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101. 发明授权

US08206575B2 Hydroconversion processes employing multi-metallic catalysts and method for making thereof 有权
标题翻译：采用多金属催化剂的加氢转化方法及其制备方法
公开(公告)号：US08206575B2
公开(公告)日：2012-06-26
申请号：US12259435
申请日：2008-10-28
申请人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman
发明人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman
IPC分类号： C10G11/04 , C10G25/00 , C10G45/00
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A process for upgrading a hydrocarbon feedstock by hydroprocessing using multi-metallic catalysts is disclosed. In one aspect, the invention relates to hydroprocessing of a hydrocarbon feedstock using a catalyst derived from a catalyst precursor of the formula Av[(MP)(OH)x(L)ny]z(MVIBO4), wherein A comprises an alkali metal cation, an ammonium, an organic ammonium or a phosphonium cation, MP is selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, L is an organic, oxygen-containing ligand, MVIB is at least one of Group VIB metals, and the atomic ratio of MVIII:MVIB is between 100:1 and 1:100.
摘要翻译：公开了一种通过使用多金属催化剂的加氢处理来升级烃原料的方法。一方面，本发明涉及使用衍生自式Av [（MP）（OH）x（L）ny] z（MVIBO4）的催化剂前体的催化剂加氢处理烃原料，其中A包含碱金属阳离子，铵，有机铵或鏻阳离子，MP选自VIII族，IIB族，IIA族，IVA族及其组合，L为有机含氧配体，MVIB为VIB族金属中的至少一种，MVIII：MVIB的原子比在100:1和1:100之间。

102. 发明申请

US20120039777A1 PROCESS FOR SEPARATING AND RECOVERING METALS 有权
标题翻译：分离和回收金属的方法
公开(公告)号：US20120039777A1
公开(公告)日：2012-02-16
申请号：US13156589
申请日：2011-06-09
申请人： Rahul Shankar Bhaduri , Louis Joseph Nordrum , Alexander E. Kuperman
发明人： Rahul Shankar Bhaduri , Louis Joseph Nordrum , Alexander E. Kuperman
IPC分类号： C22B34/30
CPC分类号： C22B34/345 , C22B7/009 , C22B23/026 , C22B23/0446 , C22B34/225 , Y02P10/214 , Y02P10/224 , Y02P10/23 , Y02P10/234
摘要： A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals.
摘要翻译：提供了一种处理含有重金属的废催化剂的方法，例如VIB族金属和VIII族金属。在脱油后的一个实施方案中，在足以将VIB族金属和VIII族金属溶解到浸出溶液中的条件下，用氨浸出溶液处理废催化剂，形成浸出浆料。在固液分离回收浸出溶液后，进行化学沉淀和固体再浆化，得到含有硫酸铵（Amsul），氨基磺酸铵，VB族，VIB族和VIII族金属的流出物流。硫化后，完全除去第Ⅷ族金属，并从Amsul流部分除去VB族和VI族金属。在氧解溶解和铁沉淀的附加步骤中，加入预选择pH下的有效量的铁离子以与VB族和VIB族金属组合形成不溶性络合物，其在液固分离时产生流出的硫酸铵流，其含有 VB族和VIB族金属中的每一种都少于10ppm。

103. 发明申请

US20110124498A1 Hydroprocessing Bulk Catalyst and Methods of Making Thereof 有权
公开(公告)号：US20110124498A1
公开(公告)日：2011-05-26
申请号：US12625399
申请日：2009-11-24
申请人： Alexander E. Kuperman , Oleg Mironov , Jinyi Han
发明人： Alexander E. Kuperman , Oleg Mironov , Jinyi Han
IPC分类号： B01J27/049 , B01J27/02 , B01J27/043
CPC分类号： B01J37/20 , B01J23/80 , B01J37/031 , B01J37/04 , C10G49/02 , C10G2300/4037
摘要： A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (Rp)i(Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least at least a “d” block element metal; L is also at least a “d” block element metal, but different from M; t, u, v, w, x, y, z representing the total charge for each of the components (M, L, S, C, H, O and N, respectively); R is optional and in one embodiment, R is a lanthanoid element metal; 0

104. 发明申请

US20100234212A1 HYDROPROCESSING BULK CATALYST AND USES THEREOF 有权
标题翻译：氢化聚合物催化剂及其用途
公开(公告)号：US20100234212A1
公开(公告)日：2010-09-16
申请号：US12787855
申请日：2010-05-26
申请人： Axel Brait , Alexander E. Kuperman , Jaime Lopez , Oleg Mironov , Bruce Reynolds , Kaidong Chen
发明人： Axel Brait , Alexander E. Kuperman , Jaime Lopez , Oleg Mironov , Bruce Reynolds , Kaidong Chen
IPC分类号： B01J31/02
CPC分类号： C10G47/04 , B01J23/24 , B01J23/28 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/8885 , B01J27/0515 , B01J35/002 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1042 , B01J35/1047 , B01J37/0236 , B01J37/031 , B01J37/038 , B01J37/04 , B01J37/16 , B01J37/20 , B01J37/343 , C10G47/06 , C10G49/04 , C10G2300/107 , C10G2300/1077 , Y10S502/517
摘要： A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h,, wherein M is at least one group VIII metal; promoter metal L is optional and if present, L is at least one Group VIII non-noble metal; t, u, v, w, x, y, z representing the total charge for each of the components (M, L, S, C, H, O and N, respectively); ta+ub+vd+we+xf+yg+zh=0; 0=
摘要翻译：提供加氢处理体积催化剂。还提供了制备加氢处理大量催化剂的方法。加氢处理催化剂具有式（Mt）a（Lu）b（Sv）d（Cw）e（Hx）f（Oy）g（Nz）h ,,其中M是至少一种VIII族金属; 促进剂金属L是任选的，如果存在，L是至少一种第VIII族非贵金属; 表示各组分（M，L，S，C，H，O和N分别）的总电荷的t，u，v，w，x，y，z; ta + ub + vd + we + xf + yg + zh = 0; 0 =

105. 发明申请

US20100200811A1 Method for Making Hydrogen Using a Gold Containing Water-Gas Shift Catalyst 有权
标题翻译：使用含金水换气催化剂制氢的方法
公开(公告)号：US20100200811A1
公开(公告)日：2010-08-12
申请号：US12701057
申请日：2010-02-05
申请人： Alexander E. Kuperman , Michael E. Moir
发明人： Alexander E. Kuperman , Michael E. Moir
IPC分类号： C01B3/16 , C01B31/20
CPC分类号： B01J35/10 , B01J21/066 , B01J23/48 , B01J23/72 , B01J27/053 , B01J27/055 , B01J35/002 , B01J35/0066 , B01J35/1014 , B01J35/1019 , B01J37/0201 , B01J37/0207 , B01J37/0236 , B01J37/031 , C01B3/16 , C01B3/583 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/1041 , C01B2203/1082 , C01B2203/1609 , H01M8/0612 , Y02P20/52 , Y02P70/56
摘要： The present invention relates to a method for oxidizing CO, comprising: passing a first feed comprising CO and a second feed comprising oxygen, in an oxidation zone, over a catalyst comprising highly dispersed gold on sulfated zirconia, at oxidation conditions, to produce an effluent comprising a lower level of CO than in the first feed.
摘要翻译：本发明涉及一种氧化CO的方法，包括：在氧化条件下使包含CO的第一种进料和包含氧的第二种进料在氧化区中，在包含高度分散的金的催化剂上，在氧化条件下，在硫酸化氧化锆上通过，以产生流出物包括比第一进料中低的CO浓度。

106. 发明授权

US07754645B2 Process for preparing hydroprocessing bulk catalysts 有权
标题翻译：加氢处理本体催化剂的制备方法
公开(公告)号：US07754645B2
公开(公告)日：2010-07-13
申请号：US11933085
申请日：2007-10-31
申请人： Alexander E. Kuperman , Jaime Lopez , Oleg Mironov , Axel Brait
发明人： Alexander E. Kuperman , Jaime Lopez , Oleg Mironov , Axel Brait
IPC分类号： B01J21/00 , B01J31/00 , B01J27/24 , B01J27/04
CPC分类号： C10G49/12 , B01J27/049 , B01J27/0515 , B01J37/20 , C07F11/005 , C07F15/045 , C10G45/04 , C10G45/08 , C10G45/16 , C10G47/26 , C10G49/02 , C10G49/04 , C10G2300/1003 , C10G2300/1022 , C10G2300/1033 , C10G2300/1074 , C10G2300/207 , C10G2300/703 , Y10S502/517 , Y10T428/2982
摘要： A process to prepare hydroprocessing bulk catalysts is provided. The hydroprocessing catalyst has the formula (Mt)a(Xu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least one group VIB metal; X is at least at least a metal compound selected from a non-noble Group VIII metal, a Group VIIIB metal, a Group VIB metal, a Group IVB metal, and a Group IIB metal (“Promoter Metal”); t, u, v, w, x, y, z representing the total charge for each of the components (M, X, S, C, H, O and N, respectively); ta+ub+vd+we+xf+yg+zh=0; and 0=
摘要翻译：提供了一种制备加氢处理大量催化剂的方法。加氢处理催化剂具有式（Mt）a（Xu）b（Sv）d（Cw）e（Hx）f（Oy）g（Nz）h，其中M为至少一种VIB族金属; X至少是选自非贵金属VIII族金属，VIIIB族金属，VIB族金属，IVB族金属和IIB族金属（“促进剂金属”）中的至少一种金属化合物。表示各组分（M，X，S，C，H，O和N分别）的总电荷的t，u，v，w，x，y，z; ta + ub + vd + we + xf + yg + zh = 0; 并且0 =

107. 发明授权

US07737072B2 Hydroprocessing bulk catalyst and uses thereof 有权
标题翻译：加氢处理本体催化剂及其用途
公开(公告)号：US07737072B2
公开(公告)日：2010-06-15
申请号：US11931972
申请日：2007-10-31
申请人： Oleg Mironov , Alexander E. Kuperman , Jaime Lopez , Axel Brait , Bruce Reynolds , Kaidong Chen
发明人： Oleg Mironov , Alexander E. Kuperman , Jaime Lopez , Axel Brait , Bruce Reynolds , Kaidong Chen
IPC分类号： B01J21/00 , B01J31/00 , B01J27/24 , B01J27/04
CPC分类号： B01J27/049 , B01J27/0515 , B01J35/002 , B01J35/023 , B01J37/03 , B01J37/20 , C10G45/04 , C10G45/08 , C10G45/50 , C10G49/02 , C10G49/04 , Y10S502/517
摘要： A hydroprocessing catalyst is provided. The hydroprocessing catalyst has the formula (Mt)a(Xu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least one group VIB metal; X is at least one Group VIII non-noble metal; t, u, v, w, x, y, z representing the total charge for each of the components (M, X, S, C, H, O and N, respectively); ta+ub+vd+we+xf+yg+zh=0; and 0=
摘要翻译：提供加氢处理催化剂。加氢处理催化剂具有式（Mt）a（Xu）b（Sv）d（Cw）e（Hx）f（Oy）g（Nz）h，其中M为至少一种VIB族金属; X是至少一种第VIII族非贵金属; 表示各组分（M，X，S，C，H，O和N分别）的总电荷的t，u，v，w，x，y，z; ta + ub + vd + we + xf + yg + zh = 0; 并且0 =

108. 发明授权

US07678730B2 Hydroprocessing bulk catalyst and uses thereof 有权
标题翻译：加氢处理本体催化剂及其用途
公开(公告)号：US07678730B2
公开(公告)日：2010-03-16
申请号：US12260668
申请日：2008-10-29
申请人： Oleg Mironov , Alexander E. Kuperman
发明人： Oleg Mironov , Alexander E. Kuperman
IPC分类号： B01J21/00 , B01J27/24 , B01J27/04
CPC分类号： C10G49/12 , B01J23/002 , B01J23/85 , B01J27/051 , B01J27/0515 , B01J35/023 , B01J37/0018 , B01J37/20 , B01J2523/00 , C10G45/04 , C10G45/08 , C10G45/16 , C10G49/02 , C10G49/04 , Y10S502/517 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least one group VIB metal; L is optional and if present, L is at least one Group VIII non-noble metal; t, u, v, w, x, y, z representing the total charge for each of the components (M, L, S, C, H, O and N, respectively); ta+ub+vd+we+xf+yg+zh=0; 0=
摘要翻译：提供加氢处理体积催化剂。还提供了制备加氢处理大量催化剂的方法。加氢处理催化剂具有式（Mt）a（Lu）b（Sv）d（Cw）e（Hx）f（Oy）g（Nz）h，其中M是至少一种VIB族金属; L是任选的，如果存在，L是至少一种第VIII族非贵金属; 表示各组分（M，L，S，C，H，O和N分别）的总电荷的t，u，v，w，x，y，z; ta + ub + vd + we + xf + yg + zh = 0; 0 =

109. 发明申请

US20090218062A1 PROCESS FOR GENERATING A HYDROCARBON FEEDSTOCK FROM LIGNIN 有权
公开(公告)号：US20090218062A1
公开(公告)日：2009-09-03
申请号：US12039374
申请日：2008-02-28
申请人： William Lawrence Schinski , Alexander E. Kuperman , Jinyi Han , Douglas Gene Naae
发明人： William Lawrence Schinski , Alexander E. Kuperman , Jinyi Han , Douglas Gene Naae
IPC分类号： D21F1/66
CPC分类号： D21C11/0007 , C10G1/06 , C10G3/44 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1074 , C10L1/02 , Y02P30/20
摘要： The present invention discloses processes for generating a hydrocarbon feedstock for biofuels synthesis from lignin via hydroprocessing. Embodiments of the present invention can occur in a refinery setting or in a paper mill setting. Embodiments of the present invention can utilize the separated lignin or the entire black liquor solution.

110. 发明申请

US20090114566A1 METHOD OF UPGRADING HEAVY HYDROCARBON STREAMS TO JET PRODUCTS 审中-公开
标题翻译：将重型油气井提升到喷射产品的方法
公开(公告)号：US20090114566A1
公开(公告)日：2009-05-07
申请号：US12260877
申请日：2008-10-29
申请人： Cong-Yan Chen , Alexander E. Kuperman
发明人： Cong-Yan Chen , Alexander E. Kuperman
IPC分类号： C10G47/02
CPC分类号： C10G49/002 , C10G45/04 , C10G45/46 , C10G45/60 , C10G49/02 , C10G2400/08
摘要： A process of upgrading a heavy hydrocarbon feedstock comprising contacting a heavy hydrocarbon feedstock with a catalyst in the presence of hydrogen in a reactor system, containing the catalyst as the only catalyst, wherein the catalyst, is prepared by sulfiding a catalyst precursor obtained by mixing at reaction conditions, to form a precipitate or cogel, at least a Promoter metal compound in solution; at least a Group VIB metal compound in solution; and, at least an organic oxygen containing ligand in solution, and thereby producing a fuel product.
摘要翻译：一种升级重质烃原料的方法，包括在氢气存在下使重烃原料与催化剂在反应器系统中接触，反应器系统含有催化剂作为唯一的催化剂，其中催化剂是通过将通过混合获得的催化剂前体硫化反应条件，以形成沉淀或共凝胶，至少在溶液中的促进剂金属化合物; 溶液中至少含有VIB族金属化合物; 和在溶液中至少含有机氧的配体，从而生产燃料产物。

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