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    • 124. 发明授权
    • Partial oxidation reactor
    • 部分氧化反应器
    • US07625414B2
    • 2009-12-01
    • US12125411
    • 2008-05-22
    • Luc NougierStéphane BertholinWilly Nastoll
    • Luc NougierStéphane BertholinWilly Nastoll
    • B06B1/00
    • B01J8/0221B01J8/0285B01J19/006B01J19/244B01J2208/00495B01J2208/0053B01J2208/00557B01J2219/00085B01J2219/00094B01J2219/00155B01J2219/00768B01J2219/182B01J2219/185B01J2219/187C01B3/36C01B2203/0255C01B2203/0883C01B2203/1241C01B2203/1247C01B2203/1282Y02P20/129
    • A reactor intended to carry out partial oxidation reactions starting from liquid feedstocks that can go from GPL to gas oil for the purpose of producing synthesis gas is characterized by finely controlled hydrodynamics and a high degree of thermal integration, and comprises an elongated jacket along an axis of any orientation, means (12) for supplying a preheated gas that contains oxygen and optionally water vapor, means (9) for supplying a hydrocarbon feedstock, means (11) for evacuation of a hydrogen-rich effluent, a first internal chamber (5) inside of which is carried out an essentially isothermal partial oxidation reaction that is connected to means (9) for supplying the hydrocarbon feedstock and to means (12) for supplying preheated gas, gas turbulizing means that are suitable for creating a perfect mixing flow, means (8) for linking first chamber (5) to a second chamber (7) with a suitable volume for carrying out a piston flow, linking means (8) that comprise at least one orifice, and second chamber (7) exchanging heat in an indirect manner over at least a portion of its length with means (12) for supplying said thus preheated gas, whereby the second chamber is connected to said means (11) for evacuating the hydrogen-rich effluent, and in which gas supply means (12) comprise an annular chamber that is essentially coaxial with the reactor jacket, and second chamber (7) is essentially coaxial with said jacket.
    • 旨在进行部分氧化反应的反应器,其特征在于精细控制的流体动力学和高度的热积分,其特征在于可以从GPL到瓦斯油从液态原料开始的部分氧化反应,并且包括沿轴线的细长夹套 任何方向的装置(12),用于提供含氧气和任选的水蒸气的预热气体,用于供应烃原料的装置(9),用于抽空富氢流出物的装置(11),第一内室(5 ),其中进行基本上等温的部分氧化反应,其连接到用于供应烃原料的装置(9)和用于供应预热气体的装置(12),适于产生完美混合流的气体湍流装置, 用于将第一室(5)与第二室(7)连接的装置(8),其具有用于进行活塞流的合适体积,连接装置(8),其包括至少一个 e和第二室(7)以间接方式在其长度的至少一部分上与用于供应所述如此预热的气体的装置(12)进行热交换,由此第二室连接到所述装置(11)以抽空氢 其中气体供应装置(12)包括基本上与反应器夹套同轴的环形室,而第二室(7)基本上与所述夹套同轴。
    • 130. 发明授权
    • Method and device for synthesizing high orientationally arranged carbon nano-tube by using organic liquid
    • 通过使用有机液体合成高取向排列碳纳米管的方法和装置
    • US07531156B2
    • 2009-05-12
    • US10481771
    • 2002-06-21
    • Toshihiro AndoMika GamoYafei Zhang
    • Toshihiro AndoMika GamoYafei Zhang
    • B82B3/00
    • B82Y30/00B01J10/007B01J2219/00094B01J2219/0013B01J2219/00263B01J2219/0884B01J2219/0894B82Y40/00C01B32/162C01B32/166C01B2202/08Y10S977/844
    • A method capable of synthesizing carbon nanotubes at low cost and large quantities, an apparatus usable for carrying out the method, and carbon nanotubes densely aligned on and firmly bonded to a Si substrate over, and oriented perpendicular to, an entire surface thereof are provided. Highly oriented, aligned carbon nanotubes are synthesized from an organic liquid by forming a substrate with a buildup thereon of a thin film or fine insular particles composed of at least one metallic element; exposing the substrate (3) having the buildup to a hydrogen plasma; and heating the substrate (3) exposed to the hydrogen plasma in the organic liquid (10) to a predetermined temperature. The synthesis apparatus comprises: a liquid chamber or tank (1) for an organic liquid; a water cooling means (2) for cooling the liquid tank (1) from its outside; a substrate holder (5) for holding a substrate (3), the holder having electrodes (4) for passing an electric current through the substrate (3); a condensing means (7) comprising water cooling tubes (6) for cooling and condensing vapor made from the organic liquid by its vaporization to return it to the liquid for return into the liquid tank (1); a valve (8) through which N2 gas is introduced; and a lid (9) that carries the substrate holder (5), the condensing means (7) and the valve (8). The organic liquid (10) is thus tightly sealed in the liquid tank (1) by the lid (9). This synthesis apparatus allows carbon nanotubes to be synthesized in large quantities, at low cost and in safety. Highly coaxially and densely oriented, aligned carbon nanotubes can be synthesized in the form of a bundle thereof, which when used in a variety of products brings about various excellent effects including extremely high usability.
    • 提供了能够以低成本和大量合成碳纳米管的方法,可用于实施该方法的装置,以及紧密地对准并牢固地结合到Si衬底并且垂直于其整个表面的碳纳米管。 通过在其上积聚由至少一种金属元素构成的薄膜或细小岛状颗粒的基板,由有机液体合成高取向的排列碳纳米管; 将具有积聚的衬底(3)暴露于氢等离子体; 以及将暴露于有机液体(10)中的氢等离子体的衬底(3)加热至预定温度。 合成装置包括:用于有机液体的液体室或罐(1); 用于从其外部冷却液体罐(1)的水冷装置(2); 用于保持基板(3)的基板保持器(5),所述保持器具有用于使电流通过所述基板(3)的电极(4); 冷凝装置(7),包括水冷却管(6),用于通过其蒸发冷却和冷凝由有机液体制成的蒸汽,以将其返回到液体以返回到液体箱(1)中; 引入N 2气体的阀(8); 以及承载基板保持件(5),冷凝装置(7)和阀(8)的盖(9)。 有机液体(10)因此通过盖(9)紧密地密封在液体罐(1)中。 该合成装置允许以低成本和安全性大量合成碳纳米管。 高度同轴且致密定向的碳纳米管可以以其束的形式合成,当用于各种产品时,可以产生包括极高的可用性的各种优异的效果。