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131. 发明授权

US4519956A Process for selectively preparing acetic anhydride by carbonylation of methyl acetate in the presence of an iodide-free catalyst system 失效
标题翻译：在不含碘化物的催化剂体系存在下通过羰基化乙酸甲酯选择性制备乙酸酐的方法
公开(公告)号：US4519956A
公开(公告)日：1985-05-28
申请号：US515748
申请日：1983-07-21
申请人： Jiang-Jen Lin , Roger G. Duranleau
发明人： Jiang-Jen Lin , Roger G. Duranleau
IPC分类号： C07C51/56 , C07C51/12
CPC分类号： C07C51/56
摘要： A process for producing acetic anhydride is disclosed which comprises reacting methyl acetate with carbon monoxide at an elevated temperature and pressure in the presence of an iodine-free catalyst system wherein the catalyst consists of ruthenium compound, quaternary phosphonium salt and cobalt-compound. A further embodiment comprises recycling product acetic anhydride with methanol to produce acetic acid.
摘要翻译：公开了一种生产乙酸酐的方法，其包括在无碘催化剂体系的存在下，在升高的温度和压力下使乙酸甲酯与一氧化碳反应，其中催化剂由钌化合物，季鏻盐和钴化合物组成。另一个实施方案包括将乙酸酐与甲醇一起再生产生乙酸。

132. 发明授权

US4434241A Catalyst recovery process from tar from carbonylation reactions 失效
标题翻译：来自羰基化反应的焦油的催化剂回收过程
公开(公告)号：US4434241A
公开(公告)日：1984-02-28
申请号：US424727
申请日：1982-09-27
申请人： Thomas H. Larkins, Jr.
发明人： Thomas H. Larkins, Jr.
IPC分类号： B01J31/40 , C01B7/13 , C07C51/573 , C22B3/16 , C22B7/00 , C22B26/12 , B01J23/96 , B01J27/32 , C07C51/12
CPC分类号： B01J31/26 , B01J31/20 , B01J31/4046 , B01J31/4092 , C01B7/13 , C07C51/573 , C22B11/04 , C22B26/12 , C22B3/165 , C22B7/007 , B01J2231/34 , B01J23/464 , B01J2531/822 , Y02P10/234 , Y02P20/584
摘要： The present invention provides a process for the recovery of rhodium, lithium, and iodine values from tar which is generated during carbonylation reactions. The process comprises sequentially extracting the tar with water and then leaching the remaining tar with acetic acid, burning the resulting residue, and recycling the resulting rhodium-enriched residue to the reaction process. Preferably, the process further comprises the recovery of iodine values by the incineration of the acetic acid leachate and treatment of the off-gas with aqueous alkali hydroxide. Lithium values are recovered by evaporating water from the aqueous phase of the water extraction step and recycling the resulting residue to the reaction process.
摘要翻译：本发明提供从羰基化反应中产生的焦油回收铑，锂和碘值的方法。该方法包括用水顺序提取焦油，然后用乙酸浸出剩余的焦油，燃烧所得残余物，并将所得的富含铑的残余物再循环到反应过程中。优选地，该方法还包括通过焚烧乙酸浸出液回收碘值，并用碱性氢氧化碱水溶液处理废气。通过从水提取步骤的水相中蒸发水来回收锂值，并将所得残余物再循环到反应过程中。

133. 发明授权

US4430506A Hydrocarbonylation/carbonylation of alkyl carboxylates 失效
标题翻译：羧酸烷基酯的羰基化羰基化
公开(公告)号：US4430506A
公开(公告)日：1984-02-07
申请号：US280219
申请日：1981-07-06
申请人： Jean Gauthier-Lafaye , Robert Perron
发明人： Jean Gauthier-Lafaye , Robert Perron
IPC分类号： C07C69/14 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/147 , C07C29/32 , C07C29/36 , C07C45/00 , C07C45/49 , C07C47/06 , C07C51/12 , C07C67/00 , C07C67/36
CPC分类号： C07C45/49 , C07C29/32 , C07C29/36 , C07C51/12 , C07C67/36
摘要： Alkyl carboxylates are hydrocarbonylated and/or carbonylated with carbon monoxide and hydrogen, in an aqueous medium, and in the presence of a catalytically effective amount of a catalyst system comprising (i) ruthenium, (ii) cobalt, (iii) at least one iodine-containing promoter, and (iv) vanadium. The subject hydrocarbonylation/carbonylation is admirably well suited, e.g., for the preparation of acetaldehyde, ethanol, ethyl acetate and acetic acid, especially from a methyl carboxylate.
摘要翻译：在水性介质中，在催化有效量的催化剂体系存在下，羧酸烷基酯在一氧化碳和氢气下进行烃基化和/或羰基化，包括（ⅰ）钌，（ⅱ）钴，（ⅲ）至少一种碘（iv）钒。本发明的烃基化/羰基化是非常适合的，例如用于制备乙醛，乙醇，乙酸乙酯和乙酸，特别是甲酸甲酯。

134. 发明授权

US4374070A Preparation of acetic anhydride 失效
标题翻译：乙酸酐的制备
公开(公告)号：US4374070A
公开(公告)日：1983-02-15
申请号：US209350
申请日：1980-11-21
申请人： Thomas H. Larkins , Stanley W. Polichnowski , Gerald C. Tustin , David A. Young
发明人： Thomas H. Larkins , Stanley W. Polichnowski , Gerald C. Tustin , David A. Young
IPC分类号： C07C53/12 , B01J23/46 , B01J27/08 , B01J27/13 , B01J31/02 , C07B61/00 , C07C51/12 , C07C51/56 , C07C51/54
CPC分类号： C07C51/56
摘要： The preparation of acetic anhydride by the carbonylation of methyl acetate in the presence of rhodium, an iodine compound and lithium at elevated temperatures and pressures is improved by the inclusion of about 2 to 7 volume percent hydrogen in the gas fed to the carbonylation reactor. The presence of hydrogen suppresses tar formation and increases reaction rate.
摘要翻译：通过在提供给羰基化反应器的气体中加入约2至7体积％的氢气，在铑，碘化合物和锂的存在下，通过羰基化乙酸甲酯来制备乙酸酐。氢的存在抑制焦油形成并增加反应速率。

135. 发明授权

US4372889A Preparation of carboxylic acids 失效
标题翻译：羧酸的制备
公开(公告)号：US4372889A
公开(公告)日：1983-02-08
申请号：US267963
申请日：1981-05-28
申请人： Nabil Rizkalla
发明人： Nabil Rizkalla
IPC分类号： C07C53/122 , B01J23/85 , B01J31/24 , B01J31/26 , B01J31/34 , C07B61/00 , C07C51/00 , C07C51/12 , C07C51/14 , C07C67/00
CPC分类号： C07C51/14 , B01J23/85 , B01J31/0231 , B01J31/1805 , B01J31/181 , B01J31/20 , B01J31/24 , B01J31/2404 , C07C51/12 , B01J2231/321 , B01J2531/64 , B01J2531/66 , B01J2531/847 , B01J31/30
摘要： A carboxylic acid, such as propionic acid, is prepared by carbonylation of an olefin, such as ethylene in the presence of water by the use of a molybdenum-nickel or tungsten-nickel cocatalyst in the presence of a promoter comprising an organophosphorus compound or an organo-nitrogen compound wherein the phosphorus and nitrogen are trivalent and in the presence of a halide.
摘要翻译：通过使用钼 - 镍或钨 - 镍助催化剂在包含有机磷化合物的助催化剂存在下，在水的存在下羰基化烯烃如乙烯来制备羧酸，例如丙酸，有机氮化合物，其中磷和氮是三价的，并且在卤化物的存在下。

136. 发明授权

US4351953A Preparation of carboxylic acids by carbonylation of alcohols 失效
标题翻译：通过羰基化醇制备羧酸
公开(公告)号：US4351953A
公开(公告)日：1982-09-28
申请号：US247744
申请日：1981-03-26
申请人： Jean Gauthier-Lafaye , Robert Perron
发明人： Jean Gauthier-Lafaye , Robert Perron
IPC分类号： B01J27/00 , B01J31/00 , C07C51/00 , C07C51/12 , C07C53/00 , C07C53/08 , C07C67/00 , C07C53/134 , C07C57/30
CPC分类号： C07C51/12
摘要： Carboxylic acids having the structural formula R.sup.1 COOH, wherein R.sup.1 is a linear, branched or cyclic chain alkyl radical of from 1 to 6 carbon atoms or a .PHI.--C.sub.n H.sub.2n -- radical wherein .PHI. is phenyl and 1.ltoreq.n.ltoreq.6, are prepared by carbonylating an alcohol having the formula R.sup.1 --OH with carbon monoxide in liquid phase, in the presence of a catalytically effective amount of nickel and an alkyl or acyl halide promoter therefor, at a temperature of at least about 120.degree. C. and under a total pressure of less than 200 bars, and said carbonylation being carried out in the presence of at least one chromium salt in which the chromium is in a state of oxidation (p) of greater than zero (p>0), and in an initial carboxylic acid reaction medium having the formula R.sup.2 --COOH, wherein R.sup.2 is defined as was R.sup.1 above, and further wherein R.sup.1 and R.sup.2 may be the same or different.
摘要翻译：具有结构式为R 1 COOH的羧酸，其中R 1是具有1至6个碳原子的直链，支链或环状链烷基或PHI-C n H 2n - ，其中PHI是苯基且1≤n≤6是在催化有效量的镍和其烷基或酰卤促进剂的存在下，在至少约120℃的温度和下面的温度下，通过羰基化具有式R1-OH的醇与一氧化碳在液相中羰基化来制备总压力小于200巴，所述羰基化在至少一种铬（其中铬处于大于零（p> 0）的状态下）的铬盐的存在下进行，并且在具有式R2-COOH的初始羧酸反应介质，其中R2定义为R1以上，并且其中R1和R2可以相同或不同。

137. 发明授权

US4341741A Recovery of rhodium from carbonylation residues 失效
标题翻译：从羰基化残基中回收铑
公开(公告)号：US4341741A
公开(公告)日：1982-07-27
申请号：US241193
申请日：1981-03-06
申请人： Walter C. Davidson , Benjamin F. Fieselmann
发明人： Walter C. Davidson , Benjamin F. Fieselmann
IPC分类号： C22B11/00 , B01J23/00 , B01J31/40 , C01G55/00 , C07C51/00 , C07C51/12 , C07C51/42 , C07C51/56 , C07C53/12 , C07C67/00 , C22B3/28
CPC分类号： B01J31/04 , B01J31/20 , B01J31/2234 , B01J31/2404 , B01J31/4038 , B01J31/4046 , C01G55/001 , C01G55/005 , C07C51/12 , C07C51/56 , C22B3/0012 , B01J2231/34 , B01J23/40 , B01J2531/82 , B01J2531/822 , B01J27/08 , B01J31/0237 , B01J31/26 , Y02P10/234 , Y02P20/584
摘要： Residues are formed in the carbonylation of esters or ethers, particularly in the production of acetic anhydride or ethylidene diacetate. Such residues contain noble metal, typically rhodium, used as a catalyst, which must be recovered before the residues can be disposed of. The rhodium values are freed from the residues by treatment with amines, preferably primary aliphatic amines and/or hydrazine, thereby enabling the rhodium to be extracted by subsequent contact with an aqueous halogen acid.
摘要翻译：残留物在酯或醚的羰基化中形成，特别是在制备乙酸酐或亚乙基二乙酸酯时。这种残留物含有用作催化剂的贵金属（通常为铑），必须在残留物被处理之前回收。铑值通过用胺，优选伯脂肪族胺和/或肼处理而从残余物中除去，从而使得铑能够随后与含卤酸的接触而被萃取。

138. 发明授权

US4334094A Method of preparing aliphatic carboxylic acids 失效
标题翻译：脂肪族羧酸的制备方法
公开(公告)号：US4334094A
公开(公告)日：1982-06-08
申请号：US164633
申请日：1980-06-30
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07C51/353 , C07C51/12 , C07C120/00 , C07C121/407 , C07C148/00 , C07C149/20
CPC分类号： C07C51/353
摘要： This invention pertains to the production of higher homologues of aliphatic carboxylic acids by reaction of said acids with carbon monoxide and hydrogen in the presence of one or more palladium-containing catalysts in combination with a Group VB tertiary donor ligand and in the presence of an iodide or bromide promoter.
摘要翻译：本发明涉及通过所述酸与一氧化碳和氢在一种或多种含钯催化剂与VB组合供体配体组合的存在下，在碘化物存在下反应生产高级脂族羧酸的同系物或溴促进剂。

139. 发明授权

US4334093A Method of preparing aliphatic carboxylic acids 失效
标题翻译：脂肪族羧酸的制备方法
公开(公告)号：US4334093A
公开(公告)日：1982-06-08
申请号：US164629
申请日：1980-06-30
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07C53/00 , B01J31/00 , C07C51/00 , C07C51/353 , C07C67/00 , C07C51/12
CPC分类号： C07C51/353
摘要： This invention pertains to the production of higher homologues of aliphatic carboxylic acids by reaction of said acids with carbon monoxide and hydrogen in the presence of one or more nickel-containing catalysts in combination with a Group VB tertiary donor ligand and in the presence of an iodide or bromide promoter.
摘要翻译：本发明涉及通过所述酸与一氧化碳和氢在一种或多种含镍催化剂与VB组合供体配体组合的存在下，在碘化物存在下，通过使所述酸与一氧化碳和氢反应来生产高级同系物的脂肪族羧酸或溴促进剂。

140. 发明授权

US4325834A Heterogeneous catalyst supports 失效
标题翻译：非均相催化剂载体
公开(公告)号：US4325834A
公开(公告)日：1982-04-20
申请号：US208902
申请日：1980-11-21
申请人： Charles M. Bartish , Larry J. Hayes
发明人： Charles M. Bartish , Larry J. Hayes
IPC分类号： B01J21/18 , B01J31/24 , C07C45/50 , C07C51/12 , B01J31/02 , B01J31/12
CPC分类号： B01J31/2404 , B01J21/18 , B01J31/1625 , B01J31/24 , B01J31/2409 , C07C45/50 , C07C51/12 , B01J2231/321 , B01J2231/34 , B01J2531/60 , B01J2531/80 , B01J2531/822 , Y02P20/588
摘要： Processes are taught for the substitution of at least partially amorphous carbon with mono- and bi-dentate phosphine ligands. The ligand-substituted carbon, on combination with complexed Group VI or VIII metals, such as Wilkinson's rhodium catalyst, provide stable heterogeneous catalysts useful in reactions of the Oxo type such as hydroformylation, carbonylation and in hydrogenation.
摘要翻译：教导了用单齿和双齿膦配体取代至少部分无定形碳的方法。配体取代的碳与络合的第VI或VIII族金属如Wilkinson的铑催化剂组合提供了稳定的非均相催化剂，可用于羰基化，羰基化和氢化等氧代反应。

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