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91. 发明授权

US5371297A Preparation of aldehydes 失效
标题翻译：醛的制备
公开(公告)号：US5371297A
公开(公告)日：1994-12-06
申请号：US121440
申请日：1993-09-16
申请人： Rolf Fischer
发明人： Rolf Fischer
IPC分类号： C07C45/67 , C07C45/54
CPC分类号： C07C45/676
摘要： A process for the preparation of aldehydes of the general formula I ##STR1## in which R.sup.1, R.sup.2 denote hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, acyl, aryl, or C.sub.7 -C.sub.20 aralkyl or together stand for --(CH.sub.2).sub.n --X--(CH.sub.2).sub.m --,X denotes methylene, oxygen, sulfur, NH or NR.sub.3 andn, m stand for an integer from 0 bis 8,wherein a geminal formyl ester of the general formula II ##STR2## in which R.sup.1 and R.sup.2 have the aforementioned meanings and R.sup.3 denotes C.sub.1 -C.sub.12 alkyl, is caused to react in the presence of an acid catalyst at temperatures ranging from 150.degree. to 400.degree. C.
摘要翻译：制备通式I（I）的醛的方法，其中R 1，R 2表示氢，C 1 -C 12烷基，C 3 -C 8环烷基，酰基，芳基或C 7 -C 20芳烷基或一起代表 - （CH 2）n -X-（CH 2）m - ，X表示亚甲基，氧，硫，NH或NR 3，n，m代表0的整数8，其中通式II的偕甲酰基）其中R 1和R 2具有上述含义，并且R 3表示C 1 -C 12烷基，在酸催化剂存在下在150-400℃的温度下反应。

92. 发明授权

US5286875A Preparation of 5-hydroxyethylpyrrolidones 失效
标题翻译： 5-羟乙基吡咯烷酮的制备
公开(公告)号：US5286875A
公开(公告)日：1994-02-15
申请号：US960776
申请日：1992-10-14
申请人： Rolf Fischer
发明人： Rolf Fischer
IPC分类号： C07D207/26 , C07D313/04
CPC分类号： C07D207/26 , C07D313/04
摘要： A process for preparing a 5-hydroxyethylpyrrolidone of the general formula I ##STR1## where R.sup.1 is hydrogen, C.sub.1 - to C.sub.12 -alkyl, C.sub.3 - to C.sub.8 -cycloalkyl, aryl or C.sub.7 - to C.sub.12 -aralkyl, by reactinga) a caprolactone of the general formula II ##STR2## or b) a butyrolactone of the general formula III ##STR3## where R.sup.2 is C.sub.1 to C.sub.12 -alkyl, ##STR4## R.sup.3 has the meaning of R.sup.2 and is additionally hydrogen and R.sup.4 is C.sub.1 - to C.sub.8 -alkyl or phenyl, with ammonia or a primary amine of the general formula IVR.sup.1 --NH.sub.2 (IV) where R.sup.1 has the abovementioned meanings, at from 150.degree. to 450.degree. C. and at from 10 to 350 bar, and the preparation of the caprolactones II and the butyrolactones III from the cyclohexanones V.
摘要翻译：制备通式I“IMAGE”的5-羟乙基吡咯烷酮的方法，其中R 1表示氢，C 1至C 12烷基，C 3至C 8环烷基，芳基或C 7至C 12 - 芳烷基，其中 a）通式II的己内酯，或b）通式III“IMAGE”的丁内酯，其中R 2表示C 1 -C 12烷基，R 3表示含义 R 2另外表示氢，R 4表示C 1〜C 8烷基和苯基，与通式IV“IMAGE”中的氨或伯胺反应，其中R 1具有上述含义，在150至450℃的温度和10至350巴的压力下，从环己酮V制备己内酯II和丁内酯III。

93. 发明授权

US5008408A Preparation of 1,4-butanediol and tetrahydrofuran 失效
标题翻译： 1,4-丁二醇和四氢呋喃的制备
公开(公告)号：US5008408A
公开(公告)日：1991-04-16
申请号：US489709
申请日：1990-03-07
申请人： Rolf Fischer , Juergen Frank , Franz Merger , Hans-Juergen Weyer
发明人： Rolf Fischer , Juergen Frank , Franz Merger , Hans-Juergen Weyer
IPC分类号： C07C29/141 , C07D307/20
CPC分类号： C07D307/20 , C07C29/141
摘要： Mixtures which contain 1,4-butanediol and tetrahydrofuran are prepared by heating 4-hydroxybutyraldehyde of the formula ##STR1## at 20.degree.-300.degree. C. in the presence or absence of 1,4-butanediol and subjecting the resulting acetals of the formulae ##STR2## to a catalytic hydrogenation at 50.degree.-300.degree. C. and 1-350 bar.
摘要翻译：含有1,4-丁二醇和四氢呋喃的混合物通过在存在或不存在1,4-丁二醇的情况下，在20-300℃下加热式Ia的4-羟基丁醛来制备，并将所得的缩醛公式 + TR 在50°-300℃和1-350巴下进行催化氢化。

94. 发明授权

US4963672A Preparation of caprolactam 失效
标题翻译：己内酰胺的制备
公开(公告)号：US4963672A
公开(公告)日：1990-10-16
申请号：US448899
申请日：1989-12-12
申请人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
发明人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
IPC分类号： B01J23/46 , C07B61/00 , C07D201/08 , C07D201/16
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared in a process comprising the following steps:(a) reacting the 5-formylvaleric ester with liquid ammonia as reaction medium and hydrogen in the presence of a ruthenium catalyst in liquid phase at from 80.degree. to 140.degree. C. under a hydrogen partial pressure of from 40 to 100 bar,(b) replacing the reaction medium ammonia by an aromatic hydrocarbon having a boiling point of from 80.degree. to 240.degree. C. which is liquid under the reaction conditions,(c) heating the resulting mixture in liquid phase under superatmospheric pressure at 230.degree.-350.degree. C. to form caprolactam, and(d) isolating caprolactam from the resulting reaction mixture.
摘要翻译：己内酰胺以包括以下步骤的方法制备：（a）使5-甲酰基戊酸酯与液氨作为反应介质和氢在钌催化剂存在下在液相中在80-140℃下在氢气分压为40〜100巴，（b）在反应条件下用沸点为80〜240℃的芳烃替代反应介质氨，（c）将所得混合物加热液相在超大气压下在230-350℃下反应形成己内酰胺，和（d）从所得反应混合物中分离己内酰胺。

95. 发明授权

US4931590A Preparation of adipic acid 失效
标题翻译：己二酸的制备
公开(公告)号：US4931590A
公开(公告)日：1990-06-05
申请号：US205340
申请日：1988-06-10
申请人： Rudolf Kummer , Franz Merger , Werner Bertleff , Rolf Fischer
发明人： Rudolf Kummer , Franz Merger , Werner Bertleff , Rolf Fischer
IPC分类号： B01J31/20 , C07B61/00 , C07C51/00 , C07C51/09 , C07C55/14 , C07C67/00 , C07C67/29 , C07C67/347 , C07C67/39 , C07C69/44 , C07C69/67
CPC分类号： C07C67/347 , C07C51/09 , C07C67/39
摘要： Adipic acid is prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a cobalt carbonyl or rhodium carbonyl complex with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) dehydrocarbonylation of the mixture consisting essentially of 4- and 3-formylvaleric esters in the presence of one or more elements of subgroup 8 of the Periodic Table at from 50.degree. to 400.degree. C. with formation of pentenoic esters, and recycling of the latter to stage (a) for hydroformylation,(d) oxidation of the 5-formylvaleric ester from stage (b) with molecular oxygen or a gas containing molecular oxygen to give a monoester of adipic acid, and(e) hydrolysis of the monoester of adipic acid to give adipic acid.
摘要翻译：己二酸通过包括以下步骤的方法制备：（a）在羰基或羰基铑羰基络合物的存在下，在一氧化碳和氢气下，在升高的温度和超大气压下与戊烯酸酯反应，加氢甲酰化形成 5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离出5-甲酰基戊酸酯，基本上由4-甲酰基戊酰胺剩余的酯，（c）在50℃至400℃下在元素周期表第8族的一种或多种元素存在下，基本上由4-甲酰基戊酸酯组成的混合物的脱氢羰基化，形成戊烯酸酯，并将后者再循环到步骤（a）进行加氢甲酰化，（d）用分子氧或含有分子氧的气体从阶段（b）氧化5-甲酰基戊酸酯，得到己二酸的单酯，和（e）水解己二酸的单酯得到己二酸。

96. 发明授权

US4906769A Isomerization of 2-pentenoates to 3-pentenoates 失效
标题翻译： 2-戊烯酸酯异构化为3-戊烯酸酯
公开(公告)号：US4906769A
公开(公告)日：1990-03-06
申请号：US333954
申请日：1989-04-06
申请人： Rolf Fischer , Franz Merger , Hans-Juergen Gosch
发明人： Rolf Fischer , Franz Merger , Hans-Juergen Gosch
IPC分类号： B01J31/02 , B01J31/00 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533 , C07C69/593
CPC分类号： C07C69/52
摘要： 3-pentenoates are prepared by isomerization of 2-pentenoates to 3-pentenoates by a process in which the 2-pentenoate is treated with from 0.01 to 0.5 mole of cyclic tertiary amine having a pK.sub.a of >6 per mold of 2-pentenoate at from 50.degree. to 250.degree. C. and the 3-pentenoate is distilled off continuously.

97. 发明授权

US4788293A Preparation of 1-pyrazolines 失效
标题翻译： 1-吡唑啉的制备
公开(公告)号：US4788293A
公开(公告)日：1988-11-29
申请号：US886407
申请日：1986-07-15
申请人： Eckhard Stroefer , Wolfgang Rohr , Gerhard W. Rotermund , Rolf Fischer , Reinhard Neudert
发明人： Eckhard Stroefer , Wolfgang Rohr , Gerhard W. Rotermund , Rolf Fischer , Reinhard Neudert
IPC分类号： C07D231/06 , C07D231/54 , C07D231/56
CPC分类号： C07D231/06 , C07D231/54
摘要： 1-Pyrazolines are prepared by oxidation of a 1,3-diamine with sodium hypochlorite and a peroxide in aqueous solution.
摘要翻译： 1-吡唑啉通过用次氯酸钠和过氧化物在水溶液中氧化1,3-二胺来制备。

98. 发明授权

US4740613A Preparation of 4-pentenoates 失效
标题翻译： 4-戊烯酸酯的制备
公开(公告)号：US4740613A
公开(公告)日：1988-04-26
申请号：US024676
申请日：1987-03-11
申请人： Rolf Fischer , Uwe Vagi
发明人： Rolf Fischer , Uwe Vagi
IPC分类号： C07C69/533 , C07C67/475 , C07C69/52 , C07C67/27
CPC分类号： C07C67/03
摘要： 4-Pentenoates of the formula ##STR1## where R is alkyl of from 1 to 6 carbon atoms, are prepared by a process in which 5-methylbutyrolactone of the formula ##STR2## is reacted with an alcohol of the formulaR--O--H III,where R has the above meaning, at from 150.degree. to 400.degree. C. in the presence of an acidic catalyst.
摘要翻译：其中R为1至6个碳原子的烷基的式Ⅰ'的4-戊烯酸酯通过下式的方法制备，其中式Ⅰ的5-甲基丁内酯与式ROH III的醇反应，其中R具有上述含义，在150℃至400℃下在酸性催化剂存在下进行。

99. 发明授权

US4731445A Preparation of epsilon-caprolactam 失效
标题翻译： ε-己内酰胺的制备
公开(公告)号：US4731445A
公开(公告)日：1988-03-15
申请号：US007585
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester
IPC分类号： B01J23/00 , B01J23/74 , B01J23/78 , B01J25/00 , C07B61/00 , C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) the 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as the solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture,(c) the resulting reaction mixture is reacted with water at elevated temperatures with simultaneous removal of alkanols, and(d) the reaction mixture thus obtained is heated to 150.degree.-370.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译：己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在作为溶剂的链烷醇存在下和氢化催化剂存在下，在超大气压下在40℃的液相中反应（b）从反应混合物中分离出过量的氨和氢，（c）将所得的反应混合物在高温下与水反应，同时除去链烷醇，和（d）由此得到的反应混合物加热至150-370℃，得到ε-己内酰胺。

100. 发明授权

US4730041A Preparation of .epsilon.-caprolactams 失效
标题翻译： ε-己内酰胺的制备
公开(公告)号：US4730041A
公开(公告)日：1988-03-08
申请号：US7789
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
IPC分类号： B01J23/74 , B01J23/78 , B01J25/00 , C07B61/00 , C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) a 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as a solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture and(c) the reaction mixture thus obtained is heated to 150.degree.-250.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译：己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在烷醇作为溶剂的存在下和氢化催化剂的存在下在超大气压下在40℃的液相中反应至130℃，（b）从反应混合物中分离出过量的氨和氢，（c）将所得反应混合物加热至150-250℃，得到ε-己内酰胺。

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