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    • 114. 发明申请
    • Chiral dopant with phenylethanediol functionality
    • 手性掺杂剂与苯乙二醇功能
    • US20060022167A1
    • 2006-02-02
    • US10519604
    • 2003-06-13
    • Johan LubRene Wegh
    • Johan LubRene Wegh
    • C09K19/36C09K19/52C09K19/20C07C69/76
    • C07D493/04C07C69/92C09K19/586Y10T428/10Y10T428/1036
    • The invention pertains to a phenylethanediol derivative having at least one polymerizable group, characterized in that the phenylethanediol derivative further comprises at least one photo-convertible group for adjusting the helical twisting power of the phenylethanediol derivative. According to a preferred embodiment the phenylethanediol has the formula wherein A stands for a bond or a p-phenylene group; B and B′ are independently (O)p—CoH2o—O—CO—CR′═CH2, o being 2-12, p being 0 or 1, and R′ being H or CH3; P stands for a CH2 or a C═O group; Q and Q′ are independently selected from H, C1-C3 alkyl, C1-C3 alkoxy, halogen, and CN; n is an integer from 1 to 3; and m is an integer from 0 to 2; and: wherein A stands for a bond or a p-phenylene group; B is (O)p—CoH2o—O—CO—CR′═CH2, o being 2-12, p is 1, and R′ being H or CH3; P stands for a CH2 or a C═O group; Q is selected from H, C1-C3 alkyl, C1-C3 alkoxy, halogen, and CN; and m is an integer from 0 to 2.
    • 本发明涉及具有至少一个可聚合基团的苯乙二醇衍生物,其特征在于所述苯乙二醇衍生物还包含至少一个用于调节苯乙二醇衍生物的螺旋扭转能力的光转化基团。 根据优选的实施方案,苯乙二醇具有下式:其中A代表键或对亚苯基; B和B'独立地是(O)-O-CO-CR'-CH 2,-O-CO-CR'-CH 2, / SUB,o为2-12,p为0或1,R'为H或CH 3。 P代表CH 2或C-O基团; Q和Q'独立地选自H,C 1 -C 3烷基,C 1 -C 3烷氧基,卤素和CN; n为1〜3的整数, m为0〜2的整数。 和:其中A代表键或对亚苯基; B是(O)-O-CO-CR'-CH 2,-O-CO-CR'-CH 2, o为2-12,p为1,R'为H或CH 3。 P代表CH 2或C-O基团; Q选自H,C 1 -C 3烷基,C 1 -C 3烷氧基,卤素和CN; m为0〜2的整数。
    • 116. 发明授权
    • Single-layer reflective super broadband circular polarizer and method of
fabrication therefor
    • US5691789A
    • 1997-11-25
    • US550022
    • 1995-10-30
    • Le LiSadeg Mustafa Faris
    • Le LiSadeg Mustafa Faris
    • C08L83/04F24J2/40G02B5/30G02F1/1335G02F1/13C09K19/36
    • B82Y15/00F24J2/407G02B5/3016E06B2009/2464Y02E10/40
    • The present invention relates generally to broadband, reflective circular polarizers and, more particularly, to single layer super broadband, reflective circular polarizers. The polarizers of the present invention are made from a film of material, like a polymer having a cholesteric order, in which a second liquid crystal material, like a nematic liquid crystal, is distributed in a non-linear fashion across the thickness of the film in a plurality of liquid crystal-rich and liquid crystal-depleted sites in the polymer. The resulting polarizers have band passes approaching 2000 nm and reflect circularly polarized light which is either left-handed or right-handed depending on the final spiral structure of the materials utilized. The material of the present invention is fabricated by mixing commercially available polymers having a cholesteric order, a second liquid crystal material and a photoinitiator at a temperature which maintains the mixture in a liquid state. The polymer and the liquid crystal are present in a ratio by weight of 1:2, for example, and the photoinitiator is present in an amount of 0.6% by weight, for example, in the mixture. The heated mixture is then subjected to actinic radiation for a time and at an intensity sufficient to polymerize the polymer or the liquid crystal material or both. Under all polymerizing conditions the segregation rate of the liquid crystal material has to be greater than the polymerization rate of the material being polymerized. The liquid crystal segregates and diffuses, during polymerization, to sites of enlarged pitch in the polymer material from sites of shrunken pitch in the polymer material. Because the actinic light has an exponential intensity distribution due to light attenuation by, for example, light absorption, polymerization occurs in a non-linear fashion resulting in a non-linear distribution of the polymer and the liquid crystal material across the film.