专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

131. 发明授权

US08071689B2 Methods of making siloxy-amine functionalized rubbery polymers and uses thereof in rubber compositions for tires 有权
标题翻译：制备甲硅烷氧基胺官能化橡胶状聚合物的方法及其在轮胎用橡胶组合物中的用途
公开(公告)号：US08071689B2
公开(公告)日：2011-12-06
申请号：US12207736
申请日：2008-09-10
申请人： Adel Farhan Halasa , Nicola Constantini , Frank Schmitz
发明人： Adel Farhan Halasa , Nicola Constantini , Frank Schmitz
IPC分类号： C08C19/22
CPC分类号： C08C19/44 , C08K3/013 , C08K5/544 , C08L9/06 , C08L15/00 , C08L19/006 , C08L21/00 , C08L2666/08
摘要： The invention includes a siloxy-amine functionalized rubbery polymer, which exhibits good reinforcing characteristics and filler dispersing effect, a method for making, and a rubber composition including the same. In one embodiment, a process for manufacturing includes polymerizing a conjugated diene monomer using an organolithium compound as an initiator in a hydrocarbon solvent. Next, an active terminal end of the polymer is reacted with a functionalized terminating agent represented by: RN—(CH2)XSi(OR1)3, Formula (I) wherein R, in combination with the nitrogen (N) atom, is a substituted or unsubstituted heterocyclic aromatic or non-aromatic compound which includes a ring structure with one or more nitrogen atoms as part of the ring; R1 represents a group having 1 to 18 carbon atoms selected from an alkyl, a cycloalkyl, an allyl, or an aryl; and X is an integer from 1 to 20.
摘要翻译：本发明包括表现出良好的增强特性和填料分散效果的甲硅烷氧基胺官能化橡胶状聚合物，其制备方法和包含该方法的橡胶组合物。在一个实施方案中，制备方法包括在烃溶剂中使用有机锂化合物作为引发剂使共轭二烯单体聚合。接下来，聚合物的活性末端与由以下物质表示的官能化终止剂反应：RN-（CH2）XSi（OR1）3，式（I）其中R与氮（N）原子结合是取代的或未取代的杂环芳族或非芳族化合物，其包括具有一个或多个氮原子作为环的一部分的环结构; R1表示选自烷基，环烷基，烯丙基或芳基的碳原子数1〜18的基团。 X为1〜20的整数。

132. 发明授权

US06765063B2 Pneumatic tire having an innerliner of a rubber composition which contains a low molecular weight trans 1,4-polybutadiene rubber 失效
公开(公告)号：US06765063B2
公开(公告)日：2004-07-20
申请号：US10207563
申请日：2002-07-29
申请人： Paul Harry Sandstrom , Wen-Liane Hsu , Roger Neil Beers , Adel Farhan Halasa
发明人： Paul Harry Sandstrom , Wen-Liane Hsu , Roger Neil Beers , Adel Farhan Halasa
IPC分类号： C08L2700
CPC分类号： B60C1/0008 , C08L9/00 , C08L21/00 , C08L23/22 , Y10T152/10495 , C08L2666/08
摘要： The present invention relates to a pneumatic rubber tire having an integral innerliner of a rubber composition comprised of butyl rubber and/or halogenated butyl rubber and low molecular weight trans 1,4-polybutadiene rubber, wherein said rubber composition may also contain a minor amount of at least one additional, sulfur curable, elastomer.

133. 发明授权

US06576728B1 Process for preparing styrene-isoprene rubber 失效
标题翻译：制备苯乙烯 - 异戊二烯橡胶的方法
公开(公告)号：US06576728B1
公开(公告)日：2003-06-10
申请号：US10000738
申请日：2001-10-31
申请人： Chad Aaron Jasiunas , Adel Farhan Halasa , John Robert Zuppo, III
发明人： Chad Aaron Jasiunas , Adel Farhan Halasa , John Robert Zuppo, III
IPC分类号： C08F456
CPC分类号： C08F236/10 , C08F4/48
摘要： This invention is based upon the discovery of certain anionic initiator systems can be used to initiate the solution polymerization of conjugated diolefin monomers into rubbery polymers having a low vinyl content. For instance, such initiator systems can be used in the copolymerization of styrene and isoprene to produce low vinyl styrene-isoprene rubber having a random distribution of repeat units that are derived from styrene. These initiator systems are comprised of (a) a lithium initiator and (b) a member selected from the group consisting of (1) a sodium alkoxide, (2) a sodium salt of a sulfonic acid, and (3) a sodium salt of a glycol ether. It is important for the initiator system to be free of polar modifiers, such as Lewis bases. The subject invention more specifically discloses an initiator system which is comprised of (a) a lithium initiator and (b) a member selected from the group consisting of (1) a sodium alkoxide, (2) a sodium salt of a sulfonic acid, and (3) a sodium salt of a glycol ether, wherein said initiator system is void of polar modifiers. The present invention also discloses a process for preparing a rubbery polymer having a low vinyl content which comprises: polymerizing at least one diene monomer with a lithium initiator at a temperature which is within the range of about 5° C. to about 180° C. in the presence of a member selected from the group consisting of (1) a sodium alkoxide, (2) a sodium salt of a sulfonic acid, and (3) a sodium salt of a glycol ether, and wherein the process is conducted in the absence of polar modifiers.
摘要翻译：本发明基于某些阴离子引发剂体系的发现，可用于引发共轭二烯烃单体溶液聚合成具有低乙烯基含量的橡胶状聚合物。例如，这种引发剂体系可以用于苯乙烯和异戊二烯的共聚合以制备具有衍生自苯乙烯的重复单元的随机分布的低乙烯基苯乙烯 - 异戊二烯橡胶。这些引发剂体系包括（a）锂引发剂和（b）选自（1）醇钠，（2）磺酸钠盐和（3）钠盐的钠盐乙二醇醚。引发剂体系不含极性改性剂如路易斯碱是重要的。本发明更具体地公开了一种引发剂体系，其包括（a）锂引发剂和（b）选自（1）烷醇钠，（2）磺酸钠盐和（3）二醇醚的钠盐，其中所述引发剂体系没有极性改性剂。本发明还公开了一种制备低乙烯基含量的橡胶状聚合物的方法，该方法包括：在约5℃至约180℃的温度范围内使锂引发剂聚合至少一种二烯单体。在选自（1）烷氧基钠，（2）磺酸钠盐和（3）二醇醚的钠盐中的成员的存在下，其中所述方法在没有极性改性剂。

134. 发明授权

US06429245B1 Tire tread with elastomers of spatially defined Tg's 失效
标题翻译：轮胎胎面与空间定义的Tg的弹性体
公开(公告)号：US06429245B1
公开(公告)日：2002-08-06
申请号：US08931169
申请日：1997-09-16
申请人： William Paul Francik , Edward John Blok , Paul Harry Sandstrom , John Joseph Andre Verthe , David John Zanzig , Adel Farhan Halasa
发明人： William Paul Francik , Edward John Blok , Paul Harry Sandstrom , John Joseph Andre Verthe , David John Zanzig , Adel Farhan Halasa
IPC分类号： C08K524
CPC分类号： C08L9/00 , B60C1/0016 , C08K3/36 , C08K5/372 , C08L9/06 , Y10T152/10495 , C08L2666/08
摘要： The invention relates to a tire with a tread. The tread is composed of at least two defined elastomers having Tg's spaced apart by at least 55° C. to the exclusion of elastomers having Tg's between −30° and −85° C. The tread composition can be reinforced with either carbon black or a combination of carbon black and silica reinforcing fillers.
摘要翻译：本发明涉及一种具有胎面的轮胎。胎面由至少两个限定的具有Tg间隔至少55℃的弹性体组成，排除Tg在-30℃和-85℃之间的弹性体。胎面组合物可以用炭黑或炭黑和二氧化硅增强填料的组合。

135. 发明授权

US3948869A Process for polymerizing conjugated dienes 失效
标题翻译：聚合共轭二烯的方法
公开(公告)号：US3948869A
公开(公告)日：1976-04-06
申请号：US458951
申请日：1974-04-08
申请人： Adel Farhan Halasa , Richard Gutierrez
发明人： Adel Farhan Halasa , Richard Gutierrez
IPC分类号： C08F210/06 , C08F236/04 , C08F4/52 , C08F36/04 , C08F36/06
CPC分类号： C08F210/06 , C08F236/04 , C08F2410/01
摘要： Conjugated dienes and alpha-olefins, such as butadiene and propylene, are copolymerized by a new catalyst system which gives copolymers containing a high proportion of the alpha-olefin with accompanying desired properties. This catalyst system comprises: (1) A titanium or vanadium halide, preferably chloride, (2) an aluminum hydrocarbon compound, preferably an aluminum trialkyl having 1-8 carbon atoms in each of said alkyl groups and (3) CS.sub.2. The copolymers produced by this process have molecular weights in the range of 100,000-5,000,000, preferably 250,000-500,000, and other desirable properties.
摘要翻译：共轭二烯和α-烯烃如丁二烯和丙烯通过新的催化剂体系进行共聚，该催化剂体系产生含有高比例的α-烯烃的共聚物以及所需的性能。该催化剂体系包括：（1）钛或卤化钒，优选氯化物，（2）铝烃化合物，优选在每个所述烷基中具有1-8个碳原子的三烷基铝，和（3）CS 2。通过该方法制备的共聚物的分子量在100,000-5,000,000，优选250,000-500,000的范围内，以及其它所需的性质。

136. 发明授权

US3931127A Cyclized copolymer from a conjugated diene and an alpha olefin, and the production thereof 失效
标题翻译：来自共轭二烯和阿尔法橡胶的环化共聚物及其生产
公开(公告)号：US3931127A
公开(公告)日：1976-01-06
申请号：US417311
申请日：1973-11-19
申请人： Adel Farhan Halasa , Tai Chun Cheng
发明人： Adel Farhan Halasa , Tai Chun Cheng
IPC分类号： C08F236/04 , C08F4/46 , C08F36/04
CPC分类号： C08F236/04
摘要： A conjugated diene or a mixture of conjugated dienes or a mixture of a conjugated diene and an aryl vinyl monomer is polymerized with an alpha olefin in a reaction which is starved for monomer, and cyclization takes place. The catalyst includes a N,N,N', N'-tetra-alkyl alkylene diamine in which each alkyl group contains about 1 to 8 carbon atoms and the alkylene group contains 2 to 10 carbon atoms. N,N,N',N'-tetraethylenediamine is preferred. Other components of the catalyst include metallic sodium or potassium and alkyl sodium or potassium, preferably together with an alkali metal alkoxide.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式