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    • 92. 发明申请
    • Method of producing 3-d photonic crystal fibers
    • 3-d光子晶体纤维的制备方法
    • US20060165984A1
    • 2006-07-27
    • US10535944
    • 2003-12-16
    • Hernan MiguezGeoffrey OzinSan YangNicolas Tetreault
    • Hernan MiguezGeoffrey OzinSan YangNicolas Tetreault
    • B05D1/40
    • C30B5/00B82Y20/00C30B29/60G02B6/02347G02B6/1225Y10T428/2933
    • The invention described herein is broadly directed to 3D photonic crystal fibers exemplified but not limited to novel 3D inverse colloidal crystal fibers made of silicon. In particular the invention relates to the general utilization of controlled size and controlled shape and controlled length microchannel surface relief patterns that have been lithographically defined in silicon substrates for the geometrically confined crystallization of silica microspheres to form highly ordered and oriented colloidal photonic crystal microchannel templates and the utilization of such templates for creating, through silicon infiltration synthetic strategies, colloidal silicon-silica photonic crystal composite materials thereof and the subsequent removal of the silica template and detachment of these colloidal silicon-silica photonic crystal composite materials from the silicon substrate by etching in a fluoride-based medium to create oriented free standing 3D inverse colloidal photonic crystal fibers. These novel fiber constructs provide a new class of optical components with a complete PBG along transverse and longitudinal directions of the microfiber axis that can be tailored to lie in the optical telecommunication wavelength range. The synthetic strategy described herein provides a versatile means for making 3D colloidal photonic crystal optical fibers with a range of cross-sectional shapes and sizes, fiber lengths, elemental compositions and photonic lattice dimensions, refractive index contrasts and optical properties and with either normal or inverse colloidal lattice structures.
    • 本文描述的本发明广泛地涉及示例的但不限于由硅制成的新型3D反胶体晶体纤维的3D光子晶体光纤。 特别地,本发明涉及一般利用受控尺寸和可控长度的微通道表面浮雕图案,其已经在硅衬底中被光刻地限定,用于二氧化硅微球的几何限制结晶以形成高度有序和取向的胶体光子晶体微通道模板, 利用这种模板,通过硅渗透合成策略,制备胶体硅 - 硅石光子晶体复合材料,随后去除二氧化硅模板,并通过蚀刻从硅衬底上剥离这些胶体硅 - 硅石光子晶体复合材料 一种基于氟化物的介质,以产生定向自立的3D反胶体光子晶体光纤。 这些新颖的纤维结构提供了一类新的光学元件,其具有沿着超细纤维轴线的横向和纵向方向的完整的PBG,其可以被定制在光通信波长范围内。 本文描述的合成策略提供了用于制造具有一定范围的横截面形状和尺寸,纤维长度,元素组成和光子晶格尺寸,折射率对比度和光学性质以及正常或反向的三维胶体光子晶体光纤的通用手段 胶体晶格结构。
    • 98. 发明申请
    • Mechanical stability enhancement by pore size and connectivity control in colloidal crystals by layer-by-layer growth of oxide
    • 通过氧化物逐层生长,胶体晶体中孔径和连接性控制的机械稳定性提高
    • US20040062700A1
    • 2004-04-01
    • US10255578
    • 2002-09-27
    • Hernan MiguezGeoffrey Alan OzinSan Ming YangNicolas Tetreault
    • C01B033/12
    • G02B6/1225B82Y20/00C30B5/00C30B29/60G02B6/122
    • The present invention provides a method to control the degree of connectivity of the colloidal particles making up a colloidal crystal and, consequently, the pore size, filling fraction, mechanical stability and optical properties of the colloidal lattice, without disrupting its long range order and without the deleterious effects of lattice contraction induced cracking observed in conventional necking methods based on thermal sintering. The colloidal particles are connected to adjacent colloidal particles in the lattice by a homogeneous layer of uniform and controllable thickness of a metal oxide. This metal oxide layer is grown in a layer-by-layer process and is chemically bonded to the colloidal particle surface and serves to enhance the mechanical stability of the colloidal crystal in addition to acting to control the pore size or void volume between the colloidal particles in the lattice.
    • 本发明提供了一种控制构成胶体晶体的胶体粒子的连通度,从而控制胶体晶格的孔径,填充率,机械稳定性和光学性质而不破坏其长程有序并且没有 在基于热烧结的常规颈缩方法中观察到晶格收缩引起的裂纹的有害影响。 胶体颗粒通过均匀且可控的金属氧化物厚度的均匀层与晶格中的相邻胶体颗粒连接。 该金属氧化物层是逐层生长的,并且化学键合到胶体颗粒表面,并用于增强胶体晶体的机械稳定性,除了用于控制胶体颗粒之间的孔径或空隙体积 在格子里