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91. 发明授权

US6127432A Processes for preparing oxygenates and catalysts therefor 失效
标题翻译：制备含氧化合物及其催化剂的方法
公开(公告)号：US6127432A
公开(公告)日：2000-10-03
申请号：US220438
申请日：1998-12-24
申请人： Richard William Wegman , David Michael Minahan , William J. Bartley , Chinsoo Stephen Lee , David McNeill Somerville
发明人： Richard William Wegman , David Michael Minahan , William J. Bartley , Chinsoo Stephen Lee , David McNeill Somerville
IPC分类号： B01J27/185 , B01J23/652 , B01J27/188 , C07B61/00 , C07C29/151 , C07C29/153 , C07C51/12 , C07C53/08 , C07C53/122 , C07C53/124 , C07C67/36 , C07C67/37 , C07C69/14 , C07C69/24 , C07C27/00 , C07C27/06 , C07C27/22 , C07C51/16
CPC分类号： C07C29/1512 , C07C29/153 , C07C51/12 , C07C67/36 , C07C67/37 , C12C11/02 , Y02P20/52 , Y02P20/582
摘要： This invention relates in part to a processes and catalysts for the conversion of a feedstock comprising carbon monoxide and hydrogen to a product stream comprising at least one of an ester, acid, acid anhydride and mixtures thereof. This invention also relates in part to processes and catalysts for converting an alcohol, ether and/or ether alcohol feedstock to oxygenated products, e.g., esters, acids, acid anhydrides and mixtures thereof. The processes and catalysts are especially suitable for the production of acetic acid and methyl acetate from a synthesis gas feedstock or from an alcohol, ether or ether alcohol feedstock.
摘要翻译：本发明部分地涉及用于将包含一氧化碳和氢的原料转化为包含酯，酸，酸酐及其混合物中的至少一种的产物流的方法和催化剂。本发明还部分涉及用于将醇，醚和/或醚醇原料转化为氧化产物，例如酯，酸，酸酐及其混合物的方法和催化剂。该方法和催化剂特别适用于从合成气原料或醇，醚或醚醇原料生产乙酸和乙酸甲酯。

92. 发明授权

US4681708A Process for converting an alkoxyalkadiene to an alkyl dialkoxyalkanoate 失效
标题翻译：将烷氧基烷烃转化成烷基二烷氧基烷酸酯的方法
公开(公告)号：US4681708A
公开(公告)日：1987-07-21
申请号：US914906
申请日：1986-10-03
申请人： Biau-Hung Chang
发明人： Biau-Hung Chang
IPC分类号： C07C65/38 , C07C67/37 , C07C67/38
CPC分类号： C07C65/38
摘要： A process for converting an alkoxyalkadiene to an alkyl dialkoxyalkanoate is disclosed. The process involves contacting an alkoxyalkadiene with carbon monoxide and an alkanol in the presence of a catalytically effective amount of a cobalt catalyst.
摘要翻译：公开了一种将烷氧基烷烃转化为烷基二烷氧基烷酸酯的方法。该方法包括在催化有效量的钴催化剂存在下使烷氧基烷烃与一氧化碳和链烷醇接触。

93. 发明授权

US4611082A Production of hex-3-enedioate esters from 1,4 dialkoxy butenes 失效
标题翻译：从1,4-二烷氧基丁烯生产己-3-烯酸酯
公开(公告)号：US4611082A
公开(公告)日：1986-09-09
申请号：US669720
申请日：1984-11-09
申请人： Albert S. C. Chan , Donald E. Morris
发明人： Albert S. C. Chan , Donald E. Morris
IPC分类号： C07C67/37
CPC分类号： C07C67/37
摘要： The dicarbonylation product of 1,4-dialkoxy substituted-2-butene is useful as intermediate in the production of adipic acid, hexamethylenediamine and 1,6-hexanediol. It is produced by carbonylating a solution of the dialkoxy substituted butene in a polar, aprotic non-basic solvent at 80.degree.-140.degree. C. in the presence of a catalyst comprising a halide of the transition metal.
摘要翻译： 1,4-二烷氧基取代-2-丁烯的二羰基化产物可用作己二酸，六亚甲基二胺和1,6-己二醇生产中的中间体。在含有过渡金属卤化物的催化剂的存在下，在极性非质子非碱性溶剂中，在80-140℃下将二烷氧基取代丁烯的溶液羰基化。

94. 发明授权

US4336399A Process for producing carboxylic acids and/or esters thereof 失效
标题翻译：制备羧酸和/或其酯的方法
公开(公告)号：US4336399A
公开(公告)日：1982-06-22
申请号：US205591
申请日：1980-11-10
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
IPC分类号： C07C67/37 , B01J23/00 , B01J27/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C51/00 , C07C51/12 , C07C51/56 , C07C53/00 , C07C67/00 , C07C69/00 , C07C67/36 , C07C69/76
CPC分类号： C07C51/12 , C07C51/56 , C07C67/36 , C07C67/37
摘要： A process for producing a carboxylic acid and/or its ester, which comprises reacting an alcohol or ether with carbon monoxide in the presence of elemental nickel or a nickel compound, iodine or an iodine compound and an organic compound of a trivalent nitrogen-group element; wherein the iodine or iodine compound is selected from the following formulae (I) to (IV),RX.sub.n (I)wherein R represents a hydrogen atom or an alkyl or alkylene group, X represents an iodine or bromine atom, and n is an integer of 1 to 3, at least one of n.multidot.X's being an iodine atom,I.sub.2 or I.sub.3 - (II)RCOI (III)wherein R represents an alkyl group,MI.sub.2 (IV)wherein M represents an alkaline earth metal, and the amount of the iodine or iodine compound is such that the amount of the free iodine or iodine compound not chemically bonded to the nickel or nickel compound or the organic compound of a nitrogen-group element is at least 0.2 mole as elemental iodine per mole of each of the nitrogen-group element compound and the nickel or nickel compound.
摘要翻译：一种制备羧酸和/或其酯的方法，其包括在元素镍或镍化合物，碘或碘化合物和三价氮基元素的有机化合物存在下使醇或醚与一氧化碳反应 ; 其中所述碘或碘化合物选自下式（I）至（IV），其中R表示氢原子或烷基或亚烷基的RXn（I），X表示碘或溴原子，n为整数为1〜3，nxX为碘原子中的至少1种，I 2 - 或I 3 - （II）RCOI（III），其中R为烷基，MI2（Ⅳ）其中M为碱土金属，碘或碘化合物使得未化学键合到镍或镍化合物或氮基元素的有机化合物的游离碘或碘化合物的量为每摩尔氮中的元素碘至少0.2摩尔 - 元素化合物和镍或镍化合物。

95. 发明授权

US4212989A Process for producing carboxylic acids or esters thereof 失效
标题翻译：制备羧酸或其酯的方法
公开(公告)号：US4212989A
公开(公告)日：1980-07-15
申请号：US955411
申请日：1978-10-26
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
IPC分类号： C07C67/37 , C07C51/00 , C07C51/12 , C07C67/00 , C07C67/36 , C07C69/157
CPC分类号： C07C51/12
摘要： In a process for producing a carboxylic acid or its ester by reacting an alcohol or an ether with carbon monoxide, the improvement wherein the reaction is performed in the presence of, as a solvent, an aryl ester of an aliphatic carboxylic acid represented by the formula ##STR1## wherein n is an integer of 1 to 5, R.sub.1 represents hydrogen or C.sub.1 -C.sub.4 alkyl or alkenyl, and R.sub.2 represents hydrogen, alkyl, aryl, alkenyl, hydroxymethyl, acyl, acyloxy, formyl, carboxy, hydroxy, halogen, sulfo, nitro, nitroso, amino, acid amide or cyano, and two or more R.sub.2 groups may be the same or different, and the substituents R.sub.2 may be bonded to each other to form a penta- or hexa-carbocyclic or heterocyclic ring.
摘要翻译：在通过醇或醚与一氧化碳反应制备羧酸或其酯的方法中，其中反应在作为溶剂存在下由式（I）表示的脂族羧酸的芳基酯进行，其中n为1〜5的整数，R1表示氢或C1-C4烷基或烯基，R2表示氢，烷基，芳基，烯基，羟甲基，酰基，酰氧基，甲酰基，羧基，羟基，卤素，磺基，硝基，亚硝基，氨基，酰胺或氰基，两个或更多个R 2基可以相同或不同，并且取代基R 2可以彼此键合形成五 - 或六碳环或杂环。

96. 发明申请

US20230001394A1 CATALYST FOR CARBONYLATION OF DIMETHYL ETHER AND METHOD FOR PREPARING THE SAME 有权
公开(公告)号：US20230001394A1
公开(公告)日：2023-01-05
申请号：US17857528
申请日：2022-07-05
申请人： RESEARCH & BUSINESS FOUNDATION SUNGKYUNKWAN UNIVERSITY
发明人： Jong Wook BAE , Jong Jin KIM
IPC分类号： B01J29/65 , B01J31/06 , B01J31/26 , B01J35/02 , B01J35/00 , B01J37/04 , B01J37/00 , B01J37/02 , B01J37/08 , B01J29/90 , B01J38/04 , C07C67/37
摘要： Disclosed are a catalyst for carbonylation of dimethyl ether that has high catalyst activity and can be regenerated using a fluidized bed reactor, and a method for preparing the same. The catalyst for carbonylation of dimethyl ether includes a support having a first density; and ferrierite zeolite catalyst particles bound to a surface of the support via a polymer binder and having a second density smaller than the first density.

97. 发明授权

US11111200B2 Method for preparing acrylic acid and methyl acrylate 有权
公开(公告)号：US11111200B2
公开(公告)日：2021-09-07
申请号：US16463415
申请日：2016-11-25
申请人： Dalian Institute of Chemical Physics, Chinese Academy of Sciences
发明人： Lei Shi , Zongmin Liu , Youming In , Wenliang Zhu , Yong Liu , Hongchao Liu
IPC分类号： C07C51/12 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/70 , C07C67/37 , C07C57/04 , C07C69/54
摘要： The present invention provides a method for preparing acrylic acid and methyl acrylate. The method comprises passing the feed gas containing dimethoxymethane and carbon monoxide through a solid acid catalyst to generate acrylic acid and methyl acrylate with a high conversion rate and selectivity at a reaction temperature in a range from 180 to 400 and a reaction pressure in a range from 0.1 MPa to 15.0 MPa, the mass space velocity of dimethoxymethane in the feed gas is in a range from 0.05 h−1 to 10.0 h−1, and the volume percentage of dimethoxymethane in the feed gas is in a range from 0.1% to 95%.

98. 发明申请

US20210114963A1 METHOD FOR PREPARING ACRYLIC ACID AND METHYL ACRYLATE 有权
公开(公告)号：US20210114963A1
公开(公告)日：2021-04-22
申请号：US16463415
申请日：2016-11-25
申请人： DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
发明人： Lei SHI , Zongmin LIU , Youming IN , Wenliang ZHU , Yong LIU , Hongchao LIU
IPC分类号： C07C51/12 , C07C67/37 , B01J29/40 , B01J29/65 , B01J29/18 , B01J29/70
摘要： The present invention provides a method for preparing acrylic acid and methyl acrylate. The method comprises passing the feed gas containing dimethoxymethane and carbon monoxide through a solid acid catalyst to generate acrylic acid and methyl acrylate with a high conversion rate and selectivity at a reaction temperature in a range from 180 to 400 and a reaction pressure in a range from 0.1 MPa to 15.0 MPa, the mass space velocity of dimethoxymethane in the feed gas is in a range from 0.05 h−1 to 10.0 h−1, and the volume percentage of dimethoxymethane in the feed gas is in a range from 0.1% to 95%.

99. 发明申请

US20200094230A1 Metal-Loaded Zeolite Catalysts for the Halogen-Free Conversion of Dimethyl Ether to Methyl Acetate 审中-公开
公开(公告)号：US20200094230A1
公开(公告)日：2020-03-26
申请号：US16697492
申请日：2019-11-27
申请人： Allen Artur Carl Reule , Natalia Semagina , Esteban Chornet
发明人： Allen Artur Carl Reule , Natalia Semagina , Esteban Chornet
IPC分类号： B01J29/24 , C07C67/37 , B01J29/18 , B01J37/14 , B01J37/18 , B01J29/90 , B01J38/10
摘要： A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.

100. 发明授权

US10583426B2 Carbonylation catalyst and process 有权
公开(公告)号：US10583426B2
公开(公告)日：2020-03-10
申请号：US16018689
申请日：2018-06-26
申请人： BP CHEMICALS LIMITED
发明人： John Glenn Sunley
IPC分类号： B01J29/06 , B01J29/87 , C07C51/347 , C07C51/09 , C07C53/08 , C07C69/14 , C07C51/12 , C07C29/132 , C07C29/153 , C07C29/136 , B01J29/18 , B01J29/24 , B01J29/65 , B01J29/70 , B01J35/10 , B01J37/00 , C01B39/26 , C07C67/37 , C01B39/06 , B01J29/50 , B01J29/88 , C01B39/44 , C01B39/30 , B01J29/86 , C01B39/08
摘要： A catalyst and process for the production of methyl acetate by contacting dimethyl ether and carbon monoxide in the presence of a catalyst which is a zeolite of micropore volume of 0.01 ml/g or less.

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