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11. 发明授权

US09162220B2 Catalyst support material comprising polyazole, electrochemical catalyst, and the preparation of a gas diffusion electrode and a membrane-electrode assembly therefrom 有权
标题翻译：催化剂载体材料包括聚唑，电化学催化剂，以及气体扩散电极和膜 - 电极组合物的制备
公开(公告)号：US09162220B2
公开(公告)日：2015-10-20
申请号：US13278792
申请日：2011-10-21
申请人： Ömer Ünsal , Sigmar Bräuninger , Claudia Querner , Ekkehard Schwab
发明人： Ömer Ünsal , Sigmar Bräuninger , Claudia Querner , Ekkehard Schwab
IPC分类号： H01M4/86 , B01J31/06 , H01M8/10 , H01M4/88 , H01M4/92
CPC分类号： B01J31/06 , H01M4/86 , H01M4/8817 , H01M4/8842 , H01M4/92 , H01M8/10 , Y02E60/50
摘要： A process for preparing a catalyst material comprising an electrically conducting support material, a proton-conducting, polyazole-based polymer and a catalytically active material. A catalyst material prepared by the process of the invention. A catalyst ink comprising a catalyst material of the invention and a solvent. A catalyst-coated membrane (CCM) comprising a polymer electrolyte membrane and also catalytically active layers comprising a catalyst material of the present invention. A gas diffusion electrode (GDE) comprising a gas diffusion layer and a catalytically active layer comprising a catalyst material of the invention. A membrane-electrode assembly (MEA) comprising a polymer electrolyte membrane, catalytically active layers comprising a catalyst material of the invention, and gas diffusion layers. And a fuel cell comprising a membrane-electrode assembly of the present invention.
摘要翻译：一种制备催化剂材料的方法，其包括导电载体材料，质子传导性聚合物基聚合物和催化活性材料。通过本发明方法制备的催化剂材料。一种催化剂油墨，其包含本发明的催化剂材料和溶剂。包含聚合物电解质膜的催化剂涂覆膜（CCM）以及包含本发明催化剂材料的催化活性层。包括气体扩散层和包含本发明的催化剂材料的催化活性层的气体扩散电极（GDE）。包含聚合物电解质膜，包含本发明的催化剂材料的催化活性层和气体扩散层的膜 - 电极组件（MEA）。以及包括本发明的膜 - 电极组件的燃料电池。

12. 发明授权

US09095845B2 Catalyst support material comprising polyazole salt, electrochemical catalyst, and the preparation of a gas diffusion electrode and a membrane-electrode assembly therefrom 有权
标题翻译：催化剂载体材料包括聚唑盐，电化学催化剂，以及气体扩散电极及其膜 - 电极组合物的制备
公开(公告)号：US09095845B2
公开(公告)日：2015-08-04
申请号：US13278830
申请日：2011-10-21
申请人： Oemer Uensal , Sigmar Brauninger , Claudia Querner , Ekkehard Schwab
发明人： Oemer Uensal , Sigmar Brauninger , Claudia Querner , Ekkehard Schwab
IPC分类号： H01M4/86 , H01M4/88 , B01J31/22 , B01J31/16 , B01J31/18 , H01M4/92 , H01M8/10
CPC分类号： B01J31/2217 , B01J31/1616 , B01J31/183 , B01J31/2295 , B01J2531/0216 , B01J2531/17 , B01J2531/18 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , H01M4/881 , H01M4/926 , H01M8/1004 , H01M8/103 , Y02E60/521
摘要： A catalyst material comprising an electrically conducting support material, a proton-conducting, acid-doped polymer based on a polyazole salt, and a catalytically active material. A process for preparing the catalyst material. A catalyst material prepared by the process of the invention. A catalyst ink comprising the catalyst material of the invention and a solvent. A catalyst-coated membrane (CCM) comprising a polymer electrolyte membrane and also catalytically active layers comprising a catalyst material of the present invention. A gas diffusion electrode (GDE) comprising a gas diffusion layer and a catalytically active layer comprising a catalyst material of the invention. A membrane-electrode assembly (MEA) comprising a polymer electrolyte membrane, catalytically active layers comprising a catalyst material of the invention, and gas diffusion layers. And a fuel cell comprising a membrane-electrode assembly of the present invention.
摘要翻译：一种催化剂材料，包括导电支撑材料，基于聚唑盐的质子传导性酸掺杂聚合物和催化活性材料。一种制备催化剂材料的方法。通过本发明方法制备的催化剂材料。包含本发明的催化剂材料和溶剂的催化剂油墨。包含聚合物电解质膜的催化剂涂覆膜（CCM）以及包含本发明催化剂材料的催化活性层。包括气体扩散层和包含本发明的催化剂材料的催化活性层的气体扩散电极（GDE）。包含聚合物电解质膜，包含本发明的催化剂材料的催化活性层和气体扩散层的膜 - 电极组件（MEA）。以及包括本发明的膜 - 电极组件的燃料电池。

13. 发明授权

US08916491B2 Process for producing a methanation catalyst and a process for the methanation of synthesis gas 有权
标题翻译：用于生产甲烷化催化剂的方法和合成气的甲烷化方法
公开(公告)号：US08916491B2
公开(公告)日：2014-12-23
申请号：US13670815
申请日：2012-11-07
申请人： Claudia Querner , Andrian Milanov , Stephan Schunk , Andreas Strasser , Guido Wasserschaff , Thomas Roussiere
发明人： Claudia Querner , Andrian Milanov , Stephan Schunk , Andreas Strasser , Guido Wasserschaff , Thomas Roussiere
IPC分类号： B01J21/10 , B01J23/02 , B01J23/78 , B01J37/04 , B01J37/08 , B01J37/14 , B01J23/755 , C10L3/06 , C10L3/08 , C07C1/04 , C07C1/12 , B01J35/00 , B01J35/10 , B01J23/00 , B01J37/00 , B01J37/02 , B01J35/02 , B01J27/236
CPC分类号： B01J21/10 , B01J23/005 , B01J23/02 , B01J23/755 , B01J23/78 , B01J27/236 , B01J35/0006 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J35/1085 , B01J35/109 , B01J37/0009 , B01J37/0036 , B01J37/0201 , B01J37/04 , B01J37/08 , B01J37/14 , C07C1/04 , C07C1/12 , C10L3/06 , C10L3/08
摘要： The present invention relates to a process for producing a catalyst for carrying out methanation reactions. The production of the catalyst is based on contacting of a hydrotalcite-comprising starting material with a fusible metal salt. The compounds brought into contact with one another are intimately mixed, thermally treated so that the metal salt fraction melts and subsequently subjected to a low-temperature calcination step and a high-temperature calcination step. The metal salt melt comprises at least one metal selected from the group consisting of K, La, Fe, Co, Ni, Cu and Ce, preferably Ni. The metal salt melt more preferably comprises/contains nickel nitrate hexahydrate. The hydrotalcite-comprising starting material is preferably hydrotalcite or a hydrotalcite-like compound as starting material, and the hydrotalcite-comprising starting material preferably comprises magnesium and aluminum as metal species.The catalyst of the invention is preferably used for carrying out methanation reactions at elevated pressures (from 10 to 50 bar) and elevated temperatures.
摘要翻译：本发明涉及一种用于进行甲烷化反应的催化剂的制备方法。催化剂的生产基于含水滑石的原料与可熔金属盐的接触。使彼此接触的化合物紧密混合，热处理，使金属盐部分熔融，随后进行低温煅烧步骤和高温煅烧步骤。金属盐熔体包含选自K，La，Fe，Co，Ni，Cu和Ce中的至少一种金属，优选为Ni。金属盐熔体更优选包含/含有硝酸镍六水合物。含水滑石的起始原料优选为水滑石或类水滑石化合物作为起始原料，含水滑石的原料优选包含镁和铝作为金属物质。本发明的催化剂优选用于在升高的压力（10至50巴）和升高的温度下进行甲烷化反应。

14. 发明申请

US20120100455A1 CATALYST SUPPORT MATERIAL COMPRISING POLYAZOLE SALT, ELECTROCHEMICAL CATALYST, AND THE PREPARATION OF A GAS DIFFUSION ELECTRODE AND A MEMBRANE-ELECTRODE ASSEMBLY THEREFROM 有权
标题翻译：催化剂支撑材料包含聚唑盐，电化学催化剂，以及气体扩散电极的制备和膜电极组件
公开(公告)号：US20120100455A1
公开(公告)日：2012-04-26
申请号：US13278830
申请日：2011-10-21
申请人： Oemer UENSAL , Sigmar Bräuninger , Claudia Querner , Ekkehard Schwab
发明人： Oemer UENSAL , Sigmar Bräuninger , Claudia Querner , Ekkehard Schwab
IPC分类号： H01M8/10 , B01J31/06
CPC分类号： B01J31/2217 , B01J31/1616 , B01J31/183 , B01J31/2295 , B01J2531/0216 , B01J2531/17 , B01J2531/18 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , H01M4/881 , H01M4/926 , H01M8/1004 , H01M8/103 , Y02E60/521
摘要： A catalyst material comprising an electrically conducting support material, a proton-conducting, acid-doped polymer based on a polyazole salt, and a catalytically active material. A process for preparing the catalyst material. A catalyst material prepared by the process of the invention. A catalyst ink comprising the catalyst material of the invention and a solvent. A catalyst-coated membrane (CCM) comprising a polymer electrolyte membrane and also catalytically active layers comprising a catalyst material of the present invention. A gas diffusion electrode (GDE) comprising a gas diffusion layer and a catalytically active layer comprising a catalyst material of the invention. A membrane-electrode assembly (MEA) comprising a polymer electrolyte membrane, catalytically active layers comprising a catalyst material of the invention, and gas diffusion layers. And a fuel cell comprising a membrane-electrode assembly of the present invention.
摘要翻译：一种催化剂材料，包括导电支撑材料，基于聚唑盐的质子传导性酸掺杂聚合物和催化活性材料。一种制备催化剂材料的方法。通过本发明方法制备的催化剂材料。包含本发明的催化剂材料和溶剂的催化剂油墨。包含聚合物电解质膜的催化剂涂覆膜（CCM）以及包含本发明催化剂材料的催化活性层。包括气体扩散层和包含本发明的催化剂材料的催化活性层的气体扩散电极（GDE）。包含聚合物电解质膜，包含本发明的催化剂材料的催化活性层和气体扩散层的膜 - 电极组件（MEA）。以及包括本发明的膜 - 电极组件的燃料电池。

15. 发明申请

US20120094199A1 CATALYST FOR ELECTROCHEMICAL APPLICATIONS 审中-公开
标题翻译：电化学应用催化剂
公开(公告)号：US20120094199A1
公开(公告)日：2012-04-19
申请号：US13375805
申请日：2010-05-27
申请人： Ekkehard Schwab , Sigmar Braeuninger , Alexander Panchenko , Claudia Querner , Oemer Uensal , Markus Vogt , Qinggang He , Nagappan Ramaswamy , Sanjeev Mukerjee
发明人： Ekkehard Schwab , Sigmar Braeuninger , Alexander Panchenko , Claudia Querner , Oemer Uensal , Markus Vogt , Qinggang He , Nagappan Ramaswamy , Sanjeev Mukerjee
IPC分类号： H01M4/90 , B01J23/89 , H01M8/08 , B01J23/648 , B01J23/656 , B01J21/18 , B01J23/42 , B01J23/652
CPC分类号： B01J21/18 , B01J23/89 , B01J23/8913 , B01J23/892 , B01J23/898 , B01J23/8986 , B01J23/8993 , B01J35/023 , B01J37/0205 , H01M4/921 , H01M4/926 , H01M8/086
摘要： The invention relates to a catalyst for electro-chemical applications comprising an alloy of platinum and a transition metal, wherein the transition metal has an absorption edge similar to the absorption edge of the transition metal in oxidic state, measured with x-ray absorption near-edge spectroscopy (XANES) wherein the measurements are performed in concentrated H3PO4 electrolyte. The invention further relates to a process for an oxygen reduction reaction using the catalyst as electrocatalyst.
摘要翻译：本发明涉及一种用于电化学应用的催化剂，其包括铂和过渡金属的合金，其中过渡金属具有与氧化态的过渡金属的吸收边缘相似的吸收边缘，边缘光谱（XANES），其中测量在浓H 3 PO 4电解质中进行。本发明还涉及使用该催化剂作为电催化剂的氧还原反应方法。

16. 发明申请

US20110195347A1 PROCESS FOR PRODUCING A CATALYST AND CATALYST 审中-公开
标题翻译：生产催化剂和催化剂的方法
公开(公告)号：US20110195347A1
公开(公告)日：2011-08-11
申请号：US13021242
申请日：2011-02-04
申请人： Claudia Querner , Ekkehard Schwab , Bastian Ewald
发明人： Claudia Querner , Ekkehard Schwab , Bastian Ewald
IPC分类号： H01M4/96 , B01J27/22
CPC分类号： H01M4/8846 , H01M4/8657 , H01M4/8885 , H01M4/92 , H01M4/921 , H01M4/926
摘要： The invention relates to a process for producing a catalyst, where the catalyst comprises a catalytically active material and a carbon-comprising support, in which the carbon-comprising support is impregnated with a metal salt solution in a first step, the carbon-comprising support impregnated with the metal salt solution is subsequently heated to a temperature of at least 1500° C. in an inert atmosphere to form a metal carbide layer and the catalytically active material is finally applied to the carbon-comprising support provided with the metal carbide layer. The invention further provides a catalyst which has been produced by the process and comprises a carbon-comprising support and a catalytically active material, with the carbon-comprising support having a metal carbide layer and the catalytically active material having been applied to the carbon-comprising support provided with the metal carbide layer.
摘要翻译：本发明涉及一种生产催化剂的方法，其中催化剂包含催化活性材料和含碳载体，其中在第一步骤中用金属盐溶液浸渍含碳载体，含碳载体随后将金属盐溶液浸渍的金属盐溶液在惰性气氛中加热到至少1500℃的温度以形成金属碳化物层，并且最终将催化活性材料施加到设置有金属碳化物层的含碳载体上。本发明还提供了一种已经通过该方法生产并包含含碳载体和催化活性材料的催化剂，其中含碳载体具有金属碳化物层，催化活性材料已被应用于含碳的载体支撑体设有金属碳化物层。

17. 发明授权

US07309525B2 Inorganic nanocrystals with organic coating layer, their method of manufacture and materials constituted by said nanocrystals 有权
标题翻译：具有有机涂层的无机纳米晶体，其制造方法和由所述纳米晶体构成的材料
公开(公告)号：US07309525B2
公开(公告)日：2007-12-18
申请号：US11000525
申请日：2004-12-01
申请人： Peter Reiss , Claudia Querner , Nicolas Charvet
发明人： Peter Reiss , Claudia Querner , Nicolas Charvet
IPC分类号： B32B5/16
CPC分类号： C30B29/605 , C09K11/02 , C09K11/883 , C30B7/00 , Y10S977/813 , Y10S977/83 , Y10T428/2991
摘要： Nanocrystal comprising an inorganic core consisting of least one metal and/or at least one semi-conductor compound comprising at least one metal, the external surface of said nanocrystal being provided with an organic coating layer, consisting of at least one ligand compound of formula (I): X—Y-Z (I) in which X represents a 1,1-dithiolate or 1,1-diselenoate group that is linked by the two atoms of sulphur or selenium to an atom of metal of the external surface of said nanocrystal; Y represents a spacer group, such as a group capable of allowing a transfer of charge or an insulating group; Z is a group chosen from among groups capable of communicating specific properties to the nanocrystal. Their methods of manufacture.
摘要翻译：纳米晶体包括由至少一种金属和/或至少一种包含至少一种金属的半导体化合物组成的无机核，所述纳米晶体的外表面具有有机涂层，该有机涂层由至少一种式（ I）：<？in-line-formula description =“In-line Formulas”end =“lead”？> XYZ（I）<？in-line-formula description =“In-line Formulas”end =“tail”？ >其中X表示通过硫或硒的两个原子与所述纳米晶体的外表面的金属原子连接的1,1-二硫醇盐或1,1-硒酸酯基团; Y表示间隔基，例如可以允许电荷转移或绝缘基的基团; Z是从能够与纳米晶体传播特定性质的组中选择的基团。他们的制造方法。

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