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    • 102. 发明授权
    • Coating compositions
    • 涂料组合物
    • US5278249A
    • 1994-01-11
    • US778899
    • 1992-01-10
    • Alastair R. Marrion
    • Alastair R. Marrion
    • C09D125/08C08F8/30C08L77/08C08L101/06C09D7/12C09D125/00C09D125/14C09D133/04C09D133/06C09D133/14C09D139/04C09D177/00C09D177/06C09D201/02C09D201/06C09D201/08C08F8/32
    • C09D177/00C08F8/30C09D125/14C09D133/064C09D177/06C08F2800/20C08L101/06C08L77/08Y10T428/31855
    • A curable coating composition comprises a hydroxy-functional component (A) having at least two hydroxy groups per molecule and an anhydride-functional component (B) having at least two carboxylic acid anhydride groups per molecule. At least one of the components (A) and (B) is a film-forming polymer. The coating composition contains amidine groups for accelerating the curing reaction between the hydroxy groups of component (A) and the anhydride groups of component (B). The amidine groups are present in the molecule of either of the components (A) or (B) and/or are present in the form of a separate compound containing an amidine group. The component or compound containing an amidine group generally has the formula ##STR1## in which R.sup.1 represents hydrogen, or an organic group attached through a carbon atom, or an amine group which can be substituted, or a hydroxy group or etherified hydroxy group; R.sup.2 and R.sup.3 each independently represent hydrogen or an organic group attached through a carbon atom or are joined to one another to form (with the linking --N.dbd.C--N--) a heterocyclic ring; and R.sup.4 represents hydrogen, an organic group attached through a carbon atom, or a hydroxyl group which can be etherified. Preferably, R.sup.2 and R.sup.3 are joined to form an imidazoline, imidazole, tetrahydropyrimidine, dihydropyrimidine or pyrimidine ring.
    • PCT No.PCT / GB90 / 01075 Sec。 371日期1992年1月10日 102(e)日期1992年1月10日PCT提交1990年7月12日PCT公布。 出版物WO91 / 00894 日本1991年1月24日。可固化涂料组合物包含每分子具有至少两个羟基的羟基官能组分(A)和每分子具有至少两个羧酸酐基团的酸酐官能组分(B)。 组分(A)和(B)中的至少一种是成膜聚合物。 涂料组合物含有用于促进组分(A)的羟基与组分(B)的酸酐基团之间的固化反应的脒基。 脒基存在于组分(A)或(B)的分子中和/或以含有脒基的分离化合物的形式存在。 含有脒基的组分或化合物通常具有式(* CHEMICAL STRUCTURE *),其中R 1表示氢,或通过碳原子连接的有机基团或可被取代的胺基,或羟基或醚化羟基 组; R2和R3各自独立地表示氢或通过碳原子连接的有机基团,或者彼此连接形成(连接-N = C-N-)杂环; R4代表氢,通过碳原子连接的有机基团或可被醚化的羟基。 优选地,R 2和R 3连接形成咪唑啉,咪唑,四氢嘧啶,二氢嘧啶或嘧啶环。