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    • 92. 发明授权
    • Selective reduction of nickel laterite ores
    • 选择性还原镍红土矿石
    • US4195986A
    • 1980-04-01
    • US949394
    • 1978-10-06
    • Jerry D. SchulzBobby P. Faulkner
    • Jerry D. SchulzBobby P. Faulkner
    • C22B23/00C22B23/02
    • C22B23/005C22B23/021
    • To prepare nickel laterite ore for selective reduction of its nonferrous metal oxides, it is comminuted (preferably to 85% minus 200 mesh) and is mixed with comminuted (preferably 100% minus 65 mesh) high volatile, high ash waste coal and a non-gaseous sulfur material. Carbon content of the coal is 50% to 150% of the amount of carbon needed for stoichiometric complete reduction of nonferrous metal oxides in the ore and partial reduction of its iron oxide content. The sulfur content of the sulfur material is such that, together with the sulfur content of the coal, the weight of sulfur is 1% to 1.5% of the weight of the ore. The mixture, preferably pelletized with water, is heated out of contact with air to bring it to 550.degree. C. (requiring 20 to 25 minutes) and is then passed to an aquatic quench. Volatiles in the coal provide reducing gas, and the ash content facilitates wet grinding after quench and provides a good filter bed for subsequent leaching to recover nonferrous metal values.
    • 为了制备镍红土矿石以选择性还原其有色金属氧化物,将其粉碎(优选至85%,减去200目),并与粉碎(优选100%-65目)高挥发性,高灰分废煤和非粉煤灰混合, 气态硫材料。 煤的碳含量为矿石中有色金属氧化物的化学计量完全还原所需碳量的50%〜150%,其氧化铁含量部分降低。 硫材料的硫含量使得与硫的硫含量一起,硫的重量为矿石重量的1%至1.5%。 将混合物,优选用水造粒,加热脱离与空气的接触,使其达到550℃(需要20至25分钟),然后通入水中淬火。 煤中的挥发物提供还原气,灰分有利于淬火后的湿磨,并提供了良好的过滤床,用于随后的浸出以回收有色金属。
    • 97. 发明授权
    • Extraction of metal values from lateritic ores
    • 从红土矿石中提取金属值
    • US3892639A
    • 1975-07-01
    • US50446474
    • 1974-09-11
    • US INTERIOR
    • LEAVENWORTH JR HOWARD WAMEY EARLE BDUNNING JR BEVERLY WGABLER JR ROBERT CGOLDSMITH CARL E
    • C22B1/08C22B23/00C22B34/32C22D1/14C22D1/24
    • C22B34/32C22B1/08C22B23/00C22B23/005Y02P10/216
    • There is disclosed a method for the extraction of metal values from laterite ores including nickel, chromium, manganese, iron and cobalt by a series of steps including chlorinating the ore in a fluidized bed with hydrogen chloride gas to form volatile metal chlorides of nickel, iron, cobalt and manganese, and a residue containing chromium, removing and condensing the volatile chlorides to effect separation, recovering the metals of nickel, cobalt and manganese and chlorine as by the use of electrolytic cells, reacting the iron chloride with oxygen to separate the iron as iron oxide; removing the residue from the fluid bed reactor for reduction with carbon to produce carbides; leaching to form salts of chromium, separating from other salts, and recovering the chromium. Also provided is a continuous method for practice of the process.
    • 公开了一种通过一系列步骤从包括镍,铬,锰,铁和钴的红土矿石中提取金属值的方法,包括在流化床中用氯化氢气体氯化矿石以形成镍,铁的挥发性金属氯化物 ,钴和锰,以及含有铬的残余物,除去和冷凝挥发性氯化物进行分离,通过使用电解池回收镍,钴和锰和氯的金属,使氯化铁与氧气反应以分离铁 作为氧化铁; 从流化床反应器中除去残余物以用碳还原以产生碳化物; 浸出以形成铬盐,与其他盐分离,并回收铬。 还提供了用于实施该方法的连续方法。