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    • 13. 发明授权
    • Antistatically conductive masking film for electrostatic spray painting
    • 用于静电喷漆的防静电导电掩膜
    • US5096761A
    • 1992-03-17
    • US560464
    • 1990-07-25
    • William P. RobertsCharles R. MorganMarvin R. Havens
    • William P. RobertsCharles R. MorganMarvin R. Havens
    • B05B15/04B05D1/32C09D5/24C09D123/02C09D123/08H01B1/12H01B1/22H01B1/24
    • B05D1/32B05B15/045C09D123/02C09D123/08C09D5/24H01B1/12H01B1/22H01B1/24Y10S428/922Y10T428/24802Y10T428/24851Y10T428/24893Y10T428/28
    • A masking film suitable for masking during electrostatic spray painting is disclosed. In one embodiment the masking film is made from an acid copolymer/quaternary amine mixture which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.8 alkyl phosphate, sulfate, C.sub.1 to C.sub.8 alkyl sulfate, formate, C.sub.1 to C.sub.8 alkyl or C.sub.6 to C.sub.24 alkaryl or aryl sulfonate, acetate, citrate, trifluoroacetate, propionate, tartrate or carbonate. In a second embodiment, the masking film is made from a polyolefin containing a particulate conductive filler.
    • 公开了一种适用于静电喷涂期间掩蔽的掩模膜。 在一个实施方案中,掩模膜由永久抗静电的酸共聚物/季胺混合物制成。 酸共聚物是(i)主要含摩尔%的式RCH = CH 2的α-烯烃,其中R是H或C 1至C 8烷基的共聚物,和(ii)少量的摩尔%的α ,β-烯属不饱和羧酸。 季胺具有式[(R 1)(R 2)(R 3)(R 4)N] + [X] - 其中R 1选自H,芳基或任选具有一个或多个不连续C = O或NHC = O或-S-或-O-,或与R2相同; R 2,R 3和R 4各自相同或不同,并且选自H,任选被一个或多个OH取代的C 1至C 18烷基或 - (R 5 -O)a -H,其中a是1至10的整数, R5是乙烯或丙烯; X为阴离子,选自氯化物,溴化物,碘化物,硝酸盐,氟硼酸盐,磷酸盐,C1至C8烷基磷酸盐,硫酸盐,C1至C8烷基硫酸盐,甲酸盐,C1至C8烷基或C6至C24烷芳基或芳基磺酸盐, 柠檬酸盐,三氟乙酸盐,丙酸盐,酒石酸盐或碳酸盐。 在第二实施例中,掩模膜由含有颗粒状导电填料的聚烯烃制成。
    • 16. 发明授权
    • UV and thermally curable, thermoplastic-containing compositions
    • UV和可热固化,含热塑性的组合物
    • US4605465A
    • 1986-08-12
    • US657607
    • 1984-10-04
    • Charles R. Morgan
    • Charles R. Morgan
    • C08F2/46C08F283/10C09D4/06C09J4/06B32B31/00
    • C09D4/06B32B37/12C08F2/46C08F283/10C09J4/06B32B2305/72B32B2310/0831
    • A UV and thermally curable composition comprising(1) a liquid, ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is at least 2,(2) a thermal initiator for (1) selected from the group consisting of substituted or unsubstituted pinacols, azo compounds, thiurams, organic peroxides and mixtures thereof,(3) a photoinitiator for (1) selected from the group consisting of aldehyde and ketone carbonyl compounds having at least one aromatic nucleus attached directly to the ##STR2## group, benzoin alkyl ethers, diethoxyacetophenone and 2,2-dimethoxy-2-phenylacetophenone,(4) a thermoplastic material, and(5) a non-polymerizable plasticizer for (4).The exposure of the composition to UV radiation under atmospheric conditions and heat in seriatim results in a cured solid product which can be utilized as adhesives, coatings, gaskets, sealants, resists and the like.
    • 一种UV和热可固化组合物,其包含(1)下式的液体,烯属不饱和单体,低聚物或预聚物:其中R是H或CH 3,R 1是有机部分,n是至少2,(2)a (1)选自由取代或未取代的频哪醇,偶氮化合物,秋兰姆,有机过氧化物及其混合物组成的组的热引发剂,(3)用于(1)选自醛和酮羰基化合物的光引发剂,其具有 至少一个芳香核直接连接到基团,苯偶姻烷基醚,二乙氧基苯乙酮和2,2-二甲氧基-2-苯基苯乙酮,(4)热塑性材料,和(5)用于(4)的不可聚合增塑剂。 在大气条件下,组合物暴露于紫外线辐射下,产生固化的固体产物,其可用作粘合剂,涂料,垫片,密封剂,抗蚀剂等。
    • 17. 发明授权
    • Process for coating of substrates with heat curable coating
    • 用可热固化涂层涂布基材的方法
    • US4560579A
    • 1985-12-24
    • US693544
    • 1985-01-22
    • Bahram SiadatCharles R. Morgan
    • Bahram SiadatCharles R. Morgan
    • C08F299/02C09J4/06C09J7/00B05D3/02
    • C09J7/00C08F299/024C09J4/06
    • A heat activatable adhesive or sealant organic resin composition comprising(1) an epoxy resin containing at least two ##STR1## (2) a thermal initiator selected from the group consisting of diaryliodonium salts and diaryliodonium salts combined with a pinacol, and(3) a thermoplastic adhesive material selected from the group consisting of polyesters, polyvinyl acetals, polyamides, butadiene-acrylonitrile copolymers, styrene-butadiene copolymers, styrene-isoprene copolymers, styrene-ethylene-butylene copolymers, ethylene-vinyl acetate copolymers, ethylene-ethyl acrylate copolymers, ethylene propylene diene monomer and mixtures thereof.The composition after application to the parts to be bonded or sealed forms a thermoset bond or seal on application of heat thereto, preferably by electromagnetic techniques including dielectric and induction heating.
    • 一种可热活化的粘合剂或密封剂有机树脂组合物,其包含(1)含有至少两种(2)热引发剂的环氧树脂,所述热引发剂选自二芳基碘鎓盐和二芳基碘盐与频哪醇的组合,和(3) 选自聚酯,聚乙烯醇缩醛,聚酰胺,丁二烯 - 丙烯腈共聚物,苯乙烯 - 丁二烯共聚物,苯乙烯 - 异戊二烯共聚物,苯乙烯 - 乙烯 - 丁烯共聚物,乙烯 - 乙酸乙烯酯共聚物,乙烯 - 丙烯酸乙酯共聚物, 乙烯丙烯二烯单体及其混合物。 施加到待粘合或密封的部件上的组合物优选通过包括电介质和感应加热的电磁技术在加热时形成热固性粘合或密封。
    • 18. 发明授权
    • Heat curable conductive ink
    • 热固性导电油墨
    • US4443495A
    • 1984-04-17
    • US491899
    • 1983-05-05
    • Charles R. MorganArthur D. Ketley
    • Charles R. MorganArthur D. Ketley
    • B41M7/00C08G75/02C08L81/02C09D11/00C09D11/10H05K1/09B05D3/06H01B1/02
    • C09D11/52B41M7/009C08G75/02C08L81/02C09D11/106H05K1/095
    • This invention relates to a heat curing process and to a solventless screen printable, heat curable conductive ink composition comprising(1) an ethylenically unsaturated member of the group consisting of(a) a liquid, ethylenically, unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is at least 2,(b) a polythiol in combination with (a) supra,(c) a polythiol in combination with a liquid ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR2## wherein R.sub.2 is H or CH.sub.3, R.sub.3 is an organic moiety and n is at least 2, and(d) mixtures of (a), (b) and (c),(2) a thermal initiator, and(3) an electrically conductive material.Heating of the composition in a desired pattern on a substrate results in a printed electric circuit.
    • 本发明涉及一种热固化方法和一种无溶剂丝网印刷的可热固化的导电油墨组合物,其包含(1)由(a)液体,烯键式,不饱和单体,低聚物或预聚物组成的组中的烯属不饱和组分 其中R为H或CH 3,R 1为有机部分,n为至少2,(b)多硫醇与上述(a)组合,(c)多硫醇与液体烯属不饱和单体的组合, 低聚物或下式的预聚物:其中R2是H或CH3,R3是有机部分,n是至少2,和(d)(a),(b)和(c)的混合物,(2) 热引发剂,和(3)导电材料。 在基板上以期望的图案加热组合物导致印刷电路。
    • 19. 发明授权
    • Heat curable conductive ink
    • 热固性导电油墨
    • US4406826A
    • 1983-09-27
    • US241144
    • 1981-03-05
    • Charles R. MorganArthur D. Ketley
    • Charles R. MorganArthur D. Ketley
    • B41M7/00C08G75/04C09D11/00C09D11/10H01B1/20H05K1/09H05K3/00H01B1/02B05D3/06
    • C09D11/52B41M7/009C08G75/045C09D11/106H05K1/095
    • This invention relates to a heat curing process and to a solventless screen printable, heat curable conductive ink composition comprising(1) an ethylenically unsaturated member of the group consisting of(a) a liquid, ethylenically, unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is at least 2,(b) a polythiol in combination with (a) supra,(c) a polythiol in combination with a liquid ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR2## wherein R.sub.2 is H or CH.sub.3, R.sub.3 is an organic moiety and n is at least 2, and(d) mixtures of (a), (b) and (c),(2) a thermal initiator, and(3) an electrically conductive material.Heating of the composition in a desired pattern on a substrate results in a printed electric circuit.
    • 本发明涉及一种热固化方法和一种无溶剂丝网印刷的可热固化的导电油墨组合物,其包含(1)由(a)液体,烯键式,不饱和单体,低聚物或预聚物组成的组中的烯属不饱和组分 其中R为H或CH 3,R 1为有机部分,n为至少2,(b)多硫醇与上述(a)组合,(c)多硫醇与液体烯属不饱和单体的组合, 低聚物或下式的预聚物:其中R2是H或CH3,R3是有机部分,n是至少2,和(d)(a),(b)和(c)的混合物,(2) 热引发剂,和(3)导电材料。 在基板上以期望的图案加热组合物导致印刷电路。