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    • 101. 发明授权
    • Polyester-based resin composition and shaped articles
    • 聚酯类树脂组合物和成型制品
    • US06733853B2
    • 2004-05-11
    • US10081217
    • 2002-02-25
    • Masahiko TakashimaKoji YamamotoHiroyuki Nanba
    • Masahiko TakashimaKoji YamamotoHiroyuki Nanba
    • C08L7700
    • C08L67/02Y10T428/1352Y10T428/31725Y10T428/31739C08L77/00
    • The polyester-based resin composition of the present invention comprises a melt blend (C) consisting of a polyamide resin (A) and a polyester resin (B). The polyester-based resin composition satisfies the following formulas 1 and 2: P×C/100≦25  (1) Y/X×100≧90  (2) wherein P is a concentration, ppm, of a phosphorus compound in the polyamide resin (A) in terms of phosphorus atom; C is a content, % by mass, of the polyamide resin (A) in the melt blend (C); X is a lightness of a 2-mm thick plate which is molded only from the polyester resin (B); and Y is a lightness of a 2-mm thick plate which is molded from the melt blend (C). By regulating the phosphorus concentration and the polyamide resin (A) content so as to meet the limitation of formula 1, the polyester-based resin composition and a shaped article or packaging container made thereof are effectively prevented from the darkening due to the deposition of antimony metal despite the blending of a polyamide resin, thereby attaining a high clearness as defined by formula 2.
    • 本发明的聚酯类树脂组合物包含由聚酰胺树脂(A)和聚酯树脂(B)组成的熔融共混物(C)。 聚酯类树脂组合物满足下式1和2:其中P是聚磷酰胺树脂(A)中磷化合物的磷原子浓度,ppm; C是熔融共混物(C)中的聚酰胺树脂(A)的含量%质量%。 X是仅由聚酯树脂(B)成型的2mm厚的板的亮度; Y是由熔融共混物(C)成型的2mm厚的板的亮度。 通过调节磷浓度和聚酰胺树脂(A)含量以满足式1的限制,可以有效地防止聚酯类树脂组合物及其制成的成型制品或包装容器由于沉积锑而变黑 尽管混合了聚酰胺树脂,从而获得如式2所定义的高清晰度。
    • 105. 发明授权
    • Polyester resin and molded article
    • 聚酯树脂和成型品
    • US06447859B2
    • 2002-09-10
    • US09879100
    • 2001-06-13
    • Dai OguroKoji YamamotoTakeo HayashiTakeshi HirokaneMasahiro Kurokawa
    • Dai OguroKoji YamamotoTakeo HayashiTakeshi HirokaneMasahiro Kurokawa
    • B29D2200
    • C08J9/141C08G63/672C08J2201/03C08J2367/02Y10T428/1352Y10T428/1376Y10T428/24
    • The polyester resin of the present invention is produced by polymerizing a monomer mixture comprising a glycol component containing 5 to 60 mol % of a spiroglycol represented by Formula I: and 30 to 95 mol % of ethylene glycol, and a dicarboxylic acid component containing 80 to 100 mol % of terephthalic acid and/or an ester thereof. The polyester resin has (1): an intrinsic viscosity of 0.4 to 1.5 dL/g, (2) a melt viscosity of 700 to 5,000 Pa·s, (3) a molecular weight distribution of 2.5 to 12.0; and (4) a glass transition temperature of 90° C. or higher and a cooling crystallization exotherm peak of 5 J/g or lower. The polyester resin of the present invention is excellent in heat resistance, transparency, mechanical properties, moldability and fabrication qualities and useful for producing shaped articles such as films, sheets, hollow containers and foamed products.
    • 本发明的聚酯树脂通过使包含含有5〜60摩尔%的式I所示的螺旋糖的二醇成分和30〜95摩尔%的乙二醇的二醇成分和含有80〜 100摩尔%的对苯二甲酸和/或其酯。 聚酯树脂具有(1):特性粘度为0.4〜1.5dL / g,(2)熔融粘度为700〜5000Pa·s,(3)分子量分布为2.5〜12.0; 和(4)玻璃化转变温度为90℃以上,冷却结晶放热峰为5J / g以下。 本发明的聚酯树脂的耐热性,透明性,机械性能,成型性和制造性能优异,可用于制造薄膜,片材,中空容器和发泡产品等成型制品。
    • 106. 发明授权
    • Resin composition for extruded forms
    • 用于挤出形式的树脂组合物
    • US06399683B1
    • 2002-06-04
    • US08967103
    • 1997-11-10
    • Koji YamamotoHajime IkenoKeiko Shichijo
    • Koji YamamotoHajime IkenoKeiko Shichijo
    • C08L2308
    • C08L23/0815C08L23/06C08L2205/02C08L2310/00C08L2314/02C08L2666/06C08L2666/02
    • A resin composition for extruded forms that has improved workability, and excellent properties with respect to transparency, heat resistance, low-temperature resistance, etc. The composition contains 50 to 99% by weight of component A, which is a copolymer of ethylene and &agr;-olefin, and 1 to 50% by weight of component B, which is an ethylene-containing polymer. The component A has: (a) a melt flow rate (MFR) of 0.1 to 5 g/10 min.; (b) a density D of 0.88 to 0.925 g/cm3; (c) a single peak of elution volume indicated by an elution curve obtained by temperature rising elution fractionation (TREF), the peak corresponding to a temperature within a range of from 30 to 100®, and the elution curve satisfying a relationship in which the ratio H/W is not less than 1 when H represents the height of the peak and W represents the width of the elution curve at half of the height H; and (d) an elution volume Y (in % of the weight thereof with respect to the total weight of the component A) at an elution temperature of 50C in TREF, the elution volume Y satisfying the following condition: {circle around (1)} Y≦−4500D+4105 when the density D of the component A is less than 0.91 g/cm3, but Y≦100; or {circle around (2)} Y≦10 when the density D of the component A is not less than 0.91 g/cm3. The component B has: (a′) a melt flow rate of 0.1 to 20 g/10 min.; (b′) a density of 0.88 to 0.93 g/cm3; (c′) a memory effect (ME) of not less than 1.3; and (d′) a melt tension (MT) of not less than 1.0 g.
    • 用于挤出形式的树脂组合物,其具有改进的加工性,并且在透明性,耐热性,耐低温性等方面具有优异的性能。该组合物含有50至99重量%的组分A,其是乙烯和α的共聚物 和1〜50重量%的作为含乙烯的聚合物的组分B。 组分A具有:(a)熔体流动速率(MFR)为0.1至5g / 10min。 (b)密度D为0.88-0.925g / cm3; (c)通过升温洗脱分级(TREF)获得的洗脱曲线所指示的洗脱体积的单峰,对应于30〜100(R)范围内的温度的峰,以及满足关系的洗脱曲线 当H表示峰的高度时,H / W的比率不小于1,W表示高度H的一半处的洗脱曲线的宽度; 和(d)在TREF中洗脱温度为50℃的洗脱体积Y(其相对于组分A的总重量的重量%),洗脱体积Y满足以下条件:{圆周(1) 当组分A的密度D小于0.91g / cm 3,但Y <= 100时,Y <= - 4500D + 4105; 或组分A的密度D为0.91g / cm 3以上的{圈(2)} Y <= 10。 组分B具有:(a')熔体流动速率为0.1至20g / 10min。 (b')密度为0.88〜0.93g / cm 3; (c')记忆效应(ME)不小于1.3; 和(d')不小于1.0g的熔体张力(MT)。
    • 107. 发明授权
    • Image forming apparatus provided with a plurality of image holding components
    • 具有多个图像保持部件的图像形成装置
    • US06192207B1
    • 2001-02-20
    • US09082011
    • 1998-05-20
    • Koji YamamotoTetsuya Onuki
    • Koji YamamotoTetsuya Onuki
    • G03G1500
    • G03G15/01G03G15/0194G03G2215/0119
    • An image forming apparatus is provided with a plurality of image forming units along a transportation path of a recording sheet transported by a revolving transport belt, each image forming unit including an image holding component. The image forming apparatus is further provided with a transport belt moving unit for moving the transport belt between a first state and a second state by changing a form of a revolution of the transport belt, the first state being where the transport belt does not touch at least one of the image holding components and the second state being where the transport belt touches the image holding components not touched in the first state.
    • 图像形成装置沿着由旋转传送带传送的记录纸的传送路径设置有多个图像形成单元,每个图像形成单元包括图像保持部件。 图像形成装置还设置有传送带移动单元,用于通过改变传送带的旋转形式来在第一状态和第二状态之间移动传送带,第一状态是传送带不接触的第一状态 图像保持部件中的至少一个和第二状态是传送带在第一状态下接触未被接触的图像保持部件的位置。
    • 110. 发明授权
    • Resin composition for laminates
    • 层压板用树脂组合物
    • US5741861A
    • 1998-04-21
    • US409957
    • 1995-03-23
    • Koji YamamotoHajime IkenoKeiko Shichijo
    • Koji YamamotoHajime IkenoKeiko Shichijo
    • B32B7/04B32B27/32C08L23/06C08L23/08C08L23/16C08L23/04
    • B32B27/32B32B7/04C08L23/0815C08L2205/02C08L23/06
    • A resin composition containing 50 to 99% by weight of component A, which is a copolymer of ethylene and .alpha.-olefin, and 1 to 50% by weight of component B, which is a high-pressure low-density polyethylene. The component A has (a) a melt flow rate (MFR) of 2 to 30 g/10 min., (b) a density of not more than 0.935 g/cm.sup.3, and (c) a single peak of elution volume indicated by an elution curve obtained by temperature rising elution fractionation, the peak corresponding to a temperature within a range of from 20.degree. C. to 85.degree. C., and the elution curve satisfying a relationship in which the ratio H/W is not less than 1 when H represents the height of the peak and W represents the width of the elution curve at half of the height H. The component B has (a') a melt flow rate of 0.1 to 20 g/10 min., (b') a density of 0.915 to 0.93 g/cm.sup.3, ('c) a memory effect (ME) of not less than 1.6, and (d') a melt tension (MT) of not less than 1.5 g. The resin composition is advantageously usable as a laminate material having improved workability, and excellent properties with respect to low-temperature heat sealability, heat sealing strength and hot tack.
    • 含有50〜99重量%的作为乙烯与α-烯烃的共聚物的成分A和1〜50重量%作为高压低密度聚乙烯的成分B的树脂组合物。 组分A具有(a)2至30g / 10min的熔体流动速率(MFR),(b)不大于0.935g / cm 3的密度,和(c)由 通过升温洗脱分级获得的洗脱曲线,峰值对应于20℃至85℃的温度,并且满足H / W比不小于1的关系的洗脱曲线 当H表示峰的高度,W表示高度H的一半处的洗脱曲线的宽度。组分B具有(a')熔体流动速率为0.1至20g / 10min。(b') 密度为0.915至0.93g / cm 3,(c)记忆效应(ME)不小于1.6,(d')熔体张力(MT)不小于1.5g。 树脂组合物有利地可用作具有改善的加工性的层压材料,并且在低温热封性,热封强度和热粘性方面具有优异的性能。