antoine Baceiredo , Etienne Fleury , Tsuyoshi Kato , Sébastien Marrot , Laurent Saint-Jalmes
发明人： Antoine Baceiredo , Etienne Fleury , Tsuyoshi Kato , Sébastien Marrot , Laurent Saint-Jalmes
IPC分类号： C08G77/08 , C08G77/04
CPC分类号： C08G77/08
摘要： A process for condensation between at least one ≡SiOH unit and at least one ≡SiOR unit is provided. In accordance with the present invention, R=a hydrogen or a C1-C20 hydrocarbon group optionally comprising one or more heteroatoms, and the ≡SiOH and ≡SiOR units belong to at least one identical or different (organo)silicon compound P. The process is conducted in the presence of an effective amount of at least one catalyst C, comprising a carbene. Compositions are also provided.
摘要翻译：提供了至少一种≡SiOH单元和至少一个≡SiOR单元之间的冷凝过程。根据本发明，R =氢或任选包含一个或多个杂原子的C 1 -C 20烃基，≡SiOH和≡SiOR单元属于至少一个相同或不同（有机）硅化合物P。该方法在有效量的至少一种包含卡宾的催化剂C的存在下进行。还提供了组合。

16. 发明申请

US20090234151A1 Preparation of Mono-/Difluorinated Hydrocarbon Compounds 审中-公开
标题翻译：单/二氟烃化合物的制备
公开(公告)号：US20090234151A1
公开(公告)日：2009-09-17
申请号：US11989143
申请日：2006-07-07
申请人： Laurent Saint-Jalmes , Daniel Uguen
发明人： Laurent Saint-Jalmes , Daniel Uguen
IPC分类号： C07C67/287 , C07C17/16 , C07C17/18
CPC分类号： C07C45/63 , C07C17/16 , C07C17/18 , C07C19/08 , C07C22/08 , C07C41/22 , C07C49/697 , C07C49/813 , C07C67/307 , C07D213/61 , C07C69/65 , C07C43/225
摘要： Mono- or difluorinated hydrocarbon compounds are prepared from an alcohol or a carbonylated compound by reacting one of these with a fluorinating reagent, optionally in the presence of a base, the fluorinating agent comprising a pyridinium reactant having the following formula (F), wherein R0 is an alkyl or cycloalkyl radical:
摘要翻译：通过使这些与氟化试剂之一，任选在碱的存在下，通过使氟化剂包含具有下式（F）的吡啶鎓反应物，从醇或羰基化化合物制备单 - 或二氟化烃化合物，其中R 0 是烷基或环烷基：

17. 发明申请

US20070276153A1 Diastereoselective Method of Preparing Olefins by Means of the Horner-Wadsworth-Emmons Reaction Using a Particular Phosphonate Which Improves Diastereoselectivity at all Temperatures Including at Ambient Temperature 审中-公开
标题翻译：通过Horner-Wadsworth-Emmons反应制备烯烃的非对映选择方法，使用特殊的膦酸酯改善包括在环境温度下的所有温度下的非对映体选择性
公开(公告)号：US20070276153A1
公开(公告)日：2007-11-29
申请号：US10578396
申请日：2004-11-04
申请人： François Touchard , Laurent Saint-Jalmes
发明人： François Touchard , Laurent Saint-Jalmes
IPC分类号： C07C67/313
CPC分类号： C07C45/72 , C07B37/04 , C07C67/343 , C07C2601/14 , C07F9/4084 , C07C69/608 , C07C69/618 , C07C69/533
摘要： The invention relates to a diastereoselective process for the preparation of olefins by the Horner-Wadsworth-Emmons reaction which consists in reacting a specific phosphonate improve the diastereoselectivity at all temperatures including at ambient temperature, with a carbonyl derivative in the presence of a base in an appropriate solvent.
摘要翻译：本发明涉及通过Horner-Wadsworth-Emmons反应制备烯烃的非对映选择性方法，该方法包括使特定的膦酸酯在包括环境温度在内的所有温度下与羰基衍生物在碱存在下改善非对映选择性适当的溶剂。

18. 发明授权

US06201149B1 Organic base hydrogenofluorosulphonates, their use in releasing organic bases from their fluorohydrate, method of preparation thereof, compound containing them 失效
标题翻译：有机碱氢氟代磺酸盐，它们用于从其氟代水合物中释放有机碱，其制备方法，含有它们的化合物
公开(公告)号：US06201149B1
公开(公告)日：2001-03-13
申请号：US09171990
申请日：1999-01-19
申请人： Laurent Saint-Jalmes , Marcel Morel
发明人： Laurent Saint-Jalmes , Marcel Morel
IPC分类号： C07C20984
CPC分类号： C01B7/191 , C01B7/195 , C07C209/62 , C07C209/84 , Y02P20/582
摘要： The invention features the use of fluorosulphonates to release the organic bases from their fluorohydrate. This use is characterised in that a hydrogenofluorosulphonate of an organic base is formed and in that the hydrofluoric acid which is associated with the said base or with one of its precursors is separated therefrom. The invention is useful in organic synthesis applications.
摘要翻译：本发明的特征在于使用氟磺酸盐从其氟代水合物中释放有机碱。该用途的特征在于形成有机碱的氟代氟磺酸盐，并且与所述碱或其前体之一相连的氢氟酸与其分离。本发明在有机合成应用中是有用的。

19. 发明授权

US5756849A Process for grafting a substituted difluoromethyl group onto a compound containing an electrophilic functional group 失效
标题翻译：将取代的二氟甲基接枝到含有亲电子官能团的化合物上的方法
公开(公告)号：US5756849A
公开(公告)日：1998-05-26
申请号：US620348
申请日：1996-03-22
申请人： Gerard Forat , Jean-Manuel Mas , Laurent Saint-Jalmes
发明人： Gerard Forat , Jean-Manuel Mas , Laurent Saint-Jalmes
IPC分类号： C07B37/04 , C07B39/00 , C07C22/08 , C07C29/38 , C07C29/62 , C07C29/64 , C07C31/38 , C07C31/44 , C07C33/46 , C07C45/48 , C07C45/70 , C07C45/74 , C07C49/613 , C07C51/363 , C07C53/15 , C07C53/18 , C07C253/30 , C07C319/14 , C07C323/03 , C07C323/09 , C07C315/00
CPC分类号： C07C319/14 , C07C253/30 , C07C29/38 , C07C29/62 , C07C45/48 , C07C45/70 , C07C45/74 , C07C51/363 , C07C2101/14 , Y02P20/582
摘要： The invention relates to a process and a nucleophilic reagent which is useful for grafting a substituted difluoromethyl group onto a compound containing at least one electrophilic function, characterized in that it comprises: a) a fluorocarboxylic acid of formula Ew--CF.sub.2 --COOH where Ew represents an electron-withdrawing atom or group, at least partially salified with an organic or inorganic cation, and b) a polar aprotic solvent; and in that the content of releasable protons carried by its various components, including their impurities, is at most equal to half the initial molar concentration of the said fluorocarboxylic acid.
摘要翻译：本发明涉及可用于将取代的二氟甲基接枝到含有至少一种亲电子功能的化合物上的方法和亲核试剂，其特征在于其包含：a）式Ew-CF2-COOH的氟代羧酸，其中Ew表示至少部分用有机或无机阳离子盐化的吸电子原子或基团，和b）极性非质子溶剂; 并且由其各种组分（包括其杂质）携带的可释放质子的含量最多等于所述氟代羧酸的初始摩尔浓度的一半。

20. 发明授权

US09102780B2 Catalysts for reaction between an isocyanate and an alcohol 有权
标题翻译：异氰酸酯与醇反应的催化剂
公开(公告)号：US09102780B2
公开(公告)日：2015-08-11
申请号：US13123981
申请日：2009-10-12
申请人： Christian Maliverney , Laurent Saint-Jalmes
发明人： Christian Maliverney , Laurent Saint-Jalmes
IPC分类号： C08G18/18 , C08G18/30 , C08G18/42 , C07C269/02 , C08J9/08 , C08G18/08 , C08G18/28 , C08G18/48
CPC分类号： C08G18/1816 , C07C269/02 , C08G18/14 , C08G18/1808 , C08G18/1858 , C08G18/2815 , C08G18/42 , C08G18/4825 , C08J9/08
摘要： Processes are described for preparing polyurethane polymers by reacting an isocyanate with an alcohol using a non-tin based catalyst having the formula where R1, which are identical or different, are a fluoroalkyl, monovalent alkyl, cycloalkyl, (cycloalkyl)alkyl, or the ring of the cycloalkyl group that optionally comprises at least one heteroatom, R2 represents a hydrogen atom, an aromatic, arylalkyl, fluoroalkyl, alkylamine, alkylguanidine, monovalent alkyl, cycloalkyl or an alkyl group substituted by an optionally substituted ring, which optionally comprises at least one heteroatom, and R3 represents an arylalkyl, fluoroalkyl, alkylamine, alkylguanidine, monovalent alkyl, cylcoalkyl, or alkyl group substituted by an optionally substituted ring which optionally comprises at least one heteroatom, when the R2 radical is not a hydrogen atom, the R2 and R3 radicals optionally being linked to form a 3 to 7 membered optionally substituted aliphatic ring, and the R1, R2 and R3 radicals do not comprise a silicon atom.
摘要翻译：描述了通过使用具有下式的非锡基催化剂使异氰酸酯与醇反应制备聚氨酯聚合物的方法，其中相同或不同的R 1是氟烷基，一价烷基，环烷基，（环烷基）烷基或环任选地包含至少一个杂原子的环烷基，R 2表示氢原子，芳族，芳基烷基，氟烷基，烷基胺，烷基胍，一价烷基，环烷基或被任选取代的环取代的烷基，其任选地包含至少一个并且R 3表示芳基烷基，氟代烷基，烷基胺，烷基胍，一价烷基，环烷基或任意取代的环取代的烷基，其任选地包含至少一个杂原子，当R 2基团不是氢原子时，R 2和R 3 可任意连接的基团形成3至7元任选取代的脂族环，并且R 1，R 2和R 3基团为n 其包含硅原子。

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