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    • 98. 发明授权
    • Low temperature sintered ceramic capacitor with a temperature
compensating capability, and method of manufacture
    • 具有温度补偿能力的低温烧结陶瓷电容器及其制造方法
    • US4723193A
    • 1988-02-02
    • US945335
    • 1986-12-22
    • Hirokazu ChazonoHiroshi KishiShunji MuraiMasami FukuiTakeshi Wada
    • Hirokazu ChazonoHiroshi KishiShunji MuraiMasami FukuiTakeshi Wada
    • H01G4/30C04B35/47C04B35/49H01B3/12H01G4/12C04B35/50
    • C04B35/47C04B35/49H01G4/1245
    • A temperature compensating capacitor of monolithic or multilayered configuration comprising a dielectric ceramic body and at least two electrodes buried therein. The ceramic body is composed of a major ingredient expressed by the formula, {(Sr.sub.1-x-y Ca.sub.x M.sub.y)O}.sub.k (Ti.sub.1-z Zr.sub.z)O.sub.2, where M is at least either of magnesium and zinc, and where x, y, k and z are numerals in the ranges of zero to 0.995 inclusive, 0.005 to 0.100 inclusive, 1.00 to 1.04 inclusive, and 0.005 to 0.100 inclusive, respectively. To this major ingredient is added a minor proportion of a mixture of boric oxide, silicon dioxide, and one or more metal oxides selected from among barium oxide, magnesium oxide, zinc oxide, strontium oxide and calcium oxide. For the fabrication of capacitors the mixture of the above major ingredient and additives in finely divided form are formed into moldings of desired shape and size, each with at least two electrodes buried therein. The moldings and electrodes are cosintered in a reductive or neutral atmosphere and then are reheated at a lower temperature in an oxidative atmosphere. The cosintering temperature can be so low that nickel or like base metal can be employed as the electrode material.
    • 一种单片或多层结构的温度补偿电容器,包括介电陶瓷体和埋在其中的至少两个电极。 陶瓷体由以下式表示的主要成分{(Sr1-x-yCaxMy)O} k(Ti1-zZrz)O2组成,其中M是镁和锌中的至少一种,其中x,y,k z分别为0〜0.995,0.005〜0.100,包括1.00〜1.04,0.005〜0.100的数字。 添加少量的氧化硼,二氧化硅和一种或多种选自氧化钡,氧化镁,氧化锌,氧化锶和氧化钙的金属氧化物的混合物。 为了制造电容器,将上述主要成分和细分散形式的添加剂的混合物形成为所需形状和尺寸的模制品,其中至少埋设有两个电极。 模制品和电极在还原或中性气氛中共烧结,然后在较低温度下在氧化气氛中再加热。 整个烧结温度可以低到可以使用镍或类似的贱金属作为电极材料。
    • 99. 发明授权
    • Low temperature sintered ceramic capacitor with a temperature
compensating capability, and method of manufacture
    • 具有温度补偿能力的低温烧结陶瓷电容器及其制造方法
    • US4709299A
    • 1987-11-24
    • US934667
    • 1986-11-25
    • Hiroshi KishiMinoru OshioShunji MuraiTakeshi WadaMasami Fukui
    • Hiroshi KishiMinoru OshioShunji MuraiTakeshi WadaMasami Fukui
    • C04B35/47C04B35/49H01B3/12H01G4/12C04B35/46
    • C04B35/49C04B35/47H01G4/1245
    • A temperature compensating capacitor of monolithic or multilayered configuration comprising a dielectric ceramic body and at least two electrodes buried therein. The ceramic body is composed of a major ingredient expressed by the formula, (CaO).sub.k.(Zr.sub.1-x Ti.sub.x)O, where k and x are numerals in the ranges of 0.8 to 1.3 inclusive and of zero to 0.3 inclusive, respectively. To this major ingredient is added a minor proportion of a mixture of boric oxide, silicon dioxide, and one or more metal oxides selected from among barium oxide, magnesium oxide, zinc oxide, strontium oxide and calcium oxide. For the fabrication of capacitors the mixture of the above major ingredient and additives in finely divided form are formed into moldings of desired shape and size, each with at least two electrodes buried therein. The moldings and electrodes are cosintered in a reductive or neutral atmosphere and then are reheated at a lower temperature in an oxidative atmosphere. The cosintering temperature can be so low that nickel or like base metal can be employed as the electrode material.
    • 一种单片或多层结构的温度补偿电容器,包括介电陶瓷体和埋在其中的至少两个电极。 陶瓷体由式(CaO)k。(Zr1-xTix)O表示的主要成分组成,其中k和x分别为0.8〜1.3的数值和0〜0.3的数值。 添加少量的氧化硼,二氧化硅和一种或多种选自氧化钡,氧化镁,氧化锌,氧化锶和氧化钙的金属氧化物的混合物。 为了制造电容器,将上述主要成分和细分散形式的添加剂的混合物形成为所需形状和尺寸的模制品,其中至少埋设有两个电极。 模制品和电极在还原或中性气氛中共烧结,然后在较低温度下在氧化气氛中再加热。 整个烧结温度可以低到可以使用镍或类似的贱金属作为电极材料。
    • 100. 发明授权
    • Low temperature sintered ceramic capacitor with a temperature
compensating capability, and method of manufacture
    • 具有温度补偿能力的低温烧结陶瓷电容器及其制造方法
    • US4700269A
    • 1987-10-13
    • US934656
    • 1986-11-25
    • Hiroshi KishiMinoru OshioShunji MuraiTakeshi WadaMasami Fukui
    • Hiroshi KishiMinoru OshioShunji MuraiTakeshi WadaMasami Fukui
    • C04B35/49H01B3/12H01G4/008H01G4/12C04B35/46
    • H01G4/008H01G4/1245
    • A temperature compensating capacitor of monolithic, multilayered configuration comprising a dielectric ceramic body and at least two electrodes buried therein. The ceramic body is composed of a major ingredient expressed by the formula, (CaO).sub.k .multidot.(Zr.sub.1-x Ti.sub.x)O.sub.2, where k and x are numerals in the ranges of 0.8 to 1.3 inclusive and of zero to 0.3 inclusive, respectively. To this major ingredient is added a minor proportion of a mixture of lithium oxide, silicon dioxide, and one or more metal oxides selected from among barium oxide, magnesium oxide, zinc oxide, strontium oxide and calcium oxide. For the fabrication of capacitors the mixture of the above major ingredient and additives in finely divided form are formed into moldings of desired shape and size, each with at least two electrodes buried therein. The moldings and electrodes are cosintered in a reductive or neutral atmosphere and then are reheated at a lower temperature in an oxidative atmosphere. The cosintering temperature can be so low that nickel or like base metal can be employed as the electrode material.
    • 一种单片,多层结构的温度补偿电容器,包括介电陶瓷体和埋在其中的至少两个电极。 陶瓷体由式(CaO)k x(Zr 1-x Tix)O 2表示的主要成分组成,其中k和x分别为0.8〜1.3的数值和0〜0.3的数值。 在该主要成分中加入少量的氧化锂,二氧化硅和选自氧化钡,氧化镁,氧化锌,氧化锶和氧化钙中的一种或多种金属氧化物的混合物。 为了制造电容器,将上述主要成分和细分散形式的添加剂的混合物形成为所需形状和尺寸的模制品,其中至少埋设有两个电极。 模制品和电极在还原或中性气氛中共烧结,然后在较低温度下在氧化气氛中再加热。 整个烧结温度可以低到可以使用镍或类似的贱金属作为电极材料。