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111. 发明授权

US6034259A .alpha.-olefins and olefin polymers and processes therefor 失效
标题翻译： α-烯烃和烯烃聚合物及其工艺
公开(公告)号：US6034259A
公开(公告)日：2000-03-07
申请号：US891398
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译：本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。聚合由选择的过渡金属化合物，有时是其他助催化剂催化。由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。公开了许多新颖的催化剂，以及一些制备它们的新方法。制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。

112. 发明授权

US5998534A Water-soluble or water-dispersible addition copolymer 失效
标题翻译：水溶性或水分散性加成共聚物
公开(公告)号：US5998534A
公开(公告)日：1999-12-07
申请号：US100517
申请日：1998-06-19
申请人： Robert H. Tang , Huawen Li , Alan E. Wang
发明人： Robert H. Tang , Huawen Li , Alan E. Wang
IPC分类号： C08F220/10 , C08F220/28 , C08F26/06
CPC分类号： C08F220/28 , C08F220/10
摘要： Water-soluble or water-dispersible addition copolymer of ethylenically unsaturated monomers, wherein the ethylenically unsaturated monomers comprise N-vinyl-2-pyrrolidinone and ethylenically unsaturated polyether, is useful as a component of inkjet printable coatings. The copolymer serves to reduce later migration of inks printed on the coatings.
摘要翻译：烯键式不饱和单体的水溶性或水分散性加成共聚物，其中烯属不饱和单体包括N-乙烯基-2-吡咯烷酮和烯属不饱和聚醚，可用作喷墨印刷涂料的组分。该共聚物用于减少印刷在涂料上的油墨的稍后迁移。

113. 发明授权

US5994025A Photoresist, compounds for composing the photoresist, and method of forming pattern by using the photoresist 失效
标题翻译：光致抗蚀剂，用于构成光致抗蚀剂的化合物，以及通过使用光致抗蚀剂形成图案的方法
公开(公告)号：US5994025A
公开(公告)日：1999-11-30
申请号：US763054
申请日：1996-12-10
申请人： Shigeyuki Iwasa , Kaichiro Nakano , Katsumi Maeda , Takeshi Ohfuji , Etsuo Hasegawa
发明人： Shigeyuki Iwasa , Kaichiro Nakano , Katsumi Maeda , Takeshi Ohfuji , Etsuo Hasegawa
IPC分类号： C08F220/04 , C08F220/06 , C08F220/10 , C08F220/18 , C08F220/26 , C08F220/28 , C09D133/04 , C09D133/14 , G03F7/004 , G03F7/039 , H01L21/027
CPC分类号： G03F7/039 , G03F7/0045 , Y10S430/11 , Y10S430/111
摘要： There is provided a photoresist including (a) a resin composed of a polymer represented with the following general formula [1], and (b) a photo acid generator which produces acid when exposed to a light: ##STR1## wherein each of R.sup.1, R.sup.3 and R.sup.7 represents one of a hydrogen atom and a methyl group, R.sup.2 represents a hydrocarbon group including a bridged cyclic hydrocarbon group and having a carbon number in the range of 7 to 13 both inclusive, R.sup.4 represents one of a hydrogen atom and a hydrocarbon group having a carbon number of 1 or 2, R.sup.5 represents a hydrocarbon group having a carbon number of 1 or 2, R.sup.6 represents one of (a) a hydrocarbon group having a carbon number in the range of 1 to 12 both inclusive, (b) a hydrocarbon group having a carbon number in the range of 1 to 12 both inclusive and replaced with an alkoxy group having a carbon number in the range of 1 to 12 both inclusive, and (c) a hydrocarbon group having a carbon number in the range of 1 to 12 both inclusive and replaced with an acyl group having a carbon number in the range of 1 to 13 both inclusive, x+y+z=1, x is in the range of 0.1 to 0.9, y is in the range of 0.1 to 0.7, and z is in the range of 0 to 0.7. The resin has a weight percent in the range of 75 to 99.8 both inclusive, and the photo acid generator has a weight percent in the range of 0.2 to 25 both inclusive. The above mentioned photoresist produces no extra polymer by side reaction. Thus, the photoresist has high resolution to thereby make it possible to form a fine pattern without resist residue.
摘要翻译：提供了包含（a）由以下通式[1]表示的聚合物构成的树脂的光致抗蚀剂，（b）暴露于光时产生酸的光酸产生剂：其中R1，R3和R7 表示氢原子和甲基中的一个，R 2表示包含桥连环烃基并且碳数为7〜13的碳原子的烃基，R4表示氢原子和具有碳原子数1或2，R 5表示碳数为1或2的烃基，R 6表示（a）碳原子数为1〜12的烃基，（b）烃碳数为1〜12的碳原子数为2〜12的碳原子数为2〜12的烷氧基，（c）碳数为1以上的烃基到12，并用a替代碳原子数为1〜13的碳原子，x + y + z = 1，x在0.1〜0.9的范围内，y在0.1〜0.7的范围内，z在范围为0〜0.7。树脂的重量百分比在75〜99.8之间，光酸产生剂的重量百分比在0.2〜25的范围内。上述光致抗蚀剂通过副反应不产生额外的聚合物。因此，光致抗蚀剂具有高分辨率，从而可以形成没有抗蚀剂残留物的精细图案。

114. 发明授权

US5993951A Transparent plastic sheet 失效
标题翻译：透明塑料片
公开(公告)号：US5993951A
公开(公告)日：1999-11-30
申请号：US035306
申请日：1998-03-02
申请人： Minoru Shimizu , Yoshifumi Kubota , Jun Nakauchi
发明人： Minoru Shimizu , Yoshifumi Kubota , Jun Nakauchi
IPC分类号： C08F220/10 , C08F220/14 , C08J5/18 , B32B9/00
CPC分类号： C08J5/18 , C08J2333/12 , Y10T428/31507
摘要： Disclosed is a transparent plastic sheet obtained by co-polymerizing 100 parts by weight of methyl methacrylate with 0.1 to 2.0 parts by weight of methacrylic acid and 0.1 to 1.5 parts by weight of glycidyl methacrylate, and having a thickness of not greater than 4 inches, wherein the angular deviation satisfies specified conditions according to the thickness of the sheet and wherein the degree of swelling is not greater than 2.50. This transparent plastic sheet shows neither coloring nor sink marks on the surface, has excellent craze resistance and low long-term water absorption percentage, and is hence suitable for use as an aircraft windshield.
摘要翻译：公开了将100重量份甲基丙烯酸甲酯与0.1〜2.0重量份甲基丙烯酸和0.1〜1.5重量份甲基丙烯酸缩水甘油酯共聚而得到的透明塑料片，其厚度不大于4英寸，其中所述角度偏差根据所述片材的厚度满足特定条件，并且其中所述溶胀度不大于2.50。该透明塑料片在表面上既不显示着色也不表示凹痕，具有优异的耐热冲击性和低的长期吸水率，因此适合用作飞机挡风玻璃。

115. 发明授权

US5959029A Composition containing a styrene/methacrylate polymer 失效
标题翻译：含有苯乙烯/甲基丙烯酸酯聚合物的组合物
公开(公告)号：US5959029A
公开(公告)日：1999-09-28
申请号：US912801
申请日：1997-08-18
申请人： Robert Koelliker , Harald Bachler
发明人： Robert Koelliker , Harald Bachler
IPC分类号： C08L33/06 , C04B24/26 , C08F2/20 , C08F2/24 , C08F212/08 , C08F220/10 , C08F261/04 , C08F265/04 , C08F271/02 , C08L25/08 , C08L33/04 , C09D5/02 , C09D5/03 , C09D125/08 , C09D133/04 , C09D133/06 , C09J125/08 , C09J133/04 , C09J133/06 , C08G63/48
CPC分类号： C04B24/2641 , C04B24/2676 , C08F212/08 , C08F220/10 , C08F261/04 , C08F265/04 , C08F271/02 , C04B2103/0057
摘要： The invention relates to a chemical composition containing a) a copolymer based on styrene and/or at least one alkyl (meth)acrylate, the quantity of styrene and/or alkyl (meth)acrylate being .gtoreq.50% by weight, based on the total monomers, and at least one further comonomer, and b) a water-soluble polymeric protective colloid, wherein about 2 to 30 parts per weight of the water-soluble polymeric protective colloid are allotted to 100 parts by weight of the copolymer, and c) optional further additives as required. The copolymer contains appoximately 0.1 to 50% by weight units of an epoxide-group-containing ethylenically unsaturated comonomer. Such units show reactive epoxide groups. The invention relates further to an aqueous polymer dispersion of said chemical composition, the production of same and a special method for obtaining the chemical composition from the polymer dispersion and special applications of the aqueous polymer dispersion and the chemical composition.
摘要翻译：本发明涉及一种含有a）基于苯乙烯和/或至少一种（甲基）丙烯酸烷基酯的共聚物的化学组合物，苯乙烯和/或（甲基）丙烯酸烷基酯的量基于总共单体和至少一种另外的共聚单体，和b）水溶性聚合物保护胶体，其中约2至30份/重量的水溶性聚合物保护胶体分配到100份重量的共聚物中，和 c）根据需要选择其他添加剂。共聚物含有约0.1〜50重量％的含环氧基的烯键式不饱和共聚单体。这些单元显示反应性环氧基团。本发明还涉及所述化学组合物的水性聚合物分散体，其制备方法和从聚合物分散体获得化学组成的特殊方法以及聚合物水分散体和化学组成的特殊应用。

116. 发明授权

US5902836A Acrylic syrup curable to a crosslinked viscoelastomeric material 失效
标题翻译：可固化至交联粘弹性材料的丙烯酸树脂
公开(公告)号：US5902836A
公开(公告)日：1999-05-11
申请号：US505350
申请日：1995-08-23
申请人： Greggory S. Bennett , Gaddam N. Babu , Kejian Chen , Louis E. Winslow , George F. Vesley , Patrick G. Zimmerman
发明人： Greggory S. Bennett , Gaddam N. Babu , Kejian Chen , Louis E. Winslow , George F. Vesley , Patrick G. Zimmerman
IPC分类号： B05D7/02 , B05D7/24 , C08F2/02 , C08F2/40 , C08F2/46 , C08F2/48 , C08F2/50 , C08F20/10 , C08F220/10 , C08F291/00 , C09D4/00 , C09D4/06 , C09J4/00 , C09J4/06 , C09J7/00 , C09J7/02 , G03F7/027 , C08J133/08 , C08J133/10
CPC分类号： G03F7/027 , C08F2/48 , C08F2/50 , C08F291/00 , C09D4/06 , C09J4/06 , Y10S522/904 , Y10S522/905
摘要： Solute polymers in solvent monomers form a coatable syrup that can be cured to a viscoelastomeric material when radiation-sensitive .alpha.-cleaving groups in either the polymer or one of the monomers are exposed to ultraviolet radiation. The solute polymers can be formed from the solvent monomers in situ or be added thereto to form the syrup.
摘要翻译： PCT No.PCT / US95 / 09601 Sec。 371日期1995年8月23日 102（e）日期1996年8月23日PCT提交1995年7月28日PCT公布。出版物WO96 / 04346 日期1996年2月15日溶剂单体中的溶剂聚合物形成可涂覆的糖浆，当聚合物或单体之一中的辐射敏感的α-分离基团暴露于紫外线辐射时，其可以固化成粘弹性材料。溶质聚合物可以由溶剂单体原位形成或加入其中形成糖浆。

117. 发明授权

US5880323A Processes for making .alpha.-olefins 失效
标题翻译：制备α-烯烃的方法
公开(公告)号：US5880323A
公开(公告)日：1999-03-09
申请号：US891331
申请日：1997-07-10
申请人： Maurice S. Brookhart, III , Lynda Kaye Johnson , Christopher Moore Killian , Lin Wang , Zhen-Yu Yang
发明人： Maurice S. Brookhart, III , Lynda Kaye Johnson , Christopher Moore Killian , Lin Wang , Zhen-Yu Yang
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译：本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。聚合由选择的过渡金属化合物，有时是其他助催化剂催化。由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。公开了许多新颖的催化剂，以及一些制备它们的新方法。制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。

118. 发明授权

US5880173A Hydrolyzable metal-containing resin and antifouling paint composition 失效
标题翻译：可水解含金属树脂和防污涂料组合物
公开(公告)号：US5880173A
公开(公告)日：1999-03-09
申请号：US793536
申请日：1997-02-25
申请人： Masayuki Matsuda , Jyoji Kitakuni , Kiyoaki Higo , Chiharu Uchida
发明人： Masayuki Matsuda , Jyoji Kitakuni , Kiyoaki Higo , Chiharu Uchida
IPC分类号： C08F8/44 , C08F20/26 , C08F220/04 , C08F220/10 , C08F220/18 , C08F220/28 , C09D5/16 , C09D133/00 , C09D133/04 , C08F20/06
CPC分类号： C09D5/1668 , C08F8/44
摘要： A substrate resin having pendant acid groups is produced by copolymerizing an acrylic or methacrylic ester of which alcoholic residue includes a bulky hydrocarbon radical or a soft segment. The substrate resin is then metallized together with an organic mobobasic acid so that both of the pendant acid group and the organic monobasic acid group are bount to the same metal atom. The resulting hydrolyzable metal-containing resin is incorporated into self-polishing antifouling paint formulations together with an antifouling pigment such as cuprous oxide.
摘要翻译： PCT No.PCT / JP95 / 01625 Sec。 371日期1997年2月25日 102（e）日期1997年2月25日PCT提交1995年8月14日PCT公布。出版物WO96 / 06870 日期：1996年3月7日具有侧基酸基的树脂通过使含有大体积烃基或软链段的醇残基的丙烯酸或甲基丙烯酸酯共聚来制造。然后将基材树脂与有机钼酸盐一起金属化，使得侧基酸基团和有机一元酸基团两者都可以与相同的金属原子结合。得到的可水解金属的树脂与防污颜料如氧化亚铜一起掺入自抛光防污涂料配方中。

119. 发明授权

US5872202A Polymethacrylate molding compound with ethylene 失效
标题翻译：聚甲基丙烯酸酯模塑料与乙烯
公开(公告)号：US5872202A
公开(公告)日：1999-02-16
申请号：US945268
申请日：1997-12-22
申请人： Werner Siol , Michael Wicker
发明人： Werner Siol , Michael Wicker
IPC分类号： C08J3/12 , C08F220/14 , C08F220/10
CPC分类号： C08F220/14
摘要： The invention relates to a molding mass which can be thermoplastically processed, characterized in that it consists of monomer units ofa) 80-99.9 wt.- % methyl methacrylate,b) 0.1-20 wt.- % ethylene,c) 0-19.9 wt.- % other comonomers.The invention further relates to a method for the production of the molding mass, as well as molded elements made from it.
摘要翻译： PCT No.PCT / EP97 / 00503 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT提交1997年2月5日PCT公布。公开号WO97 / 31043 日期：1997年8月28日本发明涉及一种能够进行热塑性加工的成型体，其特征在于其由以下单体组成：a）80-99.9重量％甲基丙烯酸甲酯，b）0.1-20重量％乙烯， c）0-19.9重量％的其它共聚单体。本发明还涉及一种用于生产成型物料的方法，以及由其制成的模制件。

120. 发明授权

US5863999A Viscosity index improving additives for phosphate ester-containing hydraulic fluids 失效
标题翻译：磷酸酯类液压油粘度指数改进添加剂
公开(公告)号：US5863999A
公开(公告)日：1999-01-26
申请号：US62806
申请日：1998-04-20
申请人： Bernard George Kinker , Robert Howard Gore , Charles William Hyndman , Bridget Marie Stevens
发明人： Bernard George Kinker , Robert Howard Gore , Charles William Hyndman , Bridget Marie Stevens
IPC分类号： C09K3/00 , C10M145/14 , C10M169/04 , C10N20/02 , C10N20/04 , C10N30/00 , C10N30/02 , C10N30/10 , C10N40/08 , C08F220/10 , C08F120/18
CPC分类号： C10M145/14 , C10M169/041 , C10M2207/024 , C10M2207/026 , C10M2207/124 , C10M2209/084 , C10M2215/064 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/003 , C10M2219/021 , C10M2219/0406 , C10M2219/044 , C10M2219/0463 , C10M2219/061 , C10M2219/081 , C10M2219/101 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2225/003 , C10M2225/025 , C10M2225/0405 , C10M2229/041 , C10N2240/08 , C10N2240/12 , C10N2240/121 , C10N2240/14
摘要： Polymer compositions derived from selected alkyl (meth)acrylate ester monomers used in certain weight ratios to provide improved viscosity control and low temperature performance characteristics in phosphate ester aircraft hydraulic fluids is disclosed. Polymer compositions for use as viscosity index improving additives in aircraft hydraulic fluids contain from 40 to 100 weight percent (C.sub.1 -C.sub.10)alkyl (meth)acrylate and zero to 60 weight percent (C.sub.11 -C.sub.20)alkyl (meth)acrylate monomer units. Preferred polymer compositions based on 40 to 70 weight percent (C.sub.1 -C.sub.10)alkyl (meth)acrylate and 30 to 60 weight percent (C.sub.11 -C.sub.15)alkyl (meth)acrylate monomer units combine good solubility in the phosphate ester hydraulic fluids with good viscosity control at low and high temperatures.
摘要翻译：公开了衍生自选定的（甲基）丙烯酸烷基酯单体的聚合物组合物，其以一定重量比使用，以提供磷酸酯飞机液压流体中改进的粘度控制和低温性能特征。在飞机液压油中用作粘度指数改进添加剂的聚合物组合物含有（甲基）丙烯酸（C 1 -C 10）烷基酯的40至100重量％（甲基）丙烯酸C至20重量％（C 11 -C 20）烷基酯单体单元。优选的基于40-70重量％（甲基）丙烯酸（C1-C10）烷基酯和（甲基）丙烯酸（C11-C15）烷基酯）单体单元的聚合物组合物在具有良好粘度的磷酸酯液压油中具有良好的溶解性在低温和高温下进行控制。

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