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    • 101. 发明申请
    • Modification of printed and dyed materials
    • 打印和染色材料的修改
    • US20030121111A1
    • 2003-07-03
    • US10287135
    • 2002-11-04
    • Novozymes North America, Inc.
    • Caroline ShiSonja SalmonHui Xu
    • D06P001/00
    • C11D11/0017C11D3/38627D06P1/16D06P1/18D06P3/54D06P5/02Y10S8/921Y10S8/922Y10S8/924Y10S8/926Y10S8/927
    • The present invention relates to methods and compositions for removing excess dye from dyed and/or printed materials, such as, textile materials dyed with disperse dyes, by treating a dyed or printed material with an esterase. The improvements resulting form the present invention include, for example, improvements in the washfastness, the wetfastness, the crockfastness, sublimation, and/or the quality of the color, such as, brightness, of dyed and/or printed materials. The present invention also relates to methods for printing or dyeing a material by dyeing or printing the material with a combination of a dye that is affected by esterase treatment and a dye that is not affected by esterase treatment, and after dyeing or printing the material, discharging residual dye by treating the material with an esterase.
    • 本发明涉及通过用酯酶处理染色或印刷的材料来从染色和/或印刷材料例如用分散染料染色的纺织材料中除去多余染料的方法和组合物。 由本发明形成的改进包括例如染色和/或印刷材料的耐洗色牢度,耐湿牢度,耐压性,升华度和/或颜色质量(如亮度)的改善。 本发明还涉及通过用受酯酶处理影响的染料和不受酯酶处理影响的染料的组合染色或印刷材料并在染色或印刷材料之后对材料进行印染或染色的方法, 通过用酯酶处理材料排出残留染料。
    • 104. 发明授权
    • Textile manufacturing and treating processes comprising a hydrophobically modified polymer
    • 包含疏水改性聚合物的纺织品制造和处理方法
    • US06337313B1
    • 2002-01-08
    • US09441714
    • 1999-11-16
    • Klein A. Rodrigues
    • Klein A. Rodrigues
    • C11D337
    • D06P5/158D06L1/14D06L4/12D06M11/40D06M15/03D06M15/09D06M15/227D06M15/233D06M15/263D06M15/27D06M15/285D06M15/333D06M15/353D06M15/3562D06M15/3566D06M15/53D06P1/16D06P1/228D06P1/48D06P1/50D06P1/5207D06P1/5221D06P1/5228D06P1/5242D06P1/525D06P1/5257D06P1/613D06P5/08
    • A method to prevent the backstaining of denim during a stonewashing process comprising treating the denim with a solution or dispersion of a hydrophobically modified polymer having a hydrophilic backbone and at least one hydrophobic moiety, wherein said hydrophilic backbone is prepared from at least one monomer selected from the group consisting of ethylenically unsaturated hydrophilic monomer selected from the group consisting of unsaturated C1-C6 acid, amide, ether, alcohol, aldehyde, anhydride, ketone and ester; polymerizable hydrophilic cyclic monomer; non-ethylenically unsaturated polymerizable hydrophilic monomer which is selected from the group consisting of glycerol and other polyhydric alcohols; and combinations thereof, wherein said hydrophilic backbone is optionally substituted with one or more amino, amine, amide, sulfonate, sulfate, phosphonate, hydroxy, carboxyl or oxide groups; wherein said hydrophobic moiety is prepared from at least one hydrophobic monomer or a chain transfer agent, said hydrophobic monomer is selected from the group consisting of a siloxane, saturated or unsaturated alkyl and hydrophobic alkoxygroup, aryl and aryl-alkyl group, alkyl sulfonate, aryl sulfonate, and combinations thereof, and said chain transfer agent has 1 to 24 carbon atoms and is selected from the group consisting of a mercaptan, amine, alcohol, and combinations thereof, wherein said hydrophobically modified polymer is present in an amount of from 0.001 to 50 weight percent, based on the total weight of the solution or dispersion.
    • 一种防止在石洗过程中对牛仔布进行背面染色的方法,包括用具有亲水主链和至少一个疏水部分的疏水改性聚合物的溶液或分散体处理牛仔布,其中所述亲水性主链由至少一种选自 由不饱和C 1 -C 6酸,酰胺,醚,醇,醛,酸酐,酮和酯组成的组中的烯属不饱和亲水单体组成的组; 可聚合的亲水环状单体; 非烯属不饱和可聚合亲水单体,其选自甘油和其他多元醇; 其中所述亲水性骨架任选被一个或多个氨基,胺,酰胺,磺酸盐,硫酸盐,膦酸盐,羟基,羧基或氧化物基团取代; 其中所述疏水部分由至少一种疏水性单体或链转移剂制备,所述疏水性单体选自硅氧烷,饱和或不饱和的烷基和疏水性烷氧基,芳基和芳基 - 烷基,烷基磺酸酯,芳基 磺酸盐及其组合,所述链转移剂具有1至24个碳原子,并且选自硫醇,胺,醇及其组合,其中所述疏水改性聚合物的存在量为0.001至 50重量%,基于溶液或分散体的总重量。
    • 110. 发明授权
    • Dyeing and monomer polymerization in protein fiber with metal catalyst and trichloroacetic acid or salt thereof
    • 用金属催化剂和三氯乙酸或其盐在蛋白纤维中染色和单体聚合
    • US3927961A
    • 1975-12-23
    • US26939872
    • 1972-07-06
    • WOOL RES ORGANISATION
    • SIMPSON WILLIAM STANLEY
    • D06M14/06D06P1/16D06P1/39D06P3/04D06P3/14D06P5/00
    • D06P3/145D06M14/06D06P1/16D06P1/39D06P3/04D06P3/047Y10S8/917
    • This invention provides a combined dyeing and polymer deposition process for protein fibres. The fibres are treated in a liquid containing a dye, a polymerisable olefinic monomer and a catalyst in the form of a complex of copper, iron, chromium, manganese, vanadium, cobalt, nickel and aluminium together with a trihaloacetic acid or a salt or ester thereof. Other substances which can form trihalomethyl ions or free radicals in the presence of the complex can also be used. The combined catalyst of metal complex and trihaloacetic acid enables polymerisation of the monomer to be carried out in the presence of air and also permits formation of the polymer within the fibre substance rather than at the surface or in the liquid. The dye may be an acid, premetallised or reactive dye and is usually applied simultaneously with the polymer, for example by heating the fibres in an aqueous solution containing the reacting materials gradually from room temperature up to a temperature in the range 50* to 100*C and maintaining them at that temperature for between 30 minutes and 2 hours. The invention enables wool to be coloured and to have its physical and mechanical properties altered by polymer deposition in a single operation in a single bath, as well as ensuring that as much as possible of the polymer forms within the substance of the fibres.
    • 本发明提供蛋白质纤维的组合染色和聚合物沉积方法。 纤维在含有染料,可聚合的烯属单体和铜,铁,铬,锰,钒,钴,镍和铝的复合物形式的催化剂以及三卤乙酸或盐或酯的液体中处理 其中。 也可以使用在复合物存在下可形成三卤甲基离子或自由基的其它物质。 金属络合物和三卤代乙酸的组合催化剂可以在空气存在下聚合单体,并且还允许在纤维物质内形成聚合物,而不是在表面或液体中形成。 染料可以是酸,预金属化或活性染料,并且通常与聚合物同时施加,例如通过将含有反应材料的水溶液中的纤维从室温逐渐加热至50℃至100℃的温度来进行。 并在该温度下保持30分钟至2小时。 本发明使得羊毛可以被着色并且在单个浴中在单次操作中通过聚合物沉积改变其物理和机械性能,并且确保尽可能多地在纤维物质内形成聚合物形式。