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    • 92. 发明申请
    • IONIC LIQUIDS
    • 离子液体
    • US20080296531A1
    • 2008-12-04
    • US12128893
    • 2008-05-29
    • Keith WhistonSTEWART FORSYTHKenneth R. Seddon
    • Keith WhistonSTEWART FORSYTHKenneth R. Seddon
    • C09K3/00
    • C07D211/14C07D223/04C25B3/02
    • The invention relates to an ionic liquid composition and a method for preparing the ionic liquid. The ionic liquid comprises a cation containing the Formula I, as herein disclosed, and wherein: n is 1 or 2, R1 is selected from the group consisting of: H, C1-C12 alkyl, aryl or together with R2 may form a heterocyclic ring, and R2 is selected from the group consisting of: H, C1-C12 alkyl, aryl or together with R1 may form a heterocyclic ring, and R3 is selected from the group consisting of hydrogen and C1-C12 alkyl, wherein if n is 1, then R3 is C1-C12 alkyl; and wherein R1 and R2 are not simultaneously selected from hydrogen. The method for the preparation of the ionic liquid composition provided herein starts with at least one N-substitution of the compound of Formula II, as herein disclosed, and wherein: n is 1 or 2, R3 is selected from the group consisting of hydrogen and C1-C12 alkyl, wherein if n is 1, then R3 is C1-C12 alkyl. Further provided is a use of the ionic liquid in a chemical method including at least a method for electrochemical oxidation.
    • 本发明涉及一种离子液体组合物和一种制备离子液体的方法。 离子液体包含如本文公开的含有式I的阳离子,其中n为1或2,R1选自:H,C1-C12烷基,芳基或与R2一起形成杂环 并且R 2选自:H,C 1 -C 12烷基,芳基或与R 1一起可以形成杂环,并且R 3选自氢和C 1 -C 12烷基,其中如果n是1 那么R 3是C 1 -C 12烷基; 并且其中R1和R2不同时选自氢。 制备本文提供的离子液体组合物的方法开始于本文公开的式II化合物的至少一个N-取代,并且其中:n为1或2,R 3选自氢和 C 1 -C 12烷基,其中如果n是1,那么R 3是C 1 -C 12烷基。 还提供了一种使用离子液体的化学方法,至少包括一种电化学氧化方法。
    • 94. 发明申请
    • Method for making caprolactam from impure 6-aminocapronitrile
    • 从不纯的6-氨基己腈制备己内酰胺的方法
    • US20080009618A9
    • 2008-01-10
    • US11083715
    • 2005-03-18
    • Alan AllgeierJohn OstermaierSourav Sengupta
    • Alan AllgeierJohn OstermaierSourav Sengupta
    • C07D201/02
    • C07D223/10
    • The invention relates to the field of production of lactams from aminonitriles, and in particular to the production of ε-caprolactam by the vapor phase hydrolytic cyclization of 6-aminocapronitrile. A crude liquid caprolactam comprising ε-caprolactarn (CL), 6-aminocapronitrile (ACN) and water obtained from a vapor phase cyclization reaction of ACN is contacted with hydrogen in the presence of a hydrogenation catalyst to convert the ACN in the crude liquid caprolactam to a product comprising hexamethylenediamine (HMD) and hexamethyleneimine (HMI). Tetrahydroazepine (THA) in the crude liquid caprolactam is converted to HMI during this hydrogenation. The HMD and HMI have lower boiling points compared to ACN and thus they are more easily separated from CL in the subsequent distillation operations. Thus a process to make CL from ACN with fewer distillation stages, and with lower pressure drop and lower base temperature, is accomplished.
    • 本发明涉及由氨基腈生产内酰胺的领域,特别涉及通过6-氨基己腈的气相水解环化生产ε-己内酰胺。 包含ε-己内酯(CL),6-氨基己腈(ACN)和由ACN的气相环化反应获得的水的粗液体己内酰胺在氢化催化剂存在下与氢气接触,将粗液体己内酰胺中的ACN转化为 包含六亚甲基二胺(HMD)和六亚甲基亚胺(HMI)的产品。 粗制液体己内酰胺中的四氢吖庚因(THA)在该氢化期间转化为HMI。 与ACN相比,HMD和HMI具有较低的沸点,因此在随后的蒸馏操作中它们更容易与CL分离。 因此,实现了具有较少蒸馏阶段以及较低压降和较低基础温度的来自ACN的CL的方法。
    • 95. 发明申请
    • Method for the purification of triorganophosphites by treatment with a basic additive
    • US20070219386A1
    • 2007-09-20
    • US11716133
    • 2007-03-09
    • Joachim C. Ritter
    • Joachim C. Ritter
    • C07F9/02
    • C07F9/025C07F9/1412C07F9/142C07F9/144C07F9/145C07F9/65744
    • The invention provides a method for separating one or more triorganophosphite components from a crude phosphite mixture containing acidic hydrolysis products, the method comprising:contacting said crude phosphite mixture with a basic additive to produce a second mixture comprising a first phase and a second phase, wherein said first phase comprises the basic additive and one or more components independently selected from the group consisting of (R2O)(R3O)POH, (R1O)(HO)PO(H) and H3PO3, wherein R1, R2 and R3 are independently selected from the group consisting of C1 to C18 alkyl, C6 to C18 aryl and hydroxyaryl, and C3 to C18 cycloalkyl and hydroxyalkyl radicals, and wherein R2 and R3 can optionally be connected to each other directly by a chemical bond or through an intermediate divalent group R9; andsaid second phase comprises one or more triorganophosphite components independently selected from the group consisting of (R4O)(R5O)P(OR6) and ((R7O)(R8O)PO)nA, wherein R4, R5, R6, R7 and R8 are independently selected from the group consisting of C1 to C18 alkyl, C6 to C18 aryl and C3 to C18 cycloalkyl radicals, wherein each of R4, R5 and R6 can optionally be connected to one or both of the other two directly by a chemical bond or through an intermediate divalent group R10, wherein R7 and R8 can optionally be connected to each other directly by a chemical bond or through an intermediate divalent group R11, wherein A is an optionally substituted or unsubstituted aliphatic, aromatic or heteroaromatic radical, and wherein n is an integer greater than 1; andR9, R10, and R11 are independently selected from the group consisting of —O—, —S—, and —CH(R12)—, wherein R12 is selected from the group consisting of H, C6 to C18 aryl, and C1 to C18 alkyl.
    • 96. 发明授权
    • Separation of 6-aminocapronitrile and hexamethylenediamine from a mixture comprising hexamethylenediamine, 6-aminocapronitrile and tetrahydroazepine
    • 从包含六亚甲基二胺,6-氨基己腈和四氢氮杂的混合物中分离6-氨基己腈和六亚甲基二胺
    • US07208632B2
    • 2007-04-24
    • US10939144
    • 2004-09-10
    • John Joseph Ostermaier
    • John Joseph Ostermaier
    • C07C209/86
    • C07C209/86C07C253/34C07C211/12C07C255/24
    • The invention relates to the field of separation by distillation of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) from a mixture comprising ACN, HMD, tetrahydroazepine (THA), adiponitrile (ADN) and low boilers (LB). Also disclosed is a method for producing a distillate stream comprising HMD; a side draw stream comprising ACN, THA and low levels of dimers of ACN and HMD; and a tails stream comprising ACN, THA and substantially higher levels of dimers of ACN and HMD than found in the side draw stream. The side draw stream is particularly suitable for use in the production of caprolactam since the low levels of dimers of ACN and HMD do not greatly affect the catalyst life in the caprolactam production process. The tails stream can be further distilled to produce a tails distillate stream comprising ACN and THA, which can be recycled back to the first distillation column, further increasing recovery of ACN from the feed stream. Process conditions of the method of the invention disfavor the production of 2-cyanocyclopentylideneimine (CPI).
    • 本发明涉及从包含ACN,HMD,四氮氮平(THA),己二腈(ADN)和低锅炉(LB))的混合物中蒸馏出6-氨基己腈(ACN)和六亚甲基二胺(HMD)的分离领域。 还公开了一种生产包含HMD的馏出液流的方法; 包含ACN,THA和ACN和HMD的低水平二聚体的侧引流; 以及包含ACN,THA和比侧馏分流中发现的ACN和HMD的显着更高水平的二聚体的尾料流。 由于ACN和HMD的低水平二聚体不会极大地影响己内酰胺生产过程中的催化剂寿命,所以侧引流特别适用于生产己内酰胺。 可以进一步蒸馏尾巴料流以产生包含ACN和THA的尾馏馏料流,其可再循环回第一蒸馏塔,进一步增加ACN从进料流中的回收。 本发明方法的工艺条件不利于2-氰基环戊烯亚胺(CPI)的生产。