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91. 发明申请

US20070255078A1 Continuous Process for the Preparation of Phenol from Benzene in a Fixed Bed Reactor 有权
标题翻译：在固定床反应器中由苯制备酚的连续方法
公开(公告)号：US20070255078A1
公开(公告)日：2007-11-01
申请号：US11575579
申请日：2005-10-26
申请人： Daniele Bianchi , Rossella Bortolo , Chiara Busto , Carla Lazzari
发明人： Daniele Bianchi , Rossella Bortolo , Chiara Busto , Carla Lazzari
IPC分类号： C07C37/00
CPC分类号： B01J37/12 , B01J29/89 , B01J37/0009 , B01J2229/30 , B01J2229/42 , C07C37/60 , Y02P20/52 , C07C39/04
摘要： The invention relates to a continuous process for the preparation of phenol by means of the direct oxidation of benzene with hydrogen peroxide in the presence of a catalyst based on titanium silicalite TS-1 comprising: (a) running the process in a fixed bed reactor containing the catalyst based on TS-1 at a temperature ranging from 80-120° C. and at a pressure ranging from 3-15 atm; (b) feeding to the reactor a stream containing H2O2, benzene, sulfolane and water in a single or double phase, wherein the quantities of the single components are within the range of 0.2-6, 15-60, 30-80, 0.5-30 parts by weight, respectively, for every 100 units fed and whose total flow rate is calculated so that the residence time in the reactor (defined as the ratio between the quantity of catalyst by weight and the feeding flow rate) ranges from 0.3 to 2 min; (c) recovery of the products, by-products and solvent from the liquid stream leaving the reactor.
摘要翻译：本发明涉及一种通过在基于钛硅沸石TS-1的催化剂存在下用过氧化氢直接氧化苯的连续方法，其包括：（a）在含有催化剂基于TS-1，温度范围为80-120℃，压力范围为3-15atm; （b）在单相或双相中向反应器中加入含有H 2 O 2 O 2，苯，环丁砜和水的流，其中单一组分的量在对于每供给的100个单位，分别为0.2-6,15-60,30-80,0.5-30重量份的范围，并且计算其总流速使得在反应器中的停留时间（定义为催化剂的重量和进料流量）为0.3〜2分钟; （c）从离开反应器的液体流中回收产物，副产物和溶剂。

92. 发明授权

US07038093B2 Integrated process for the preparation of phenol from benzene with recycling of the by-products 有权
标题翻译：从苯中制备苯酚的副产物回收综合工艺
公开(公告)号：US07038093B2
公开(公告)日：2006-05-02
申请号：US10716460
申请日：2003-11-20
申请人： Daniele Bianchi , Rossella Bortolo , Roberto Buzzoni , Alberto Cesana , Leonardo Dalloro , Rino D'Aloisio
发明人： Daniele Bianchi , Rossella Bortolo , Roberto Buzzoni , Alberto Cesana , Leonardo Dalloro , Rino D'Aloisio
IPC分类号： C07C37/00
CPC分类号： C07C37/60 , B01J29/89 , B01J2229/30 , Y02P20/125 , Y02P20/52 , C07C39/04
摘要： The invention relates to a process for the preparation of phenol comprising the following phases: 1) preparation in continuous of phenol by means of the direct oxidation of benzene with hydrogen peroxide operating with an H2O2/benzene ratio ranging from 10 to 70%, in a three-phase reaction system comprising a first liquid phase consisting of benzene and an organic solvent, a second liquid phase consisting of water, a solid phase consisting of an activated catalyst based on titanium silicalite TS-1; 2) separation of the phenol and non-reacted benzene from the reaction mixture of the oxidation section (1), by means of fractionated distillation; 3) separation of the solvent and by-products from the mixture coming from the distillation tail (2), by means of basic extraction; 4) transformation of the by-products obtain in section (3) to phenol by means of hydrodeoxygenation with hydrogen operating in continuous, in aqueous solution, at a temperature ranging from 250 to 500° C., at pressures of 1-100 bar and in the presence of a catalyst based on elements of group VIB or their mixtures or group VIII of the periodic table or their mixtures; 5) recycling of the phenol obtained in section (4) to the distillation section (2).
摘要翻译：本发明涉及一种制备苯酚的方法，包括以下阶段：1）通过苯与氧化氢的直接氧化制备苯酚连续操作，所述过氧化氢用H 2 O 2 在含有由苯和有机溶剂组成的第一液相的三相反应体系中，第二液相由水组成，固相由活化的基于钛硅沸石TS-1的催化剂; 2）通过分级蒸馏从氧化段（1）的反应混合物中分离苯酚和未反应的苯; 3）通过碱性萃取法从蒸馏尾料（2）中分离出溶剂和副产物与混合物; 4）将第（3）部分获得的副产物转化为苯酚，通过加氢脱氧，氢气在连续的水溶液中，在250-500℃的温度，1-100巴的压力和在基于元素周期表VIB族元素或它们的混合物或VIII族元素或其混合物的催化剂的存在下; 5）将第（4）节中得到的酚再循环至蒸馏段（2）。

93. 发明申请

US20060070953A1 Process for the recovery of tyrosol and hydroxytyrosol from oil mill wastewaters and catalytic oxidation method in order to convert tyrosol in hydroxytyrosol 有权
标题翻译：从油厂废水中回收酪醇和羟基酪醇的方法和催化氧化方法，以转化羟基酪醇中的酪醇
公开(公告)号：US20060070953A1
公开(公告)日：2006-04-06
申请号：US11197359
申请日：2005-08-05
申请人： Luigi Villanova , Luciano Villanova , Gianluca Fasiello , Alessandro Merendino
发明人： Luigi Villanova , Luciano Villanova , Gianluca Fasiello , Alessandro Merendino
IPC分类号： B01D61/58 , C07C229/00
CPC分类号： B01J31/165 , A23L33/105 , A61K8/347 , A61Q19/02 , B01J2231/70 , B01J2531/74 , C02F1/001 , C02F1/26 , C02F1/441 , C02F1/442 , C02F1/444 , C02F1/725 , C02F9/00 , C02F2103/322 , C07C37/009 , C07C37/60 , C07C39/11
摘要： A for preparing Tyrosol and/or Hydroxytyrosol from oil mill wastewaters. includes: a) Microfiltration (MF), Ultrafiltration (UF), Nanofiltration (NF) and Reverse Osmosis (RO) of the OMW; b) Separation of Tyrosol, Hydroxytyrosol and other phenolic compounds from the concentrated RO; c) Oxidation of the obtained Tyrosol to Hydroxytyrosol in the presence of methyl rhenium trioxide and of hydrogen peroxide in a protic solvent.
摘要翻译： A用于从油磨废水中制备Tyrosol和/或羟基酪氨酸。包括：a）OMW的微滤（MF），超滤（UF），纳滤（NF）和反渗透（RO）; b）从浓缩的RO中分离出Tyrosol，羟基酪醇和其他酚类化合物; c）在甲基三氧化铼和过氧化氢的存在下，在质子溶剂中将所得Tyrosol氧化成羟基酪醇。

94. 发明授权

US06872857B1 Process for conversion of phenol to hydroquinone and quinones 失效
标题翻译：苯酚转化为氢醌和醌的方法
公开(公告)号：US06872857B1
公开(公告)日：2005-03-29
申请号：US10671871
申请日：2003-09-29
申请人： Gajanan Kundali Dewkar , Vinay Vijayraj Thakur , Sanjeevani Amrit Pardhy , Arumugam Sudalai , Sukumar Devotta
发明人： Gajanan Kundali Dewkar , Vinay Vijayraj Thakur , Sanjeevani Amrit Pardhy , Arumugam Sudalai , Sukumar Devotta
IPC分类号： B01J21/06 , B01J37/03 , C07C37/60 , C07C39/08 , C07C46/06 , C07C409/00 , C07C50/04 , C07C37/10
CPC分类号： B01J21/063 , B01J37/033 , C07C37/60 , C07C46/06 , C07C50/24 , C07C50/04 , C07C50/02 , C07C39/08
摘要： The present invention relates to a process for the conversion of phenol to hydroquinone and quinones. More particularly this invention relates to a process for the oxidation of phenol to a mixture of 1,4-benzoquinone and hydroquinone using an oxidant in the presence of titanium superoxide as a reusable catalyst in a liquid phase condition.
摘要翻译：本发明涉及一种将苯酚转化为氢醌和醌的方法。更具体地说，本发明涉及在液相条件下，在超氧化钛作为可重复使用的催化剂存在下，使用氧化剂将苯酚氧化为1,4-苯醌和氢醌的混合物的方法。

95. 发明申请

US20040110995A1 Reaction method utilizing diaphram type catalyst and apparatus therefor 有权
标题翻译：利用二价型催化剂的反应方法及其设备
公开(公告)号：US20040110995A1
公开(公告)日：2004-06-10
申请号：US10451624
申请日：2003-12-10
发明人： Fujio Mizukami , Shuichi Niwa , Makoto Toba , Naotsugu Itoh , Tomonari Saito , Takemi Nanba , Hiroshi Shoji , Kazuhiko Haba
IPC分类号： C07C027/00
CPC分类号： C07D213/63 , B01J8/009 , B01J10/007 , B01J12/007 , B01J14/005 , B01J19/2475 , B01J23/44 , B01J35/065 , B01J2219/00063 , B01J2219/00094 , B01J2219/00099 , C07C29/50 , C07C37/58 , C07C37/60 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/40 , C07C2601/14 , Y02P20/52 , C07C49/08 , C07C47/22 , C07C35/08 , C07C39/04 , C07C39/07 , C07C39/14 , C07C35/36
摘要： A method for carrying out a reaction of one substance capable of being activated by a catalyst with another substance capable of reacting with said one substance activated, characterized in that the substance capable of being activated is activated by passing the substance through a diaphragm type catalyst and the reaction is thus performed in one reaction step; a method for producing an aromatic alcohol utilizing the above method; and a reaction apparatus suitable for these reactions. In the method, one substance is activated by passing through a diaphragm type catalyst and an objective reaction is carried out by using the activated substance, and the reaction can be performed in one reaction step and with safety. Moreover, the contact of the above activated substance with a compound to be reacted therewith can be freely controlled, and therefore, over-reaction can be prevented and an objective product can be produced in high yield. The method is thus markedly advantageous from an economical view point as a commercial process for producing oxygen-containing organic compounds such as an aromatic alcohol, a ketone, an aldehyde, a carboxylic acid and an epoxide.
摘要翻译：一种能够使一种能够被催化剂活化的物质与能够与所述一种活化物质反应的物质进行反应的方法，其特征在于，通过使该物质通过隔膜型催化剂而活化，因此在一个反应步骤中进行反应; 利用上述方法制备芳族醇的方法; 和适用于这些反应的反应装置。在该方法中，通过隔膜型催化剂活化一种物质，并通过使用活性物质进行目标反应，反应可以在一个反应步骤和安全性下进行。此外，可以自由地控制上述活性物质与其反应的化合物的接触，因此可以防止过度反应，并且可以高产率制备目标产物。因此，作为用于生产含氧有机化合物如芳族醇，酮，醛，羧酸和环氧化物的商业方法，从经济角度看，该方法显着是有利的。

96. 发明申请

US20040063568A1 Method for the production of form-selective catalysts and use thereof 审中-公开
标题翻译：生产形式选择性催化剂的方法及其用途
公开(公告)号：US20040063568A1
公开(公告)日：2004-04-01
申请号：US10399781
申请日：2003-10-23
发明人： Adolf Kuhnle , Mark Duda , Karsten Seelbach , Steffen Hasenzahl , Uwe Tanger , Carsten Jost , Elias Klemm , Andreas Reitzmann
IPC分类号： B01J029/04 , B01J029/87
CPC分类号： C07D301/12 , B01D53/8628 , B01D53/8668 , B01J29/061 , C07C37/60 , C07C213/00 , Y02P20/52 , C07C215/76 , C07C39/04
摘要： The invention relates to a process for manufacturing zeolite catalysts containing subgroup metals by hydrothermal synthesis with subsequent calcination, which is characterized in that the subgroup metals are used in hydrothermal synthesis in the form of carbonyl, isonitrile or cyanocomplexes. The catalysts thus produced can be used as a catalyst for removing nitrogen or for oxidizing organic compounds.
摘要翻译：本发明涉及通过随后的煅烧水热合成制备含亚金属的沸石催化剂的方法，其特征在于亚组金属以羰基，异腈或氰基络合物的形式用于水热合成。由此生产的催化剂可用作除去氮气或氧化有机化合物的催化剂。

97. 发明授权

US06586624B1 Oxidation process 失效
标题翻译：氧化工艺
公开(公告)号：US06586624B1
公开(公告)日：2003-07-01
申请号：US08570885
申请日：1995-12-12
申请人： Clive A. Henrick , Randall A. Scheuerman
发明人： Clive A. Henrick , Randall A. Scheuerman
IPC分类号： C07C6500
CPC分类号： C07C37/60 , C07C39/30
摘要： Preparation of 2,5-dichlorophenol by selectively oxidizing 1,4-dichlorobenzene using a peroxo-, hydroperoxo-, superoxo- or alkylperoxo-vanadium species in the presence of an &agr;-hydroxy-, dibasic-, tribasic- or sulfonic acid.
摘要翻译：通过在α-羟基，二元，三元或磺酸的存在下，使用过氧化氢，过氧化，超氧化或烷基过氧钒物质选择性氧化1,4-二氯苯，制备2,5-二氯苯酚。

98. 发明授权

US06476277B2 Process for preparing hydroxyaromatics 失效
标题翻译：羟基芳烃的制备方法
公开(公告)号：US06476277B2
公开(公告)日：2002-11-05
申请号：US09915079
申请日：2001-07-24
申请人： Bernd Vogel , Elias Klemm , Mathias Seitz , Jochen Heller , Jörg Reiser
发明人： Bernd Vogel , Elias Klemm , Mathias Seitz , Jochen Heller , Jörg Reiser
IPC分类号： C07C3700
CPC分类号： C07C37/60 , Y10S977/775 , Y10S977/776 , Y10S977/779 , Y10S977/84 , Y10S977/896 , C07C39/07
摘要： The present invention relates to a process for preparing hydroxyaromatics by oxidizing aromatics with dinitrogen monoxide in the gas phase in the presence of nanocrystalline zeolites.
摘要翻译：本发明涉及通过在纳米晶体沸石存在下在气相中用一氧化二氮氧化芳族化合物来制备羟基芳族化合物的方法。

99. 发明授权

US06388145B1 Method for the oxidation of benzene and/or toluene to phenol and/or cresols 有权
标题翻译：将苯和/或甲苯氧化成苯酚和/或甲酚的方法
公开(公告)号：US06388145B1
公开(公告)日：2002-05-14
申请号：US09533739
申请日：2000-03-23
申请人： Leonid Modestovich Kustov , Andrei Leonidovich Tarasov , Aleksandr Arunovich Tyrlov , Viktor Ignatyevich Bogdan
发明人： Leonid Modestovich Kustov , Andrei Leonidovich Tarasov , Aleksandr Arunovich Tyrlov , Viktor Ignatyevich Bogdan
IPC分类号： C07C3700
CPC分类号： C07C37/60 , B01J29/061 , B01J29/40 , B01J2229/26 , B01J2229/42 , Y02P20/52 , C07C39/04 , C07C39/07
摘要： The invention relates to the field of organic synthesis, more specifically to a method for the production of phenol and cresol by the direct selective oxidation of benzene and toluene with nitrous oxide in the presence of a heterogeneous catalyst. Commercial high-silica zeolites are first calcined at a temperature of 500-950° C. sufficient to dehydroxylate it. It is then modified by the addition of modifying agents—zinc ions or zinc oxide—by applying a zinc compound to it. The catalyst is then activated in air or an inert gas at 300-850° C. The mixture of benzene or toluene with the nitrous oxide is brought into contact with the modified catalyst at 225 to 500° C.
摘要翻译：本发明涉及有机合成领域，更具体地涉及通过在多相催化剂存在下用一氧化二氮直接选择性氧化苯和甲苯来生产苯酚和甲酚的方法。商业高硅沸石首先在500-950℃的温度下煅烧足以使其脱氢化。然后通过添加改性剂 - 锌离子或氧化锌 - 通过向其施加锌化合物来进行改性。然后将催化剂在空气或惰性气体中在300-850℃下活化。苯或甲苯与一氧化二氮的混合物在225-500℃下与改性催化剂接触。

100. 发明申请

US20020026085A1 Process for activating catalyst for the hydroxylation of aromatics 失效
标题翻译：活化芳烃羟基化催化剂的方法
公开(公告)号：US20020026085A1
公开(公告)日：2002-02-28
申请号：US09837548
申请日：2001-04-18
发明人： Valery S. Chernyavsky , Alexander Sergeevich Kharitonov , Gennady I. Panov , Konstantin a. Dubkov
IPC分类号： C07C037/60
CPC分类号： C07C37/60 , B01J29/06 , B01J29/40 , B01J29/46 , B01J29/90 , B01J2229/36 , B01J2229/40 , B01J2229/42 , Y02P20/52 , Y02P20/584 , C07C39/04
摘要： A method for catalytic production of hydroxylated aromatics by exposing zeolite catalyst to a reducing atmosphere to activate said catalyst, and reacting an aromatic with nitrous oxide in the presence of said activated catalyst.
摘要翻译：一种用于通过将沸石催化剂暴露于还原气氛来活化所述催化剂并在所述活化的催化剂存在下使芳族化合物与一氧化二氮反应来催化生产羟基化芳族化合物的方法。

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