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    • 115. 发明申请
    • COMPOSITE OXIDE
    • 复合氧化物
    • US20140309104A1
    • 2014-10-16
    • US14358780
    • 2012-11-01
    • SANTOKU CORPORATION
    • Tadatoshi MurotaShigeru OnoTomonori Tahara
    • B01J23/10
    • B01J23/10B01D53/945B01D2255/407B01D2255/908B01J35/1038B01J37/031B01J37/04B01J37/12C01G25/00C01G25/006C01P2002/52C01P2002/54C01P2002/74C01P2006/14
    • Provided is a composite oxide which is suitable as a co-catalyst for an exhaust gas purifying catalyst or the like, has high heat resistance, and has an excellent oxygen absorbing and desorbing capability at low temperatures. The composite oxide contains Ce and Zr, wherein the Ce content is 30 to 80 at % and the Zr content is 20 to 70 at %, based on the total of Ce and Zr being 100 at %, or further contains particular element M, wherein the Ce content is not less than 30 at % and less than 80 at %, the Zr content is not less than 20 at % and less than 70 at %, and the content of element M is more than 0 at % and not more than 15 at %, based on the total of Ce, Zr, and element M being 100 at %; wherein the composite oxide has CaF2-type or CaF2-like structure phase, wherein the ratio of an actual lattice parameter in the (311) plane to the theoretical is 1.000, and wherein the composite oxide has a property of exhibiting a total pore volume of not less than 0.30 cc/g after calcination at 1000° C. for 5 hours in the atmosphere.
    • 作为废气净化用催化剂等的助催化剂适合的复合氧化物,耐热性高,在低温下具有优异的氧吸收和解吸能力。 复合氧化物含有Ce和Zr,其中Ce含量为30〜80原子%,Zr含量为20〜70原子%,基于Ce和Zr的总量为100原子%,或者还含有特定的元素M,其中 Ce含量不小于30at%且小于80at%,Zr含量不小于20at%且小于70at%,元素M的含量大于0at%且不大于 15原子%,基于Ce,Zr和元素M的总量为100原子%; 其中所述复合氧化物具有CaF 2型或CaF 2样结构相,其中(311)面中的实际晶格参数与所述理论值的比值为1.000,并且其中所述复合氧化物具有显示总孔体积 在大气中在1000℃煅烧5小时后不少于0.30cc / g。