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    • 114. 发明授权
    • Processes for producing pentafluoropropenes and azeotropes comprising HF and certain halopropenes of the formula C3Cl2F4, C3ClF5, or C3HF5
    • 制备五氟丙烯的方法和包含HF的共沸物和式C3Cl2F4,C3ClF5或C3HF5的某些卤代丙烯
    • US08058489B2
    • 2011-11-15
    • US12444598
    • 2007-11-15
    • Velliyur Nott Mallikarjuna RaoAllen Capron Sievert
    • Velliyur Nott Mallikarjuna RaoAllen Capron Sievert
    • C07C17/10C07C17/00
    • C07C21/18C07C17/206C07C17/23C07C17/25C07C17/354Y02P20/582C07C19/08
    • A process is disclosed for making CF3CF═CHF or mixtures thereof with CF2═CFCHF2. The process involves (i) contacting CHCl2CF2CF3, and optionally CHClFCF2CClF2, in a reaction zone in the presence of a catalytically effective amount of dehydrofluorination catalyst to produce CCl2═CFCF3, and, if CHClFCF2CClF2 is present, CClF═CFCClF2; (ii) contacting CCl2═CFCF3 and CClF═CFCClF2, if any, formed in (i) with hydrogen fluoride (HF) in a reaction zone, optionally in the presence of a fluorination catalyst, to produce CClF═CFCF3, and if CClF═CFCClF2 is present, CF2═CFCClF2; (iii) contacting CClF═CFCF3 and CF2═CFCClF2, if any, formed in (ii) in a reaction zone with H2 in the presence of a catalyst comprising a catalytically effective amount of palladium supported on a support of chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride, and/or fluorinated alumina to produce a product mixture comprising CF3CF═CHF, and if CF2═CFCClF2 is present, CF2═CFCHF2; and (iv) recovering CF3CF═CHF, or a mixture thereof with CF2═CFCHF2, from the product mixture formed in (iii); and optionally (v) separating at least a portion of any CF3CF═CHF in the product mixture formed in (iii) from the CF2═CFCHF2 in the product mixture formed in (iii).Also disclosed are azeotropic compositions involving CCl2═CFCF3 and HF; involving CCl2═CFCF3, CClF═CFCClF2 and HF; involving CClF═CFCF3 and HF; involving CClF═CFCF3, CF2═CFCClF2 and HF; or involving CF2═CFCHF2 and HF.
    • 公开了制备CF 3 CF = CHF或其与CF 2 = CFCHF 2的混合物的方法。 该方法包括(i)在催化有效量的脱氟化氢催化剂存在下,在反应区中使CHCl 2 CF 2 CF 3和任选的CHClFCF 2 CClF 2接触以产生CCl 2 = CFCF 3,并且如果存在CHClFCF 2 CClF 2,则CClF = CFCClF 2; (ii)在反应区中任选地在(i)中与氟化氢(HF)形成的CCl 2 = CFCF 3和CClF = CFCClF 2(如果有的话)任选地在氟化催化剂的存在下接触,生成CClF = CFCF 3,并且如果CClF = 存在CFCClF 2,CF 2 = CFCClF 2; (iii)在包含催化有效量的负载在氧化铬载体上的载体的催化剂存在下,在与反应区中的(ii)反应区中形成的CClF = CFCF 3和CF 2 = CFCClF 2, ,氟化铬,氧化铝,氟化铝和/或氟化氧化铝,以产生包含CF 3CF≡CHF的产物混合物,如果存在CF 2 = CFCClF 2,CF 2 = CFCHF 2; 和(iv)从(iii)中形成的产物混合物中回收CF 3 CF = CHF或其与CF 2 = CFCHF 2的混合物; (iii)中形成的产物混合物中的CF 3 CF = CHF的至少一部分与(iii)中形成的产物混合物中的CF 2 = CFCHF 2分离。 还公开了包含CCl 2 = CFCF 3和HF的共沸组合物; 涉及CCl 2 = CFCF 3,CClF = CFCClF 2和HF; 涉及CClF = CFCF3和HF; 涉及CClF = CFCF3,CF2 = CFCClF2和HF; 或涉及CF2 = CFCHF2和HF。
    • 120. 发明授权
    • Catalytic isomerization between E and Z isomers of 1,2,3,3,3-pentafluoropropene
    • 1,2,3,3,3-五氟丙烯的E和Z异构体之间的催化异构化
    • US08044252B2
    • 2011-10-25
    • US12373588
    • 2007-07-11
    • Mario Joseph NappaDonald J. TotonVelliyur Nott Mallikarjuna Rao
    • Mario Joseph NappaDonald J. TotonVelliyur Nott Mallikarjuna Rao
    • C07C17/00
    • B01J27/12B01J27/135C07C17/358C07C21/18
    • A process is disclosed to increase the Z/E ratio of 1,2,3,3,3-pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3-pentafluoropropene with a catalyst on AlF3 or carbon, wherein the catalyst is selected from the group consisting of SbClwF5-w, TiClxF4-x, SnClyF4-y and TaCl2F5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is increased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in the starting material.A process is also disclosed to decrease the Z/E ratio of 1,2,3,3,3-pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3-pentafluoropropene with a catalyst on AlF3 or carbon, wherein the catalyst is selected from the group consisting of SbClwF5-w, TiClxF4-x, SnClyF4-y and TaClzF5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is decreased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in the starting material.
    • 公开了提高1,2,3,3,3-五氟丙烯的Z / E比的方法。 该方法包括使包含1,2,3,3,3-五氟丙烯的起始材料与AlF 3或碳上的催化剂接触,其中催化剂选自SbClwF5-w,TiClxF4-x,SnClyF4-y和TaCl2F5 -z其中w为0至4,x为0至3,y为0至3,z为0至4,得到其Z / E比为1,2,3,3, 3-五氟丙烯相对于起始原料中1,2,3,3,3-五氟丙烯的Z / E比增加。 还公开了降低1,2,3,3,3-五氟丙烯的Z / E比的方法。 该方法包括将包含1,2,3,3,3-五氟丙烯的原料与AlF 3或碳上的催化剂接触,其中催化剂选自SbClwF5-w,TiClxF4-x,SnClyF4-y和TaClzF5 -z其中w为0至4,x为0至3,y为0至3,z为0至4,得到其Z / E比为1,2,3,3, 3-五氟丙烯相对于起始原料中1,2,3,3,3-五氟丙烯的Z / E比降低。