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    • 135. 发明授权
    • Highly permeable composite reverse osmosis membrane and method of producing the same
    • 高透性复合反渗透膜及其制备方法
    • US06837381B2
    • 2005-01-04
    • US10002549
    • 2001-11-02
    • Masahiko Hirose
    • Masahiko Hirose
    • B01D69/12B01D71/38B01D71/56B01D71/60
    • B01D71/38B01D69/125B01D71/56B01D71/60
    • The present invention provides a composite reverse osmosis membrane as a polyamide membrane including a side chain amino group such as a residue of a polyvinyl alcohol-based amine compound represented by Formula 1. Such a membrane can remove organic impurities under a low pressure, providing an economical method for removal of impurities. An aqueous solution including a polyvinyl alcohol-based amine compound having a side chain amino group represented by Formula 1 is applied on a polysulfone-based ultrafiltration membrane as a microporous support. Next, trimesic acid chloride solution is applied causing interfacial polycondensation, which generates a reverse osmosis membrane. When this composite reverse osmosis membrane is evaluated by using a pH 6.5 aqueous solution including 500 mg/l of sodium chloride at an operation pressure of 5 kg/cm2 and at a temperature of 25° C., the permeable flux is at least 1.5 m3/m2·d, and the salt rejection is 80% or less. wherein 0
    • 本发明提供作为聚酰胺膜的复合反渗透膜,其包含侧链氨基,例如由式1表示的聚乙烯醇类胺化合物的残基。这种膜可以在低压下除去有机杂质,提供 经济的去除杂质的方法。 将作为微孔载体的聚砜系超滤膜涂布在具有由式1表示的侧链氨基的聚乙烯醇系胺化合物的水溶液中。 接下来,施加均苯三酰氯溶液引起界面缩聚,产生反渗透膜。 当通过在5kg / cm 2的操作压力和25℃的温度下使用包含500mg / l氯化钠的pH 6.5水溶液评价该复合反渗透膜时,渗透通量为 至少1.5m 3 / m 2 .d,并且盐排斥率为80%以下。在0
    • 140. 发明授权
    • Cationic charge modified microporous membranes
    • 阳离子电荷改性微孔膜
    • US5269931A
    • 1993-12-14
    • US747668
    • 1991-08-20
    • Ho-Pin HuInessa KatsnelsonAlan SellingerWesley Tamashiro
    • Ho-Pin HuInessa KatsnelsonAlan SellingerWesley Tamashiro
    • B01D71/38B01D67/00B01D71/52B01D71/68C07K1/26C08L71/03C08L71/08C08L71/10C12N15/09C12Q1/04C12Q1/68G01N27/447G01N33/543G01N33/545
    • B01D67/0093B01D71/68G01N27/44717G01N33/54386G01N33/545B01D2323/38
    • Cationic charged semihydrophobic polyethersulfone (CSfIP) membranes having hydrophilic and semihydrophobic properties are provided, as well as preparation of the same by post-treatment. Typically, as an illustration, a microporous hydrophilic polyethersulfone membrane substrate which contains non-leachable polymeric additive having functional groups is treated in an alkaline solution for simultaneous or sequential reaction with 1) a primary charge modifying agent which is an epichlorohydrin modified polyamine, and 2) a secondary polymeric charge modifying agent containing a positive charge (or for reaction with the primary charge modifying agent alone); then baked until cured at elevated temperature; and finally washed and dried. The CSHP membranes are used in various applications such as the filtration of fluids and the macromolecular transfer of biomolecules either from electrophoresis gels or directly to immobilization on the membrane for hybridization and stripping. The CSHP membranes--unlike conventional charged membranes which typically show a decrease in sensitivity and reprobing performance--retain their sensitivity and reprobing performance and excel in this regard throughout multiple reprobing cycles.
    • 提供具有亲水和半疏水性质的阳离子带电半疏水聚醚砜(CSfIP)膜,以及通过后处理制备。 通常,作为说明,含有具有官能团的不可浸出的聚合物添加剂的微孔亲水性聚醚砜膜底物在碱性溶液中进行处理,以与1)作为表氯醇改性多胺的主要电荷改性剂和2 )含有正电荷的次级聚合物电荷改性剂(或仅与单电荷改性剂反应); 然后烘烤直至在升高的温度下固化; 最后洗净干燥。 CSHP膜用于各种应用,例如流体的过滤和生物分子的大分子转移,从电泳凝胶或直接固定在膜上用于杂交和剥离。 CSHP膜与常规带电膜(通常显示灵敏度降低和再现性能)不同,保持了它们的灵敏度和再现性能,并且在多重重复循环中在这方面表现优异。