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111. 发明申请

US20090275712A1 Metallocene Compounds 有权
标题翻译：茂金属化合物
公开(公告)号：US20090275712A1
公开(公告)日：2009-11-05
申请号：US12226095
申请日：2007-04-06
申请人： Luigi Resconi , Francesca Focante , Davide Balboni , liya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov
发明人： Luigi Resconi , Francesca Focante , Davide Balboni , liya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov
IPC分类号： C08F4/76 , C07F17/00 , B01J31/12 , B01J31/14 , C08F2/00
CPC分类号： C07F17/00 , C07F7/081 , C07F7/0812 , C08F4/65912 , C08F10/00 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/15 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F210/14 , C08F210/08
摘要： A bridged metallocene compound of formula (I) wherein: M is a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing heteroatoms; L is a divalent bridging group; R1 is a linear C1-C40 hydrocarbon radical optionally containing heteroatoms; T1 and T4 are a oxygen, sulfur atom or a C(R18)3 group; wherein R18, are hydrogen atoms or a C1-C40 hydrocarbon radical; T3 and T4 are C1-C40 hydrocarbon radicals; R4 is a hydrogen atom or a C1-C40 hydrocarbon radical; W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥连茂金属化合物，其中：M是过渡金属; X是氢原子，卤原子或任选含有杂原子的烃基; L是二价桥基; R1是任选地含有杂原子的直链C 1 -C 40烃基; T1和T4是氧，硫原子或C（R18）3基团; 其中R18为氢原子或C1-C40烃基; T3和T4是C1-C40烃基; R4是氢原子或C1-C40烃基; W是芳族5或6元环。

112. 发明授权

US07589160B2 Process for preparing 1-butene polymers 有权
标题翻译： 1-丁烯聚合物的制备方法
公开(公告)号：US07589160B2
公开(公告)日：2009-09-15
申请号：US10536858
申请日：2003-11-03
申请人： Luigi Resconi , Antonio Cascio Ingurgio
发明人： Luigi Resconi , Antonio Cascio Ingurgio
IPC分类号： C08F4/64 , C08F4/72 , C07F17/00
CPC分类号： C08F10/08 , C07F17/00 , C08F4/65912 , C08F110/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/20 , C08F2500/03
摘要： A process for obtaining 1-butene polymers comprising the step of contacting under polymerization conditions 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I): wherein: M is an atom of a transition metal belonging to group 3, 4, 5, 6 or to the lanthanide or actinide groups in the Periodic Table of the Elements; p is an integer from 0 to 3; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group; R1 is a hydrocarbon group; R2, R3 and R6 are hydrogen atoms or hydrocarbon groups; R4 and R5 join to form a condensed saturated or unsaturaded 4–7 membered ring; and L is a divalent bridging group; and b) an alumoxane or a compound able to form an alkylmetallocene cation.
摘要翻译：一种获得1-丁烯聚合物的方法，包括在聚合条件下1-丁烯和任选的乙烯，丙烯或所述α-烯烃在催化剂体系存在下接触的步骤，所述催化剂体系可通过以下步骤获得：a）式（I）的茂金属化合物）：其中：M是属于第3,4,5,6族的过渡金属或元素周期表中的镧系元素或锕系元素的原子; p是0至3的整数; X是氢原子，卤素原子或烃基; R1是烃基; R2，R3和R6是氢原子或烃基; R4和R5连接形成稠合的饱和或不饱和的4-7元环; L是二价桥基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

113. 发明授权

US07459511B2 Process for the polymerization of 1-butene 有权
标题翻译： 1-丁烯聚合方法
公开(公告)号：US07459511B2
公开(公告)日：2008-12-02
申请号：US10480762
申请日：2002-06-11
申请人： Luigi Resconi
发明人： Luigi Resconi
IPC分类号： C08F10/08 , C08F4/76 , C08F4/52 , C08F4/64
CPC分类号： C08F110/08 , C08F4/65912 , C08F10/08 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/12 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F210/16
摘要： A process for polymerizing 1-butene comprising the step of contacting under polymerization conditions 1-butene and optionally from 0 to 20% by mol of an alpha olefin with a catalyst system obtainable by contacting a bridget metallocene compound of formula (I) wherein R1 and R2 are an hydrocarbon radical A is a carbon atom, a germanium atom or a silicon atom; m is 1, 2; M is a metal of group 4 of the Periodic Table of the Elements; X, is hydrogen, a halogen atom, or a group R, OR, OSO2CF3, OCOR, SR, NR2 or PR2, wherein the substituents R are hydrocarbon radical; L is a moiety of formula (IIa) or (IIb) wherein T is an oxigen (O) or sulphur (S) atom or a CH2 group; and R3 and R4 are hydrogen atoms or hydrocarbon radicals; one or more alumoxanes or compounds able to form an alkylmetallocene cation; and optionally an organo aluminium compound.
摘要翻译：一种聚合1-丁烯的方法，包括在聚合条件下使1-丁烯和任选的0至20摩尔％的α-烯烃与可通过使式（I）的桥连金属茂化合物（其中R1和 R2是烃基A是碳原子，锗原子或硅原子; m为1,2; M是元素周期表第4族的金属; X是氢，卤素原子或基团R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2，其中取代基R是烃基; L是式（IIa）或（IIb）的部分，其中T是氧原子（O）或硫（S）原子或CH 2基团; 并且R 3和R 4是氢原子或烃基; 一种或多种能够形成烷基茂金属阳离子的铝氧烷或化合物; 和任选的有机铝化合物。

114. 发明申请

US20080249273A1 Isotactic 1-butene copolymers 有权
标题翻译：全同立构1-丁烯共聚物
公开(公告)号：US20080249273A1
公开(公告)日：2008-10-09
申请号：US11981497
申请日：2007-10-30
申请人： Luigi Resconi , Anteo Pelliconi , Enea Garagnani
发明人： Luigi Resconi , Anteo Pelliconi , Enea Garagnani
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/15 , C08F2500/20
摘要： An isotactic 1-butene copolymer having a content up to 30% by mol of at least one alpha-olefin of formula CH2═CHZ derived units, wherein Z is a C3-C20 hydrocarbon group, having the following features: isotactic pentads (mmmm) >90%; and a percentage of soluble fraction in diethylether (% SD) and a molar content of said alpha olefins (% O) in the polymer chain meeting the following relation: % SD>2.8% O+8.
摘要翻译：具有至多30摩尔％的至少一种式CH 2 -CH-Z衍生单元的α-烯烃的全同立构1-丁烯共聚物，其中Z是C 3 90％; 以及在聚合物链中的二乙醚中可溶性部分的百分比（％SD）和所述α-烯烃（％O）的摩尔含量满足以下关系：<？在线公式描述=“在线公式” “lead”？>％SD> 2.8％O + 8。<？in-line-formula description =“In-line Formulas”end =“tail”？>

115. 发明授权

US07417006B2 Catalyst system for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：US07417006B2
公开(公告)日：2008-08-26
申请号：US10478346
申请日：2002-05-07
申请人： Luigi Resconi , Simona Guidotti
发明人： Luigi Resconi , Simona Guidotti
IPC分类号： C07D207/00 , C07D209/00 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/44
CPC分类号： C07F5/027
摘要： A salt of formula (I) [HEoR13]+[T1T2]− (I) wherein Eo is a nitrogen or phosphorous atom; R1 is hydrocarbon radical; T1 is a Lewis acid that forms a complex with T2, and T2 is a substituted pyrrolyl radical of formula (III) These salts can be used as cocatalyst in a process for the polymerization of alpha-olefins in conjunction with a transition metal organometallic compound.
摘要翻译：式（I）的盐<？in-line-formula description =“In-line Formulas”end =“lead”？> （I）＆lt;＆lt;＆gt;（I）＆lt;＆lt; line-formula description =“In-line Formulas”end =“tail”？>其中E o是O或磷原子; R 1是烃基; T 1是与T 2形成络合物的路易斯酸，T 2是式（III）的取代的吡咯基。这些盐可以在与过渡金属有机金属化合物结合的α-烯烃的聚合方法中用作助催化剂。

116. 发明申请

US20080139761A1 Process for polymerizing 1-butene 审中-公开
公开(公告)号：US20080139761A1
公开(公告)日：2008-06-12
申请号：US12006938
申请日：2008-01-07
申请人： Luigi Resconi
发明人： Luigi Resconi
IPC分类号： C08F4/44 , C08F10/08 , C07F5/00 , C07F7/00 , C07D333/50
CPC分类号： C07F17/00 , C08F4/65912 , C08F10/08 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F210/16
摘要： A process for polymerizing 1-butene, optionally with up to 30% by mol of ethylene, propylene or an alpha olefin of formula CH2═CHT wherein T is a C3-C10 alkyl group, in the presence of a catalyst system obtainable by contacting a metallocene compound of formula (I) Wherein M is an atom of a transition metal; X, is a hydrogen atom, a halogen atoms or a hydrocarbon group; R1, R2, R5, R6, R7, R8 and R9 are hydrogen atoms or hydrocarbon groups; with the proviso that at least one of R6 or R7 is a C1-C20 alkyl group; R3 and R4 are C1-C20 alkyl groups; and an alumoxane and/or a compound capable of forming an alkyl metallocene cation.

117. 发明申请

US20080027190A1 Process for Producing Fractionable 1-Butene Polymers 失效
标题翻译：生产可分级1-丁烯聚合物的方法
公开(公告)号：US20080027190A1
公开(公告)日：2008-01-31
申请号：US11632612
申请日：2005-06-10
申请人： Maria Tonti , Luigi Resconi
发明人： Maria Tonti , Luigi Resconi
IPC分类号： C08F4/52 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/08 , Y10S526/943 , C08F4/65904 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2/001
摘要： A process for producing a 1-butene polymer comprising the step of polymerizing 1-butene in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (Ia) in the meso or meso-like form: wherein M is an atom of a transition metal p is an integer from 0 to 3, X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group. L is a divalent C1-C40 hydrocarbon radical R1 and R2, equal to or different from each other, are C1-C40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa), (IIb) or (IIc): wherein R3 and R5 are a C1-C40 hydrocarbon radical; R4 and R6, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon radicals and R7 and R8, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon radicals b) at least a metallocene compound of formula (Ib) in the racemic (rac) or racemic-like form c) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：一种制备1-丁烯聚合物的方法，包括在催化剂体系存在下聚合1-丁烯的步骤，所述催化剂体系可通过以下步骤获得：b）至少一种中内消旋或内消旋形式的式（Ia）金属茂化合物：其中 M为过渡金属的原子，p为0〜3的整数，X相同或不同，为氢原子，卤素原子或烃基。 L是二价C 1 -C 40烃基R 1和R 2，其等于或不同于彼此是C 1 -C 40烃基; T为相同或不同的式（IIa），（IIb）或（IIc）的部分：其中R 3和R 5为C 烃基; C 1 -C 40烃基; R 4和R 6彼此相同或不同，是氢原子或C 1 -C 40 烃基和R 7和R 8彼此相同或不同的是氢原子或C 1 -C 3烷基， 40个烃基b）至少一种外消旋（rac）或外消旋形式的式（Ib）金属茂化合物，c）铝氧烷或能够形成烷基茂金属阳离子的化合物。

118. 发明授权

US07314903B2 Catalyst system for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：US07314903B2
公开(公告)日：2008-01-01
申请号：US10520565
申请日：2003-07-09
申请人： Luigi Resconi , Francesca Focante , Isabella Camurati , Simona Guidotti
发明人： Luigi Resconi , Francesca Focante , Isabella Camurati , Simona Guidotti
IPC分类号： C08F6/64 , C08F6/643 , C08F6/6392 , C08F4/70
CPC分类号： C07F5/027 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F110/02 , C08F4/65908
摘要： An organometallic compound obtainable by contacting: a compound having the following formula (I), wherein: Ra is a hydrocarbon radical; Rb, Rc and Rd, are hydrogen atoms, halogen atoms, or hydrocarbon radicals; with a Lewis acid of formula (II) MtR13 (II) wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R1 are selected from the group consisting of halogen atoms, halogenated C6–C20 aryl and halogenated C7–C20 alkylaryl groups
摘要翻译：通过使具有下式（I）的化合物接触可得到的有机金属化合物，其中：R a是烃基; R b，R c和R d是氢原子，卤素原子或烃基; 与式（II）的路易斯酸反应，其中Mt是属于元素周期表第13族的金属; R 1选自卤素原子，卤代C 6 -C 20芳基和卤代C 7 H 12 -C 20烷基芳基

119. 发明申请

US20070112152A1 Metallocene compounds 失效
标题翻译：茂金属化合物
公开(公告)号：US20070112152A1
公开(公告)日：2007-05-17
申请号：US10584003
申请日：2004-11-16
申请人： IIya Nifant'ev , Pavel Ivchenko , IIya Tajdakov , Luigi Resconi
发明人： IIya Nifant'ev , Pavel Ivchenko , IIya Tajdakov , Luigi Resconi
IPC分类号： B01J31/00 , C08F4/44 , C07F17/00
CPC分类号： C07D495/04 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/02 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17
摘要： A metallocene compound of formula (I) wherein: M is an atom of a transition metal; X, same or different, is a hydrogen atom, a halogen atom, or a R, OR, OSO2CF3, OCOR, SR, NR2 or PR2 group, wherein R is C1-C40 hydrocarbon group; L is a divalent bridging group; R1, is a C1-C40 hydrocarbon group; R3 is a C1-C40 hydrocarbon group; R2, R4, R5, R6, R7 and R8, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon groups.
摘要翻译：式（I）的茂金属化合物，其中：M是过渡金属的原子; X相同或不同，为氢原子，卤原子或R，OR，OSO 2，CF 3，OCOR，SR，NR 2，或其中R是C 1 -C 40烃基; L是二价桥基; R 1是C 1 -C 40烃基; R 1是C 1 -C 40烃基; R 3是C 1 -C 40烃基; R 2，R 4，R 5，R 6，R 7和/或R 5， R 8彼此相同或不同，为氢原子或C 1 -C 40烃基。

120. 发明申请

US20060235173A1 Process for polymerizing 1-butene 有权
标题翻译： 1-丁烯聚合方法
公开(公告)号：US20060235173A1
公开(公告)日：2006-10-19
申请号：US10556373
申请日：2004-05-07
申请人： Luigi Resconi
发明人： Luigi Resconi
IPC分类号： C08F4/44 , C07F15/02 , C07F15/04 , C07F15/06
CPC分类号： C07F17/00 , C08F4/65912 , C08F10/08 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F210/16
摘要： A process for polymerizing 1-butene, optionally with up to 30% by mol of ethylene, propylene or an alpha olefin of formula CH2═CHT wherein T is a C3-C10 alkyl group, in the presence of a catalyst system obtainable by contacting a metallocene compound of formula (I) Wherein is an atom of a transition metal; is a hydrogen atom, a halogen atoms or a hydrocarbon group; R1, R2, R5, R6, R7, R8 and R9 are hydrogen atoms or hydrocarbon groups; with the proviso that at least one of R6 or R7 is a C1-C20 alkyl group; R3 and R4 are C1-C20 alkyl groups; and an alumoxane and/or a compound capable of forming an alkyl metallocene cation.
摘要翻译：聚合1-丁烯的方法，任选地含有至多30摩尔％的乙烯，丙烯或式CH 2 -CH 2的α-烯烃，其中T是C 3 - 在通过使式（I）的茂金属化合物与过渡金属的原子接触而获得的催化剂体系的存在下，是氢原子，卤原子或烃基; R 1，R 2，R 5，R 6，R 7， R 8和R 9是氢原子或烃基; 条件是R 6或R 7中的至少一个是C 1 -C 20烷基， ; R 3和R 4是C 1 -C 20烷基; 和铝氧烷和/或能够形成烷基茂金属阳离子的化合物。

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